Abstract
Laser-heated float zone growth was used to study the directional solidification behavior of Bi–Sr–Ca–Cu–O superconductors. The phases that solidify from the melt, their morphology, and their composition are altered by growth rate. Highly textured microstructures are achieved by directional solidification at all growth rates. The superconducting phase is found always to have the composition Bi2.5Sr2CaCu2.2Oy when grown from boules with composition 2:2:1:2 (BiO1.5:SrO:CaO:CuO). Planar growth fronts of Bi2.5Sr2CaCu2.2Oy are observed when the temperature gradient divided by the growth rate (G/R) is larger than 3 ⊠ 1011 K-s/m2 in 2.75 atm oxygen. Thus, the 2212 compound was observed to solidify directly from the melt at the slowest growth rates used in this study. Measurement of the steady-state liquid zone composition indicates that it becomes bismuth-rich as the growth rate decreases. Dendrites of the primary solidification phase, (Sr1−xCax)14Cu24Oy, form in a matrix of Bi2.5Sr2CaCu2.2Oy when G/R is somewhat less than 3 ⊠ 1011 K-s/m2. Observed microstructures are consistent with a peritectic relationship among Bi2.5Sr2CaCu2.2Oy, (Sr1−xCax)14Cu24Oy (x = 0.4), and a liquid rich in bismuth at elevated oxygen pressure. At lower values of G/R, Sr3Ca2Cu5Oy is the primary solidification phase and negligible Bi2.5Sr2CaCu2.2Oy forms in the matrix.
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J. W. Ekin, A. I. Braginski, A. J. Panson, M. A. Janocko, D. W. Capone, N. J. Zaluzec, B. Flandermeyer, O. F. deLima, M. Hong, J. Kwo, and S. H. Lion, J. Appl. Phys. 62 (12), 4821–4828 (1987).
D. Dimos, P. Chaudhari, J. Mannhart, and F. K. LeGoues, Phys. Rev. Lett. 61 (2), 219–222 (1988).
J. Mannhart, P. Chaudhari, D. Dimos, C. C. Tsuei, and T. R. McGuire, Phys. Rev. Lett. 61 (21), 2476–2479 (1988).
J. S. Haggerty and W. P. Menashi, NASA, Contract No. NAS3–13479 (February 1971).
J. S. Haggerty, W. P. Menashi, and J. F. Wenckus, “Methods of Forming Refractory Fibers by Laser Energy,” U. S. Patent No. 3944640, March 1976.
S. Jin, T. H. Tiefel, R. C. Sherwood, M. E. Davis, R. B. van Dover, G. W. Kanemlott, R. A. Fastnacht, and H. D. Keith, Appl. Phys. Lett. 52 (24), 2074–2076 (1988).
M. Murakami, M. Marita, K. Doi, and K. Miyamoto, J. Appl. Phys., preprint (1989).
R. S. Feigelson, D. Gazit, D. K. Fork, and T. H. Geballe, Science 240, 1642–1645 (1988).
S. Takekawa, H. Nozaki, A. Umizone, K. Kosuda, and M. Kobayashi, J. Cryst. Growth 92, 687 (1988).
H. D. Brody, J. S. Haggerty, M. J. Cima, M. C. Flemings, R. L. Barns, M. Gyorgy, D. W. Johnson, W. W. Rhodes, W. A. Sunder, and R. A. Laudise, J. Cryst. Growth 96, 225–233 (1989).
Y. Shiohara, M. Nakagawa, T. Suga, K. Ishige, T. Oyama, T. Izumi, S. Nagaya, M. Miyajima, I. Hirabayashi, and S. Tanaka, Proc. of 2nd Int. Symp. on Superconductivity, Tsukuba, Japan, 1989 (to be published by Springer-Verlag, Tokyo).
