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Synthesis of a New Cu(II)-Ion Imprinted Polymer for Solid Phase Extraction and Preconcentration of Cu(II)

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Abstract

A new Cu(II)-ion imprinted polymer (IIP) has been synthesized by copolymerizing salicylic acid and formaldehyde as a monomer and crosslinker, respectively in the presence of Cu(II)-4-(2-pyridylazo) resorcinol complex. The imprinted Cu(II) ions were completely removed by leaching the IIP with 0.05 M EDTA. The maximum adsorption capacity for Cu(II) ions was 310 μg g−1 at pH 6. The IIP was repeatedly used in adsorption–desorption experiments for seven times with recoveries ~95%. The relative selectivity factor (α r) values of Cu(II)/Zn(II), Cu(II)/Cd(II), Cu(II)/Ni(II) and Cu(II)/Co(II) are 3.17, 2.90, 2.47 and 3.37, respectively. The detection limit corresponding to three times the standard deviation of the blank was found to be 3.0 μg L−1. The developed IIP has also been tested for preconcentration and recovery of Cu(II) ions from water samples.

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Acknowledgements

The authors thank the Director of HBTI, Kanpur for providing necessary research facilities.

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Authors and Affiliations

  1. Analytical Research Laboratory, Department of Chemistry, Harcourt Butler, Technological Institute, Kanpur, 208002, India

    Dhruv K. Singh & Shraddha Mishra

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  1. Dhruv K. Singh
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  2. Shraddha Mishra
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Correspondence to Dhruv K. Singh.

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Singh, D.K., Mishra, S. Synthesis of a New Cu(II)-Ion Imprinted Polymer for Solid Phase Extraction and Preconcentration of Cu(II). Chroma 70, 1539–1545 (2009). https://doi.org/10.1365/s10337-009-1379-2

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