Skip to main content
SpringerLink
Log in

Polyhydrogenosiloxanes: Powerful Tools for Silanization of Commercial Monolithic Rods

  • Published:
Chromatographia Aims and scope Submit manuscript

Abstract

An in situ method of bonding monolithic rods clad in poly-ether-ether-ketone (PEEK) based on polyhydrogenosiloxane is described. The hydrogenosiloxanes provide good solubility for the substances used in the silanization reaction in aromatic hydrocarbon solvents (non-aggressive to PEEK). The reaction of the Si-H bond with silanol groups produces hydrogen as a non-aggressive byproduct to the environment. This hydrogenosiloxane method is illustrated in the synthesis of monomeric and polymeric acceptor-bonded, monolithic phases. The use of these new bonded monolithic rods for the separation of PAHs in normal phase LC is described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Cabrera K, Wieland G, Lubda D, Nakanishi K, Soga N, Minakuchi H, Unger KK (1998) Trends Anal Chem 17:50

    Article  CAS  Google Scholar 

  • Sinz K, Cabrera K (2001) Inter Labmate 25:17

    Google Scholar 

  • Cabrera K, Lubda D, Eggenweller H.M, Minakuchi H, Nakanishi K (2000) J High Resolut Chromatogr 23:93

    Article  CAS  Google Scholar 

  • Leinweber FC, Lubda D, Cabrera K, Tallarek U (2002) Anal Chem 74:2470

    Article  CAS  PubMed  Google Scholar 

  • Lubda D, Cabrera K, Kraas W, Schaefer G, Cunningham D (2001) LC-GC Int 14:730

    Google Scholar 

  • Thienpont A, Félix G (1993) Chromatographia 37:505

    CAS  Google Scholar 

  • Félix G, Meïouet F, Legrand AP, Hommel H, Ta H (1991) Chromatographia 31:335

    Google Scholar 

  • Félix G, Meïouet F, Legrand A. P, Hommel H, Taïbi H (1991) J Chromatogr Sci 9:457

    Google Scholar 

  • Félix G, Bertrand C (1984) J High Resolution Chromatogr 3:160

    Google Scholar 

  • Holstein W (1981) Chromatographia 14:468

    CAS  Google Scholar 

  • Félix G, Bertrand C (1989) Analusis 17:326

    Google Scholar 

  • Walczak B, Dreux M, Chrétien J-R, Morin-Allory L, Lafosse M, Félix G (1989) J Chromatogr 464:237

    Article  CAS  Google Scholar 

  • Félix G, Thienpont A, Dentraygues P (1992) Chromatographia 34:177

    Google Scholar 

  • Merck technical product information brochure of Chromolith™ Prep

  • Perrin J-L, Poirot N, Liska P, Hanras C, Thienpont A, Félix G (1993) Fat Sci Tech 95:46

    CAS  Google Scholar 

  • Pyell U, Garrigues P, Félix G, Rayez M.-T, Thienpont A, Dentraygues P (1993) J Chromatogr 634:169

    Article  CAS  Google Scholar 

  • Liu M, Thienpont A, Delville M-H, Félix G, Netter C (1994) J High Resol Chromatogr 17:104

    CAS  Google Scholar 

  • Unger K. K, Becker N, Roumeliotis PJ (1976) J Chromatogr 125:115

    Article  CAS  Google Scholar 

  • Cagniant D, Davankov VA, Félix G, Nondek L (1991) Complexation Chromatography. In: Cagniant D (ed) Chromatogr Sci Ser p 57

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie Organique et Matériaux Moléculaires (UMR 6114) Faculté des Sciences de Luminy, 163 Avenue de Luminy, 13 288, Marseille cedex 9, France

    G. Félix

  2. Merck KGaA, Frankfurter Str 250, 64271, Darmstadt, Germany

    K. Cabrera & D. Lubda

  3. Laboratoire de Synthèse, Catalyse et Chiralité (UMR 6516) Faculté des Sciences et Techniques de St Jérome, Avenue Escadrille Normandie-Niémen, 13 397, Marseille cedex 20, France

    J.-M. Roussel & A. M. Siouffi

Authors
  1. G. Félix
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Cabrera
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. Lubda
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J.-M. Roussel
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. M. Siouffi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. Félix.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Félix, G., Cabrera, K., Lubda, D. et al. Polyhydrogenosiloxanes: Powerful Tools for Silanization of Commercial Monolithic Rods. Chromatographia 60, 3–8 (2004). https://doi.org/10.1365/s10337-004-0341-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1365/s10337-004-0341-6

Keywords

Search

Navigation