Abstract
A simple on-column injection system for large volume of liquid samples for the GC-MS determination of traces of PAHs and PCBs has been investigated. A deactivated fused silica capillary 20 m × 0.53 mm I.D. and 2 meters of an HP5 column (0.53 mm,1 μm film thickness) were used as retention gaps. Injection volumes of 80 μL for PAHs and 90 μL for PCBs, allow determination of 5–50 ng L−1 PAHs and 11–44 ng L−1 PCBs in hexane solution with an RSD of < 10%. The method has been used for the determination of PCBs and PAHs in soil sample.
Similar content being viewed by others
References
Korenková E, Matisová E, Slobodník J (2001) Chem Listy 95:528–539
Wells DE, Cowan AA (1983) J Chromatogr 279:209–218
Mol HGJ, Janssen HGM, Cramers CA, Vreuls JJ, Brinkman UAT (1995) J Chromatogr A 703:277–307
Grob JrK, Stoll JM (1986) J High Resolut Chromatogr 9:518–523
Trisciani A, Munari F (1994) J High Resolut Chromatogr 17:452–456
Vreuls JJ, Swen RJJ, Goudriaan VP, Kerkhoff MAT, Jongenotter GA, Brinkman UAT (1996) J Chromatogr A 750:275–286
Hyötyläinen T, Keski-Hyunilä H, Riekkola ML (1997) J Chromatogr 771:360–365
Engewald W, Teske J, Efer J (1999) J Chromatogr A 842:143–161
Grob K, Biedermann M (1996) J Chromatogr A 750:11–23
Müller S, Efer J, Engewald W (1994) Chromatographia 38:694–700
Boderius U, Grob K, Biedermann M (1995) J High Resolut Chromatogr 18:573–578
Teske J, Efer J, Engewald W (1998) Chromatographia 47:35–41
Ramos L, Vreuls JJ, Brinkmann UAT (2000) J Chromatogr A 891:275–286
Hauser B, Popp P, Kleine-Benne E (2002) J Chromatogr A 963:27–36
Grob K (2000) J Chromatogr A 892:407–420
Munari F, Trisciani A, Mapelli G, Trestianu S, Grob Jr K, Colin JM (1985) J High Resolut Chromatogr 8:601–606
Goosens EC, de Jong D, van den Berg JHM, de Jong GJ, Brinkman UAT (1991) J Chromatogr 552:489–500
Kelly GW, Bartle KD (1994) J High Resolut Chromatogr 17:390–397
Beens J, Tijssen R (1995) J Microcol Sep 7:345–354
Vreuls JJ, Louter AJH, Brinkman UAT (1999) J Chromatogr A 856:279–314
Pocurull E, Biedermann M, Grob K (2000) J Chromatogr A 876:135–145
Verma KK, Louter AJH, Jain A, Pocurull E, Vreuls JJ, Brinkman UAT (1997) Chromatographia 44:372–380
standard procedure No. 338/1997 of the law about wastes of the Czech Republic
Acknowledgments.
This work was carried out under grants of GA ČR No. 526/03/1182 and No. 525/04/0011.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Večeřa, Z., Bartošíková, A., Sklenská, J. et al. A Large Volume Injection Procedure for GC-MS Determination of PAHs and PCBs. Chroma 61, 197–200 (2005). https://doi.org/10.1365/s10337-004-0475-6
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1365/s10337-004-0475-6