Abstract
Au-Pt and Au-Pd bimetallic nanoclusters that catalyzed the aerobic oxidation of alcohols during a once-through pass through gas-liquid-liquid-solid flow systems were developed. Alcohols were converted to aldehydes and ketones in benzotrifluoride (BTF)/water media by Au-Pt catalyst or to the corresponding methyl esters in methanol/water media by Au-Pd catalyst. The flow systems were superior to the batch systems in terms of both yield and selectivity.
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Details of ratio of catalysts and Celite are shown in Supporting Information.
Details of determination of the residence time are shown in Supporting Information.
Details of reaction profiles are shown in Supporting Information.
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Kaizuka, K., Lee, KY., Miyamura, H. et al. Multiphase Flow Systems for Selective Aerobic Oxidation of Alcohols Catalyzed by Bimetallic Nanoclusters. J Flow Chem 2, 1–4 (2012). https://doi.org/10.1556/jfchem.2011.00014
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DOI: https://doi.org/10.1556/jfchem.2011.00014