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Effect of End-Capping and Surface Coverage on the Mechanism of Solvent Adsorption

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Abstract

Adsorption of acetonitrile and methanol was measured on non-endcapped and endcapped octadecyl stationary phases. The results enabled us to characterize the effect of end-capping on the adsorption of the organic modifiers. Our results clearly demonstrate how the end-capping groups modify the chromatographic properties of adsorbents. Differences between solvent adsorption mechanisms are also discussed. Adsorption of acetonitrile is governed by hydrophobic effects whereas methanol is adsorbed by the organic ligand by a hydrophobic interaction and by the residual silanols by hydrogen-bond formation and dipole–dipole interactions.

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References

  1. Jaroniec M (1993) J Chromatogr A 656:37–50. doi:10.1016/0021-9673(93)80796-B

    Article  CAS  Google Scholar 

  2. Kazakevich YV (2006) J Chromatogr A 1126:232–243. doi:10.1016/j.chroma.2006.05.022

    Article  CAS  Google Scholar 

  3. Bocian S, Felinger A, Buszewski B (2008) Chromatographia 68:S19–S26. doi:10.1365/s10337-008-0519-4

    Article  CAS  Google Scholar 

  4. Jaroniec M (1996) J Chromatogr A 722:19–24. doi:10.1016/0021-9673(95)00482-3

    Article  CAS  Google Scholar 

  5. Kazakevich YV, McNair HM (1995) J Chromatogr Sci 33:321–327

    CAS  Google Scholar 

  6. Gritti F, Guiochon G (2005) Anal Chem 77:4257–4272. doi:10.1021/ac0580058

    Article  CAS  Google Scholar 

  7. Gritti F, Guiochon G (2007) J Chromatogr A 1155:85–99. doi:10.1016/j.chroma.2007.04.024

    Article  CAS  Google Scholar 

  8. Jandera P, Skavrada M, Andela L, Komers D, Guiochon G (2001) J Chromatogr A 908:3–17. doi:10.1016/S0021-9673(00)01003-7

    Article  CAS  Google Scholar 

  9. Gritti F, Kazakevich YV, Guiochon G (2007) J Chromatogr A 1169:111–124. doi:10.1016/j.chroma.2007.08.071

    Article  CAS  Google Scholar 

  10. Buszewski B, Bocian S, Felinger A (2008) J Chromatogr A 1191:72–77. doi:10.1016/j.chroma.2007.11.074

    Article  CAS  Google Scholar 

  11. Sandi A, Szepesy L (1999) J Chromatogr A 845:113–131. doi:10.1016/S0021-9673(99)00361-1

    Article  CAS  Google Scholar 

  12. Gritti F, Guiochon G (2005) J Chromatogr A 1075:117–126. doi:10.1016/j.chroma.2005.03.095

    Article  CAS  Google Scholar 

  13. Nawrocki J (1997) J Chromatogr A 779:29–71. doi:10.1016/S0021-9673(97)00479-2

    Article  CAS  Google Scholar 

  14. Knox JH, Kaliszan R (1985) J Chromatogr 349:211–234. doi:10.1016/S0021-9673(01)83779-1

    Article  CAS  Google Scholar 

  15. McCormick RM, Karger BL (1980) Anal Chem 52:2249–2257. doi:10.1021/ac50064a005

    Article  CAS  Google Scholar 

  16. Eltekov A, Kazakevich YV (1987) J Chromatogr 395:473–480. doi:10.1016/S0021-9673(01)94134-2

    Article  CAS  Google Scholar 

  17. Riedo F, Kovats E (1982) J Chromatogr 239:1–28. doi:10.1016/S0021-9673(00)81964-0

    Article  CAS  Google Scholar 

  18. Kazakevich YV, LoBrutto R, Chan F, Patel T (2001) J Chromatogr A 913:75–87. doi:10.1016/S0021-9673(00)01239-5

    Article  CAS  Google Scholar 

  19. Bocian S, Vajda P, Felinger A, Buszewski B (2008) J Chromatogr A 1204:35–41. doi:10.1016/j.chroma.2008.07.056

    Article  CAS  Google Scholar 

  20. Buszewski B, Krupczyńska K, Gadzała-Kopciuch RM, Rychlicki G, Kaliszan R (2003) J Sep Sci 26:313–321. doi:10.1002/jssc.200390037

