Summary
Nanomaterials show a better performance in environmental remediation than other conventional materials because of their high surface area and their associated high reactivity. Nanostructured photocatalysts, especially TiO2, are widely studied for the treatment of contaminated water. They can indeed degrade organic pollutants and microorganisms. In the first part of this review, the fundamentals of heterogeneous photocatalysis are described, with particular attention to the most important recent progresses in the field of nanostructured TiO2 for water treatment. The strategies to improve its efficiency and to enhance its photo-catalytic performance in the visible region are also illustrated. However, although the nanoscaled catalysts show considerable improvement in terms of water purification efficiency, their size remains the main problem in a large-scale process because of the need of a post-treatment recovery, necessary to avoid their impact on the environment and human health. For this reason, the immobilization of photocatalysts on different substrates has been drawing a significant attention. Considering the various substrates, polymers seem to be very promising. The most recent developments in the applications of polymer-TiO2 nanocomposites for water purification are presented. Finally, the recent interest addressed to the use of molecularly imprinted polymers for wastewater treatment is discussed, showing preliminary results and future perspectives.
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References
Padmanabhan P. V. A., Sreekumar K. P., Thiyagarajan T. K., Satpute R. U., Bhanumurthy K., Sengupta P., Dey G. K. and Warrier K. G. K., Vacuum, 80 (2006) 11.
Gaya U. I. and Abdullah A. H., J. Photochem. Photobiol. C: Photochem. Rev., 9 (2008) 1.
Yang H. and Cheng H., Sep. Purif. Technol., 56 (2007) 392.
Fujishima A. and Honda K., Nature, 238 (1972) 37.
Frank S. N. and Bard A. J., J. Phys. Chem., 81 (1977) 1484.
Krautler B. and Bard A. J., J. Am. Chem. Soc., 100 (1978) 5958.
Fujishima A., Rao T. N. and Tryk D. A., J. Photochem. Photobiol. C: Photochem. Rev., 1 (2000) 1.
Houas A., Lachheb H., Ksibi M., Elaloui E., Guillard C. and Hermann J. M., Appl. Catal. B Environ., 31 (2001) 145.
Chong M. N., Jin B., Chow C. W. K. and Saint C., Water Res., 44 (2010) 2997.
Hu A. and Apblett A., Nanotechnology for water treatment and purification (Springer International Publishing, Switzerland) 2014.
Carp O., Huisman C. L. and Reller A., Prog. Solid State Chem., 32 (2004) 33.
Diebold U., Surf. Sci. Rep., 48 (2003) 53.
Luttrell T., Sci. Rep. (2014) DOI: 10.1038/srep04043.
Yang H. G., Sun C. H., Qiao S. Z., Zou J., Liu G., Smith S. C., Cheng H. M. and Lu G. Q., Nature, 453 (2008) 638.
D’Arienzo M., Carbajo J., Bahamonde A., Crippa M., Polizzi S., Scotti R., Wahba L. and Morazzoni F., J. Am. Chem. Soc., 133 (2011) 17652.
Han X., Kuang Q., Jin M., Xie Z. and Zheng L., J. Am. Chem. Soc., 131 (2009) 3152.
Yang H. G., Liu G., Qiao S. Z., Sun C. H., Jin Y. G., Smith S. C., Zou J., Cheng H. M. and Lu G. Q., J. Am. Chem. Soc., 131 (2009) 4078.
Gordon T. R., Cargnello M., Paik T., Mangolini F., Weber R. T., Fornasiero P. and Murray C. B., J. Am. Chem. Soc., 134 (2012) 6751.
Xiang Q., Lv K. and Yua J., Appl. Catal. B, 95 (2010) 557.
Etacheri V., Di Valentin C., Schneider J., Bahnemann D. and Pillai S., J. Photochem. Photobiol. C: Photochem. Rev., 25 (2015) 1.
Matsunaga T., Tomoda R., Nakajima T. and Wake H., FEMS Microbiol. Lett., 29 (1985) 211.
Zimbone M., Buccheri M. A., Cacciato G., Sanz R., Rappazzo G., Boninelli S., Reitano R., Romano L., Privitera V. and Grimaldi M. G., Appl. Catal. B, 165 (2015) 487.
Ibanez J. A., Litter M. I. and Pizarro R. A., J. Photochem. Photobiol. A Chem., 157 (2003) 81.
Cho M., Chung H., Choi W. and Yoon J., Water Res., 38 (2004) 1069.
Pelaez M., Nolan N. T., Pillai S. C., Seery M. K., Falaras P., Kontos A. G., Dunlop P. S. M., Hamilton J. W. J., Byrne J. A. and Dionysiou D. D., Appl. Catal. B: Environ., 125 (2012) 331.
