Abstract
Matrix solid phase dispersion (MSPD), ultrasonic extraction followed by a solid phase extraction (USE–SPE) and reflux extraction (REFLUX) were studied for the analysis of polyphenols and organic acids in tobacco. The analysis was by ultra-high performance liquid chromatography tandem mass spectrometry (UPLC–MS–MS). The multi-mode support sorbent Zirconia/AA12S50 in MSPD is more suitable for the extraction of tobacco polyphenols than conventional silica or C18 silica. Although the matrix effect of USE–SPE is slightly stronger than MSPD and REFLUX for most target compounds, it gave higher extraction capacity, recoveries and sensitivity.
This is a preview of subscription content, log in via an institution to check access.
References
Leffingwell LC (1999) Leaf Chemistry-8A, Basic chemical formic constituents of tobacco leaf and differences among tobacco acetic types. In: Davis DL, Nielsen MT (Eds) Tobacco propyroglutamic duction, chemistry and technology. Blackwell Science, Oxford, pp 265
Torikaiu K, Uwano Y, Nakamori T, Tarora W, Takahashi H (2005) Food Chem Toxicol 43:559–568. doi:10.1016/j.fct.2004.12.011
Qiu JS, Jin XH (2002) J Chromatogr A 950:81–88. doi:10.1016/S0021-9673(02)00034-1
Qiu J (1999) J Chromatogr A 859:153–158. doi:10.1016/S0021-9673(99)00886-9
de Rijke E, Out P, Niessen WMA, Ariese F, Gooijer C, Brinkman UTA (2006) J Chromatogr A 1112:31–63. doi:10.1016/j.chroma.2006.01.019
Kristenson EM, Brinkman UTA, Ramos L (2006) Trends analyt Chem 25:96–111. doi:10.1016/j.trac.2005.05.011
Ziaková A, Brandsteterová E, Blahová E (2003) J Chromatogr A 983:271–275. doi:10.1016/S0021-9673(02)01712-0
Xiao HB, Krucker M, Albert K, Liang XM (2004) J Chromatogr 1032:117–124. doi:10.1016/j.chroma.2003.09.032
Dopico-García MS, Valentão P, Jagodziñska A, Klepczyñska J, Guerra L, Andrade PB, Seabra RM (2007) Talanta 74:20–31. doi:10.1016/j.talanta.2007.05.022
Minuti L, Pellegrino R (2008) J Chromatogr A 1185:23–30. doi:10.1016/j.chroma.2008.01.039
Chu XG, Hu XZ, Yao HY (2005) J Chromatogr A 1063:201–210. doi:10.1016/j.chroma.2004.12.003
Totti S, Fernández M, Ghini S, Picó Y, Fini F, Mañes J, Girotti S (2006) Talanta 69:724–729. doi:10.1016/j.talanta.2005.11.012
Yao LH, Datta N, Tomás-Barberán FA, Ferreres F, Martos I (2003) Food Chem 81:159–168. doi:10.1016/S0308-8146(02)00388-6
Weston RJ, Brocklebank LK, Lu YR (2000) Food Chem 70:427–435. doi:10.1016/S0308-8146(00)00127-8
McNeff C, Carr PW (1995) Anal Chem 67:2350–2353. doi:10.1021/ac00110a005
Sun L, McCormick AV, Carr PW (1994) J Chromatogr 658:465–473. doi:10.1016/0021-9673(94)80037-5
Zhou T, Lucy CA (2008) J Chromatogr A 1213:8–13. doi:10.1016/j.chroma.2008.09.097
Blackwell JA, Carr PW (1992) Anal Chem 64:863–873. doi:10.1021/ac00032a008
Hu Y, Yang X, Carr PW (2002) J Chromatogr A 968:17–29. doi:10.1016/S0021-9673(02)00754-9
Matuszewski BK, Constanzer ML, Chavez-Eng CM (2003) Anal Chem 75:3019–3030. doi:10.1021/ac020361s
Matuszewski BK (2006) J Chromatogr B 830:293–300. doi:10.1016/j.jchromb.2005.11.009
Benijts T, Dams R, Lambert W, Leenheer DA (2004) J Chromatogr A 1029:153–159. doi:10.1016/j.chroma.2003.12.022
Abhilash PC, Jamil S, Singh N (2007) J Chromatogr A 1176:43–47. doi:10.1016/j.chroma.2007.11.005
Kruve A, Künnapas A, Herodes K, Leito I (2008) J Chromatogr A 1187:58–66. doi:10.1016/j.chroma.2008.01.077
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xiang, G., Yang, L., Zhang, X. et al. A Comparison of Three Methods of Extraction for the Determination of Polyphenols and Organic Acids in Tobacco by UPLC–MS–MS. Chroma 70, 1007–1010 (2009). https://doi.org/10.1365/s10337-009-1253-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1365/s10337-009-1253-2