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Thin films of rf-magnetron sputtered InN on mica: Crystallography, electrical transport, and morphology

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Abstract

Reactive rf-magnetron sputtering has been employed for the growth of thin films of InN on the (001) face of mica at a variety of substrate temperatures from 50 to 550 °C. These films have been characterized by x-ray scattering, stylus profilometry, and electrical transport measurements, and their topography has been studied by SEM and STM. At low deposition temperatures, the InN films exhibit texture [(00.1)InN‖ (001)mica], while at higher deposition temperatures a large fraction of the grains are heteroepitaxial [(00.1)InN‖(001)mica, (21.0)InN · (060)mica]. The utility of the x-ray precession method in the determination of this heteroepitaxial relationship is highlighted. The films exhibit a local mobility maximum near a substrate temperature of 350 °C, beyond which a sharp increase in resistivity associated with voids and cracks owing to the onset of secondary grain growth leads to a dramatic decrease in electrical mobility. At the highest growth temperatures, however, the interconnection between grains improves and lower resistivity and higher mobility are re-established.

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References

  1. See, for example, G.A. Cox, D. O. Cummins, K. Kawabe, and R.H. Tredgold, J. Phys. Chem. Solids 28, 543 (1967); D.K. Wickenden, K. R. Faulkner, R. W. Faulkner, R. W. Brander, and B.J. Isherwood, J. Cryst. Growth 9, 158 (1971); W.M. Yim, E.J. Stofko, P.J. Zanzucchi, J.I. Pankove, M. Ettenberg, and S.L. Gilbert, J. Appl. Phys. 44, 292 (1973).

    Google Scholar 

  2. See, for example, T. Sasaki and S. Zembutsu, J. Appl. Phys. 61, 2533 (1987); H. Amano, I. Akasaki, K. Hiramatsu, N. Koide, and N. Sawaki, Thin Solid Films 163, 415 (1988); H. Amano, T. Asahi, and I. Akasaki, Cryst. Growth 98, 209 (1989); T.J. Kistenmacher, D. Dayan, R. Fainchtein, W. A. Bryden, J. S. Morgan, and T. O. Poehler, in Diamond, Boron Nitride, Silicon Carbide and Related Wide Bandgap Semiconductors, edited by J. T. Glass, R. F. Messier, and N. Fujimori (Mater. Res. Soc. Symp. Proc. 162, Pittsburgh, PA, 1990), p. 573.

    Google Scholar 

  3. See, for example, T. Sasaki, T. Matsuoka, and A. Katsui, Appl. Surf. Sci. 41/42, 504 (1989); Z. Sitar, M.J. Paisley, J. Ruan, W.J. Choyke, and R.F. Davis, J. Vac. Sci. Technol. B 8, 316 (1990).

  4. For a recent review and fresh insight, see J. I. Pankove, in Diamond, Boron Nitride, Silicon Carbide and Related Wide Bandgap Semiconductors, edited by J.T. Glass, R.F. Messier, and N. Fujimori (Mater. Res. Soc. Symp. Proc. 162, Pittsburgh, PA, 1990), p. 515.

    Google Scholar 

  5. See, for example, A. J. Noreika and D. W. Ing, J. Appl. Phys. 39, 5578 (1968); Y. Morimoto, K. Uchiho, and S. Ushio, J. Electron. Soc. 120, 1783 (1973); M. Morita, S. Isogai, N. Shimizu, K. Tsubouchi, and N. Mikoshiba, Jpn. J. Appl. Phys. 20, L173 (1981); C.R. Aita and C.J. Gawiak, J. Vac. Sci. Technol. A 1, 403 (1983).

    Google Scholar 

  6. B. B. Kosicki and D. Kahng, J. Vac. Sci. Technol. 6, 595 (1969); M. Mizuta, S. Fujieda, Y. Matsumoto, and T. Kawamura, Jpn. J. Appl. Phys. 25, L945 (1986); Y. Sato and S. Sato, Jpn. J. Appl. Phys. 28, L1641 (1989); Y. Mochizuki, M. Mizuta, S. Fujieda, and Y. Matsumoto, Appl. Phys. Lett. 55, 1318 (1989).