Reddy P. A. K., Reddy P. V. L., Kwon E., Kim K. H., Akter T. and Kalagara S., Environ. Int., 91 (2016) 94.
Dong H., Zeng G., Tang L., Fan C., Zhang C., He X. and He Y., Water Res., 79 (2015) 128.
Impellizzeri G., Scuderi V., Romano L., Sberna P., Arcadipane E., Sanz R., Simone F. and Privitera V., J. Appl. Phys., 116 (2014) 173507.
Scuderi V., Impellizzeri G., Romano L., Scuderi M., Brundo M. V., Bergum K., Zimbone M., Sanz R., Buccheri M. A., Simone F., Nicotra G., Svensson B. G., Grimaldi M. G. and Privitera V., Nanoscale, 6 (2014) 11189.
Wang W., Zhang J., Chen F., He D. and Anpo M. J., Colloid. Interface Sci., 323 (2008) 182.
Ambrus Z., Balasz N., Alapi T., Wittmann G., Sipos P., Dombi A. and Mogyorosi K., Appl. Catal. B, 81 (2008) 27.
Tong T., Zhang J., Tian B., Chen F. and He D. J., Hazard. Mater., 155 (2008) 572.
Impellizzeri G., Scuderi V., Romano L., Napolitani E., Sanz R., Carles R. and Privitera V., J. Appl. Phys., 117 (2015) 105308.
Zaleska A., Recent Pat. Eng., 2 (2008) 157.
Irie H., Watanabe Y. and Hashimoto K., J. Phys. Chem. B, 107 (2003) 5483.
Lindgren T., Mwabora J. M., Avandano E., Jonsson J., Hoel A., Granqcist C. G. and Lindquist S. E., J. Phys. Chem. B, 107 (2003) 5709.
Pichat P., Photocatalysis and Water Purification: from fundamentals to recent applications, first edition (Wiley-VCH Verlag GmbH & Co) 2013.
Abe R., Sayama K. and Arakawa H., Chem. Phys. Lett., 362 (2002) 441.
Wang Y., He Y., Lai Q. and Fan M., J. Environ. Sci., 26 (2014) 2139.
Scuderi V., Impellizzeri G., Zimbone M., Sanz R., Di Mauro A., Buccheri M. A., Miritello M., Terrasi A., Rappazzo G., Nicotre G. and Privitera V., Appl. Catal. B, 183 (2016) 328.
Scuderi V., Impellizzeri G., Romano L., Scuderi M., Nicotra G., Bergum K., Irrera A., Svensson B. G. and Privitera V., Nanoscale Res. Lett., 9 (2014) 458.
Convertino A., Maiolo L., Scuderi V., Di Mauro A., Scuderi M., Nicotra G., Impellizzeri G., Fortunato G. and Privitera V., RSC Advances, 6 (2016) 91121.
Schultz A. G., Boyle D., Chamot D., Ong K. J., Wilkinson K. J., McGeer J. C., Sunahara G. and Goss G. G., Environ. Chem., 11 (2014) 207.
Walters C. R., Pool E. J. and Somerset V. S., J. Environ. Sci. Health. Part A, 49 (2014) 1588.
Kwak J. I. and An Y. J., Int. J. Environ. Sci. Technol., 12 (2015) 1163.
Fernandez-Ibanez P., Blanco J., Malato S. and De Las Nieves F. J., Water Res., 37 (2003) 3180.
Lee S. A., Choo K. H., Lee C. H., Lee H. I., Hyeon T., Choi W. and Kwon H. H., Ind. Eng. Chem. Res., 40 (2001) 1712.
Molinari R., Palmisano L., Drioli E. and Schiavello M., J. Memb. Sci., 206 (2002) 399.
Di Mauro A., Cantarella M., Nicotra G., Scuderi M., Brundo M. V., Privitera V. and Impellizzeri G., Sci. Rep., 7 (2017) 40895.
Di Mauro A., Cantarella M., Nicotra G., Privitera V. and Impellizzeri G., Appl. Catal. B, 196 (2016) 68.
Shan A. Y., Ghazi T. I. M. and Rashid S. A., Appl. Catal A, 389 (2010) 1.
Singh S., Mahalingam H. and Singh P. K., Appl. Catal A, 462 (2013) 178.
Fabiyi M. E. and Skelton R. L., J. Photochem. Photobiol. A, 132 (2000) 121.
Magalhaes F., Moura F. C. C. and Lago R. M., Desalination, 276 (2011) 266.
Kim H., Hong H. J., Jung J., Kim S. H. and Yang J. W., J. Hazard. Mater., 176 (2010) 1038.
Chen Y., Stathatos E. and Dionysiou D. D., Surf. Coat. Technol., 202 (2008) 1944.
Balasubramanian G., Dionysiou D. D., Suidan M. T., Baudin I. and Laine J. M., Appl. Catal. B: Environ., 47 (2004) 73.
