Abstract
The reversed flow – inverse gas chromatography is a simple and fast technique for the determination of kinetic and energetic parameters, for the degradation diagnosis describing the action of one or two gases simultaneously on a solid surface. The RF-IGC (or RF-GC) method was used to measure directly from experimental data, not only kinetic physicochemical quantities, but also adsorption energies, local monolayer capacities, local adsorption isotherms, the probability density function for the adsorption energies as distributed over the experimental time. This method has been applied by using n-hexane as probe gas and magnesium oxide, chromium oxide, silicon oxide and cadmium sulfide as solid adsorbents. In that way, one can be led to the characterization of heterogeneous surfaces and throw some light to the mechanism of heterogeneous reactions taking place in nature, as the deterioration of monuments and works of art by air pollutants, or in industrial processes.
Similar content being viewed by others
References
Roubani-Kalantzopoulou F, Artemiadi Th, Bassiotis I, Katsanos NA, Plagianakos V (2001) Chromatographia 53:315–320
Bakaev VA, Steele WA (1992) Langmuir 8:1372–1378
Katsanos NA, Arvanitopoulou E, Roubani-Kalantzopoulou F, Kalantzopoulos A (1999) J Phys Chem B 103:1152–1157
Katsanos NA, Iliopoulou E, Roubani-Kalantzopoulou F, Kalogirou E (1999) J Phys Chem B 103:10 228–10 233
Katsanos NA, Rakintzis N, Roubani-Kalantzopoulou F, Arvanitopoulou E, Kalantzopoulos A (1999) J Chromatogr A 845:103–111
Katsanos NA, Thede R, Roubani-Kalantzopoulou F (1998) J Chromatogr A 795:133–184
Kalantzopoulos A, Abatzoglou Ch, Roubani-Kalantzopoulou F (1999) Colloids and Surfaces A 151:377–387
Katsanos NA, Roubani-Kalantzopoulou F, Iliopoulou E, Bassiotis I, Siokos V, Vrahatis MN, Plagianakos VP (2002) Colloids and Surfaces A 201:173–180
Roubani-Kalantzopoulou F, Bassiotis I, Artemiadi Th, Margariti S, Arvanitopoulou E, Katsanos NA (2001) Fresenius Environ Bull 10:98–102
Siokos V, Kapolos J, Roubani-Kalantzopoulou F (2002) Z Phys Chem 216:1311–1321
Birbatakou St, Pagopoulou I, Kalantzopoulos A, Roubani-Kalantzopoulou F (1998) J Chim Phys 95:2180–2198
Metaxa H, Kalogirou E, Roubani-Kalantzopoulou F (1999) Russian J Phys Chem 73:112–116
Katsanos NA, Roubani-Kalantzopoulou F (2000) Adv Chromatogr 40:231–273.
Zahariou-Rakanta H, Kalantzopoulos A, Roubani-Kalantzopoulou F (1997) J Chromatogr A 776:275–282
Kalantzopoulos A, Birbatakou S, Roubani-Kalantzopoulou F (1998) Atmos Environ 32:1811–1816
Roubani-Kalantzopoulou F (1998) J Chromatogr A 806:293–303
Kalogirou E, Bassiotis I, Artemiadi Th, Margariti S, Siokos V, .Roubani-Kalantzopoulou F (2002) J Chromatogr A 969:81–86
Roubani-Kalantzopoulou F, Kalogirou E, Kalantzopoulos A, Metaxa H, Thede R, Katsanos NA, Sotiropoulou V (1997) Chromatographia 46:161–169
Arvantopoulou E, Katsanos NA, Metaxa H, Roubani-Kalantzopoulou F (1994) Atmos Environ 28:2407–2412
Sotiropoulou V, Vassilev GP, Katsanos NA, Metaxa H, Roubani-Kalantzopoulou F (1995) J Chem Soc Faraday Trans 91:485–492
Katsanos NA, Roubani-Kalantzopoulou F (1995) J Chromatogr A 710:191–228
Sotiropoulou V, Katsanos NA, Metaxa H, Roubani-Kalantzopoulou F (1996) Chromatographia 42:441–450
Karagiorgos G, Roubani-Kalantzopoulou F (1998) Z Phys Chem 203:231–246
Jaroniek M, Madey R (1988) In: Physical adsorption on heterogeneous solids, Elsevier, Amsterdam
Hazlet JD, Hsce CC, Wojciechowsky BW (1979) J Chem Soc Faraday Trans 75:602
Rudzinski W, Wojciechowsky BW (1977) J Colloid Polym Sci 255:869, 1086
Rudzinski W, Everett DH (1992) In: Adsorption of Gases on Heterogeneous Surfases, Acadenic Press, London, (a) pp 134–136, (b) 452–456
Sircar SJ (1984) Colloid Interface Sci 101:452
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tylipaki, H., Margariti, S., Bassiotis, I. et al. Time Resolved Chromatographic Study and Characterization of Gas-Solid Interfaces. Chromatographia 59, 197–203 (2004). https://doi.org/10.1365/s10337-003-0137-0
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1365/s10337-003-0137-0