    Google Scholar 

  7. J. M. Axelrod and F. S. Grimaldi, Am. Mineral. 34, 559 (1949); E.W. Radoslovich, Acta Crystallogr. 13, 919 (1969).

    Google Scholar 

  8. W. A. Bryden, T. J. Kistenmacher, D. K. Wickenden, J. S. Morgan, A. K. Estes-Wickenden, S. A. Ecelberger, and T. O. Poehler, APL Tech. Dig. 10, 3 (1989); W.A. Bryden, J.S. Morgan, T.J. Kistenmacher, D. Dayan, R. Fainchtein, and T. O. Poehler, in Diamond, Boron Nitride, Silicon Carbide and Related Wide Bandgap Semiconductors, edited by J. T. Glass, R. F. Messier, and N. Fujimori (Mater. Res. Soc. Symp. Proc. 162, Pittsburgh, PA, 1990), p. 567.

    Google Scholar 

  9. J. S. Morgan, W.A. Bryden, T.J. Kistenmacher, S.A. Ecelberger, and T. O. Poehler, J. Mater. Res. 5, 2677 (1990).

    Article  CAS  Google Scholar 

  10. M. H. Read and D. H. Hensler, Thin Solid Films 10, 123 (1972).

    Article  CAS  Google Scholar 

  11. M.J. Buerger, The Precession Method in X-Ray Crystallography (Wiley, New York, 1964).

    Google Scholar 

  12. Nanoscope II from Digital Instruments, Inc., 6780 Cortona Drive, Santa Barbara, CA 93110.

  13. E. W. Miiller and T. T. Tsong, Field Ion Microscopy (American Elsevier Publishing Co. Inc., New York, 1969).

    Book  Google Scholar 

  14. R. C. Gifkins, Optical Microscopy of Metals (American Elsevier Publishing Co. Inc., New York, 1970).

    Google Scholar 

  15. T. J. Kistenmacher, W. A. Bryden, J. S. Morgan, and T. O. Poehler, J. Appl. Phys. 68, 1541 (1990).

  16. M. Bettini and G. Brandt, J. Appl. Phys. 50, 6938 (1979).

  17. M. Mizuta, S. Fujieda, Y. Matsumoto, and T. Kawamura, Jpn. J. Appl. Phys. 25, L945 (1986).

  18. R. D. Horning and J-L. Staudenmann, J. Cryst. Growth 80, 125 (1987).

    Article  CAS  Google Scholar 

  19. R. Fainchtein, D. Dayan, W. A. Bryden, J. C. Murphy, and T. O. Poehler, Rev. Prog. Quant. Nondestr. Eval. 9B, 1093 (1990).

    Article  Google Scholar 

  20. See, for example: (a) J. K. Gimzewski, A. Humbert, J. G. Bednorz, and B. Reihl, Phys. Rev. Lett. 55, 951 (1985); (b) C.E.D. Chidsey, D. N. Loiacono, T. Sleator, and S. Nakahara, Surf. Sci. 200, 45 (1988); (c) C. Schonenberger, S.F. Alvarado, and C. Ortiz, J. Appl. Phys. 66, 4258 (1989); (d) R.C. Barrett and C. F. Quate, J. Vac. Sci. Technol. A8, 400 (1990).

    Google Scholar 

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Kistenmacher, T.J., Bryden, W.A., Morgan, J.S. et al. Thin films of rf-magnetron sputtered InN on mica: Crystallography, electrical transport, and morphology. Journal of Materials Research 6, 1300–1307 (1991). https://doi.org/10.1557/JMR.1991.1300

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  • DOI: https://doi.org/10.1557/JMR.1991.1300

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