Liu A. and Chen X., J. Chem. Technol. Biotechnol., 82 (2007) 453.
Djosic M. S., Miskovic-Stankovic V. B., Janackovic D. T., Kacarevic-Popovic Z. M. and Petrovic R. D., Colloids Surf. A, 274 (2006) 185.
Langlet M., Kim A., Audier M. and Hermann J. M., J. Sol-Gel Sci. Technol., 25 (2002) 223.
Tennakone K., Tilakaratne C. T. K. and Kottegoda I. R. M., J. Photochem. Photobiol. A, 87 (1995) 177.
Kasanen J., Suvanto M. and Pakkanen T. T., J. Appl. Polym. Sci., 111 (2009) 2597.
Fostier A. H., Pereira M. D. S. S., Rath S. and Guimaraes J. R., Chemosphere, 72 (2008) 319.
Meichtry J. M., Lin H. J., de la Fuente L., Levy I. K., Gautier E. A., Blesa M. A. and Litter M. I., J. Sol. Energy Eng., 129 (2007) 119.
Sriwong C., Wongnawa S. and Patarapaiboolchai O., Catal. Commun., 9 (2008) 213.
Demir M. M., Memesa M., Castignolles P. and Wegner G., Macromol. Rapid Commun., 10 (2006) 763.
Demir M. M., Castignolles P., Akbey U. and Wegner G., Macromolecules, 40 (2007) 4190.
Cantarella M., Sanz R., Buccheri M. A., Ruffino F., Rappazzo G., Scalese S., Impellizzeri G., Romano L. and Privitera V., J. Photochem. Photobiol. A, 321 (2016) 1.
Cantarella M., Sanz R., Buccheri M. A., Romano L. and Privitera V., Mater. Sci. Semicond. Process., 42 (2016) 58.
Hafizah N. N., Mamat M. H., Said C. M. S., Abidin M. H. and Rusop M., IOP Conf. Ser. Mater. Sci. Eng., 46 (2013) 012045.
Mills A., Hill C. and Robertson P. K. J., J. Photochem. Photobiol. A, 237 (2012) 7.
Fine ceramics (advanced ceramics, advanced technical ceramics) — Determination of photocatalytic activity of surfaces in an aqueous medium by degradation of methylene blue. ISO 10678:2010(E). International Organization for Standardization, Switzerland (2010).
Rochking M., Pasternak S. and Paz Y., Molecules, 20 (2015) 88.
Hoffmann M. R., Martin S. T., Choi W. and Bahnemann D. W., Chem. Rev., 95 (1995) 69.
Guldi D. M., Rahman G. M. A., Zerbetto F. and Prato M., Acc. Chem. Res., 38 (2005) 871.
Woan K., Pyrgiotakis G. and Sigmund W., Adv. Mater., 21 (2009) 2233.
Chen J., Qiu F., Xu W., Cao S. and Zhu H., Appl. Catal. A, 495 (2015) 131.
Wang C., Li J., Mele G., Yang G. M., Zhang F. X., Palmisano L. and Vasapollo G., Appl. Catal. B, 76 (2007) 218.
Youngblood W. J., Anna Lee S. H., Maeda K. and Mallouk T. E., Acc. Chem. Res., 42 (2009) 1966.
Pellegrino G., Condorelli G. G., Privitera V., Cafra B., Di Marco S. and Alberti A., J. Phys. Chem. C, 115 (2011) 7760.
Zhou X. T., Ji H. B. and Huang X. J., Molecules, 17 (2012) 1149.
Cherian S. and Wamser C. C., J. Phys. Chem. B, 104 (2000) 3624.
Boxall A. B. A., New and Emerging Water Pollutants arising from Agriculture (OECD Publishing) 2012.
Oaks J. L., Gilbert M., Virani M. Z., Watson R. T., Meteyer C. U., Rideout B. A., Shivaprasad H. L., Ahmed S., Chaudhry M. J. I., Arshad M., Mahmood S., Ali A. and Khan A. A., Nature, 427 (2004) 630.
Garric J., Vollat, B., Duis K., Péry A., Junker T., Ramil M., Fink G. and Ternes T. A., Chemosphere, 69 (2007) 903.
Lange R., Hutchinson T. H., Croudace C. P., Siegmund F., Schweinfurth H., Hampe P., Panter G. H. and Sumpter J. P., Environ. Toxicol. Chem., 20 (2001) 1216.
Boxall A. B. A., Kolpin D. W., Halling-Sorensen B. and Tolls J., Environ. Sci. Technol., 37 (2003) 286A.
Alder A. C., Consumption and occurrence, in Human Pharmaceuticals, Hormones and Fragrances. The challenge of Micropollutants in Urban Water Management, edited by Ternes T. A. and Joss A. (IWA Publishing) 2006.