W. G. Pfann, Zone Melting (John Wiley & Sons, New York, 1958).
M. C. Flemings, Solidification Processing (McGraw-Hill, New York, 1974).
F. R. Mollard and M. C. Flemings, Trans. TMS-AIME 239, 1526–1533 (1967).
M. Rinaldi, R. M. Sharp, and M. C. Flemings, Metall. Trans. 3, 3139 (1972).
S. A. David and H. D. Brody, Metall. Trans. 5, 2608–2610 (1974).
J. D. Hunt and K. A. Jackson, AIME Trans. 236, 843 (1966).
V. S. Stubican and R. C. Bradt, Ann. Rev. Mat. Sci. 11, 287–297 (1981).
D. Dubois, G. Dhalenne, F. d’Yvoire, and A. Revcolevschi, J. Am. Ceram. Soc. 69 (1), C6–C8 (1986).
G. Sheherbakov, S. A. David, and H. D. Brody, Scripta Metall. 8, 1239–1244 (1974).
H. D. Brody and S. A. David, Solidification and Casting of Metals (Institute of Metals, New York, 1979), pp. 141–151.
F. Kimura and I. Shindo, J. Cryst. Growth 41, 192–198 (1977).
B. Chalmers, Principles of Solidification (J. Wiley, New York, 1964), pp. 150–163.
W. A. Tiller, K. A. Jackson, J. W. Rutter, and B. Chalmers, Acta Metall. 1, 428 (1953).
W. Kurz and D. J. Fisher, Fundamentals of Solidification (Trans. Tech. Publications, Ltd., Switzerland, 1986), pp. 47–58.
Z. Schlesinger, R. T. Collins, and D. L. Kaiser, Phys. Rev. Lett. 59, 1958–1961 (1987).
Y. Oka, N. Yamamoto, H. Kitaguchi, K. Oda, and J. Takada, Jpn. J. Appl. Phys. 28 (2), L213–L216 (1989).
M. Onoda, A. Yamamoto, E. Takayama-Muromachi, and S. Takekawa, Jpn. J. Appl. Phys. 27 (5) L833–L836 (1988).
J. Luo, J. A. Cutro, H. M. Chow, M. J. Cima, and D. A. Rudman, 1990 APS, March Meeting, Anaheim, CA.
R. Guillermo, P. Confiant, J. Boivin, and D. Thomas, Rev. de Chim. minèrale 15, 153–159 (1978).
P. Confiant, J. Boivin, and D. Thomas, J. Solid State Chem. 18, 133–140 (1976).
E. M. Levin and R. S. Roth, J. Res. N. B. S. 68A (2), 197–206 (1964).
B. C. Chakoumakos, P. S. Ebey, B. C. Sales, and E. Sonder, J. Mater. Res. 4, 767–780 (1989).
J. Boivin, D. Thomas, and G. Tridot, C. R. Acad. Sc. Paris 276, 1105–1107 (1973).
R. S. Roth, C. J. Rawn, J. D. Whitler, J. J. Ritter, and B. Burton, to be published in the J. Am. Ceram. Soc.
C. C. Torardi, M. A. Subramanian, J. C. Calabrese, J. Gopalakrishnan, K. J. Morrissey, T. R. Askew, R. B. Flippen, U. Chowdhry, and A. W. Sleight, Science 240, 631–634 (1988).
J. A. Saggio, K. Sujata, J. Hahn, S. J. Hwu, K. R. Poeppelmeier, and T. O. Mason, J. Am. Ceram. Soc. 72 (5), 849–853 (1989).
F. Lange, University of California, Santa Barbara (private communication).
A. M. Gadalla and J. White, Trans. Brit. Ceram. Soc. 65 (4), 185 (1966).
N. G. Schmal and E. Minzl, Z. Physik. Chem. Frankfurt/M 47, 358 (1965).
Teske and H-K. Müller-Buschbaum, Z. Anorg. Allg. Chem. 371, 325–332 (1969).
Teske and H-K. Müller-Buschbaum, Z. Anorg. Allg. Chem. 379, 234–241 (1970).
D. Gazit, P. N. Peszkin, L. V. Moulton, and R. S. Feigelson, J. Cryst. Growth 98, 545–549 (1989).
X. P. Jiang, H. D. Brody, M. J. Cima, H. M. Chow, J. S. Haggerty, and M. C. Flemings, in preparation.
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Cima, M.J., Jiang, X.P., Chow, H.M. et al. Influence of growth parameters on the microstructure of directionally solidified Bi2Sr2CaCu2Oy. Journal of Materials Research 5, 1834–1849 (1990). https://doi.org/10.1557/JMR.1990.1834
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DOI: https://doi.org/10.1557/JMR.1990.1834