Abstract
This paper analyzes the influence of the deposition conditions (substrate temperature and oxygen flow) on the magnetic moment of Fe3O4 films grown by reactive RF sputtering. With conversion electron Mössbauer spectroscopy and transmission electron microscopy of specific microstructures we have identified different mechanisms which can contribute to the decrease of M in our samples: decrease of average grain size (superparamagnetism) and distortion of the lattice which may induce mispopulation of tetrahedral and octahedral sites and decrease of crystalline quality.
Similar content being viewed by others
References
C. Ortiz, G. Lim, M. M. Chen, and G. Castillo, J. Mater. Res. 3, 344 (1988).
For instance, J. Y. Feng, C. H. Bajorek, and M. A. Nicolet, IEEE Trans. Mag. 9, 344 (1988).
P. J. Picone and A. H. Morrish, J. Appl. Phys. 53, 2471 (1982).
W. Kuendig and R. S. Hargrove, Solid State Commun. 7, 223 (1969).
G. A. Sawatzky, F. Van der Wonde, and A. H. Morrish, Phys. Rev. 183, 383 (1969).
This overlap can often be reduced by applying an external magnetic field. In our case, we could not do so because we used a gas detector.
C. Hwang and M. M. Chen, J. Appl. Phys. 63, 3275 (1988).
K. Haneda and A. H. Morrish, Solid State Commun. 22, 779 (1977).
K. Haneda and A. H. Morrish, Proc. Int. Symp. Physics Mag. Materials, Sendai, Japan, 214 (1987).
P. Roggwiller and W. Kundig, Solid State Commun. 12, 901 (1973).
M. Fujinani and Y. Ujikira, Hyperfine Interactions 29, 1475 (1986).
S. Parkin (private communication).
T. Terashim and Y. Bando, J Phys. Soc. Japan 54, 3920 (1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ortiz, C., Hwang, C., Morrish, A.H. et al. Microstructure and conversion electron Mössbauer studies of M decrease in Fe3O4 films. Journal of Materials Research 5, 824–828 (1990). https://doi.org/10.1557/JMR.1990.0824
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1990.0824