    Article  CAS  Google Scholar 

  21. Buszewski B, Jaroniec M, Gilpin RK (1994) J Chromatogr A 668:293–299. doi:10.1016/0021-9673(94)80118-5

    Article  CAS  Google Scholar 

  22. Wang HL, Duda JL, Radke CJ (1978) J Colloid Interface Sci 66:153–165. doi:10.1016/0021-9797(78)90196-0

    Article  CAS  Google Scholar 

  23. Hafkenscheid TL, Tomlinson E (1986) Adv Chromatogr 25:1–62

    CAS  Google Scholar 

  24. Berendsen GE, de Galan L (1980) J Chromatogr 196:21–37. doi:10.1016/S0021-9673(00)80356-8

    Article  CAS  Google Scholar 

  25. Buszewski B, Jaroniec M, Gilpin RK (1994) J Chromatogr A 673:11–19. doi:10.1016/0021-9673(94)87052-7

    Article  CAS  Google Scholar 

  26. Buszewski B, Schmid J, Albert K, Bayer E (1991) J Chromatogr 552:415–427. doi:10.1016/S0021-9673(01)95957-6

    Article  CAS  Google Scholar 

  27. Buszewski B, Gadzała-Kopciuch RM, Kaliszan R, Markuszewski M, Matyska MT, Pesek JJ (1998) Chromatographia 48:615–622. doi:10.1007/BF02467590

    Article  CAS  Google Scholar 

  28. Buszewski B, Gadzała-Kopciuch RM, Markuszewski M, Kaliszan R (1997) Anal Chem 69:3277–3284. doi:10.1021/ac9612032

    Article  CAS  Google Scholar 

  29. Giaquinto A, Liu Z, Bach A, Kazakevich YV (2008) Anal Chem 80:6358–6364. doi:10.1021/ac800772s

    Article  CAS  Google Scholar 

  30. Bocian S, Vajda P, Felinger A, Buszewski B (2009) Anal Chem 81:6334–6346. doi:10.1021/ac9005759

    Article  CAS  Google Scholar 

  31. Buszewski B, Jezierska M, Wełniak M, Berek D (1998) J High Resolut Chromatogr 21:267–281. doi:10.1002/(SICI)1521-4168(19980501)21:5

    Article  CAS  Google Scholar 

  32. Nondek L, Buszewski B, Berek D (1986) J Chromatogr 360:241–246. doi:10.1016/S0021-9673(00)91669-8

    Article  CAS  Google Scholar 

  33. Krupczyńska K, Buszewski B, Jandera P (2004) Anal Chem 76:227A–234A. doi:10.1021/ac041583o

    Google Scholar 

  34. Buszewski B, Suprynowicz Z (1988) Anal Chim Acta 208:263–273. doi:10.1016/S0003-2670(00)80754-0

    Article  CAS  Google Scholar 

  35. Albert K (2003) J Sep Sci 26:215–224. doi:10.1002/chin.200335278

    Article  CAS  Google Scholar 

  36. Maciel GE, Maciel DW, Sindorf DW (1980) J Am Chem Soc 102:7606–7607. doi:10.1021/ja00545a056

    Article  CAS  Google Scholar 

  37. Maciel GE, Maciel DW, Sindorf DW (1983) J Am Chem Soc 105:1487–1493. doi:10.1021/ja00344a013

    Article  Google Scholar 

  38. Buszewski B, Suprynowicz Z, Staszczuk P, Albert K, Pfleinder B, Bayer E (1990) J Chromatogr 499:305–316. doi:10.1016/S0021-9673(00)96981-4

    Article  CAS  Google Scholar 

  39. Zhang L, Rafferty JL, Siepmann JI, Chen B, Schure MR (2006) J Chromatogr A 1126:219–231. doi:10.1016/j.chroma.2006.06.003

    Article  CAS  Google Scholar 

  40. Poplewska I, Antos D (2005) Chem Eng Sci 60:1411–1427. doi:10.1016/j.ces.2004.10.014

    Article  CAS  Google Scholar 

  41. Rafferty JL, Siepmann JI, Schure MR (2008) J Chromatogr A 1204:11–19. doi:10.1016/j.chroma.2008.07.037

    Article  CAS  Google Scholar 

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Acknowledgments

The work was supported by grants OTKA-K75717 and OTKA-NKTH NI-68863, and by Ceepus II scholarship CII-PL-0004-04-0809-M-24435. Financial support from the European Social Fund, the Polish National Budget, the Kujawsko-pomorskie Voivodship Budget (within Sectoral Operational Programme Human Resources) “Krok w przyszlosc” and “Stypendia dla doktorantow 2008/2009-ZPORR” is gratefully acknowledged. The authors thank Akzo Nobel (Bohus, Sweden) for kind donation of the Kromasil 100 silica gel used in this study.

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Authors and Affiliations

  1. Department of Environmental Chemistry and Bioanalysis, Faculty of Chemistry, Nicolaus Copernicus University, Gagarin 7 St, 87-100, Torun, Poland

    Szymon Bocian & Bogusław Buszewski

  2. Department of Analytical and Environmental Chemistry, University of Pécs, Ifjúság útja 6, 7624, Pécs, Hungary

    Péter Vajda & Attila Felinger

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  1. Szymon Bocian
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  2. Péter Vajda
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  3. Attila Felinger
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  4. Bogusław Buszewski
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Correspondence to Bogusław Buszewski.

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Bocian, S., Vajda, P., Felinger, A. et al. Effect of End-Capping and Surface Coverage on the Mechanism of Solvent Adsorption. Chroma 71 (Suppl 1), 5–11 (2010). https://doi.org/10.1365/s10337-010-1522-0

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