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Intercalation of mixed chloride–fluorides of antimony in graphite

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Abstract

The intercalation of SbCl4F and SbCl3F2 into graphite is described. The c-axis identity period, measured by (00/) x-ray diffraction, is 9.30, 12.69, and 16.04 Å for stages 1, 2, and 3, respectively, of SbCl4 F-intercalated graphite. The c-axis identity period for stage 1 SbCl4F-intercalated graphite is 8.85 Å. Mass spectroscopy shows that the molecule in SbCl4F-intercalated graphite is a (SbCl4F)4 tetramer. The molecule in SbCl3F2-intercalated graphite is a (SbCl3F2)4 tetramer. Mossbauer measurements show that Sb is in a 5 + state in SbCl4F-intercalated graphite.

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Authors and Affiliations

  1. Department of Physics, McMaster University, Hamilton, L8S4M1, Ontario, Canada

    W. R. Datars, H. Zaleski & P. K. Ummat

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  1. W. R. Datars
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  2. H. Zaleski
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  3. P. K. Ummat
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Datars, W.R., Zaleski, H. & Ummat, P.K. Intercalation of mixed chloride–fluorides of antimony in graphite. Journal of Materials Research 3, 705–709 (1988). https://doi.org/10.1557/JMR.1988.0705

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  • DOI: https://doi.org/10.1557/JMR.1988.0705

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