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Identification and Structural Elucidation of Corrosion Inhibiting Long-Chain N-1-Alkyl-1,3-propanediamines by GC–MS

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Abstract

Gas chromatography–mass spectrometry has been used to identify long-chain (C8–C18) N-1-alkyl-1,3-propanediamines after derivatization with trifluoroacetic anhydride. Electron impact ionization and negative chemical ionization mass spectra of trifluoroacetylated derivatives of the identified N-1-alkyl-1,3-propanediamines are presented for the first time. The corrosion inhibiting long-chain N-1-alkyl-1,3-propanediamines were applied in the preparation and investigation of a new anticorrosive and antifouling formulation for water–steam circuit of energy systems in the power industry. Using the GC–MS data, it was possible to identify residues of the N-1-alkyl-1,3-propanediamines in complex samples of boiler water from the power plant after solid-phase extraction and acylation.

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Acknowledgments

This work was done under the Eureka-research project E!2426 BOILTREAT: New technology for boiler water chemical treatment in the energy industry, 01.01.2001–29.08.2006 [5].

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Authors and Affiliations

  1. Department of Applied Natural Sciences, Hochschule Bonn-Rhein-Sieg, University of Applied Sciences, von-Liebig-Str. 20, 53359, Rheinbach, Germany

    Peter Kusch & Gerd Knupp

  2. Institute of Heavy Organic Synthesis “Blachownia”, ul. Energetyków 9, 47-225, Kędzierzyn-Koźle, Poland

    Marian Kozupa & Maria Majchrzak

Authors
  1. Peter Kusch
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  2. Gerd Knupp
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  3. Marian Kozupa
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  4. Maria Majchrzak
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Correspondence to Peter Kusch.

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Kusch, P., Knupp, G., Kozupa, M. et al. Identification and Structural Elucidation of Corrosion Inhibiting Long-Chain N-1-Alkyl-1,3-propanediamines by GC–MS. Chroma 70, 875–881 (2009). https://doi.org/10.1365/s10337-009-1210-0

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