Lonappan L., Brar S. K, Das R. K., Verma M. and Surampalli R. Y., Environ. Int., 96 (2016) 127.
Hughes S. R., Kay P. and Brown L. E., Environ. Sci. Technol., 47 (2013) 661.
Loos R., Carvalho R., Antonio D. C., Comero S., Locoro G., Tavazzi S., Paracchini B., Ghiani M., Lettieri T., Blaha L., Jarosova B., Voorspoels S., Servaes K., Haglund P., Fick J., Lindberg R. H., Schwesig D. and Gawlik B. M., Water Res., 47 (2013) 6475.
Petrie B., Barden R. and Kasprzyk-Horden B., Water Res., 72 (2015) 3.
Haupt K. and Mosbach K., Chem. Rev., 100 (2000) 2495.
MartÃn-Esteban A., Trac-Trends Anal. Chem., 45 (2013) 169.
Malitesta C., Mazzotta E., Picca R. A., Poma A., Chianella I. and Piletsky S. A., Anal. Bioanal. Chem., 402 (2012) 1827.
Huang D. L., Wang R. Z., Liu Y. G., Zeng G. M., Lai P., Lu B. A., Xu J. J., Wang C. and Huang C., Environ. Sci. Pollut. Res., 22 (2015) 963.
He C. Y., Long Y. Y. and Pan J. L., J. Biochem. Bioph. Meth., 70 (2007) 133.
Zheng C., Huang Y. P. and Liu Z. S., Anal. Bioanal. Chem., 405 (2013) 2147.
Mayes A. G. and Mosbach K., Anal. Chem., 68 (1996) 3769.
Yan S. L., Gao Z. X., Fang Y. J., Cheng Y. Y., Zhou H. Y. and Wang H. Y., Dyes Pigm., 74 (2007) 572.
Hu X., Hu Y. and Li G., J. Chromatogr. A, 1147 (2007) 1.
Gao B., Wang J., An F. and Liu Q., Polymer, 49 (2008) 1230.
Puoci F., Iemma F., Cirillo G., Picci N., Matricardi P. and Alhaique F., Molecules, 12 (2007) 805.
Bhaskarapillai A., Sevilimedu N. V. and Sellergren B., Ind. Eng. Chem. Res., 48 (2009) 3730.
Gholivand M. B., Torkashvand M. and Malekzadeh G., Anal. Cim. Acta, 713 (2012) 36.
Ivanova-Mitsev P. K., Guerreiro A., Piletska E. V., Whitcombe M. J., Zhou Z., Mitsev P. A., Davis F. and Piletsky S. A., Angew. Chem., Int. Ed., 51 (2012) 5196.
Spivak D. A. and Shea K. J., Macromolecules, 31 (1998) 2160.
Byun H. S., Youn Y. N., Yun Y. H. and Yoon S. D., Sep. Purif. Technolog., 74 (2010) 144.
Apodaca D. C., Pernites R. B., Ponnapati R., Del Mundo F. R. and Advincula R. C., Macromolecules, 44 (2011) 6669.
Abbate V., Bassindale A. R., Brandstadt K. F. and Taylor P. G., J. Catal., 284 (2011) 68.
da Silva M. S., Viveiros R., Morgada P. I., Aguiar-Ricardo A., Correia I. J. and Casimiro T., Int. J. Pharm., 416 (2011) 61.
Hoshino Y., Koide H., Urakami T., Kanazawa H., Kodama T., Oku N. and Shea K. J., J. Am. Chem. Soc., 19 (2010) 644.
Shen X., Xu C. and Ye L., Ind. Eng. Chem. Res., 52 (2013) 13890.
Dai C. M., Geissen S. U., Zhang Y. L., Zhang Y. J. and Zhou X. F., Environ. Pollut., 159 (2011) 1660.
Jing T., Wang J., Liu M., Zhou Y., Zhou Y. and Mei S., Environ. Sci. Pollut. R., 21 (2014) 1153.
Meng Z., Zhang Q., Xue M., Wang D. and Wang A., Propellants Explos. Pyrotech., 37 (2012) 100.
Liu J. and Wulff G., J. Am. Chem. Soc., 130 (2008) 8044.
Shen X., Zhu L., Liu G., Yu H. and Tang H., Environ. Sci. Technol., 42 (2008) 1687.
Pan G. Q., Zhang Y., Ma Y., Li C. X. and Zhang H. Q., Angew. Chem., Int. Ed., 50 (2011) 11731.
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Cantarella, M., Impellizzeri, G. & Privitera, V. Functional nanomaterials for water purification. Riv. Nuovo Cim. 40, 595–632 (2017). https://doi.org/10.1393/ncr/i2017-10142-8
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DOI: https://doi.org/10.1393/ncr/i2017-10142-8