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Preparation and Evaluation of 1,3-alternate 25,27-Bis-[p-nitrobenzyloxy]-26,28-bis-[3-propyloxy]-calix[4]arene-bonded Silica Gel Stationary Phase for LC

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Abstract

A novel 1,3-alternate 25,27-bis-[p-nitrobenzyloxy]-26,28-bis-[3-propyloxy]-calix[4]arene-bonded silica gel stationary phase has been prepared and used for separating various selected analytes by HPLC. The effect of organic modifier and pH of the mobile phase on retention and selectivity were studied using aromatic positional isomers as an example. Application examples have been provided for separation of alkylbenzenes, PAHs, xanthine derivatives, and purine and pyrimidine bases. A selectivity comparison of the novel phase versus CalixBz and Backerbond PhenylEthyl phases has been performed.

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Acknowledgments

The authors gratefully acknowledge financial support for this work from the State Committee for Scientific Research (KBN 3 T09 A, Project No. 138 29).

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Authors and Affiliations

  1. Department of Organic Chemistry, Gdansk University of Technology, Narutowicza St. 11/12, 80-952, Gdansk, Poland

    Katarzyna Jaszczołt & Magdalena Śliwka-Kaszyńska

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  1. Katarzyna Jaszczołt
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  2. Magdalena Śliwka-Kaszyńska
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Correspondence to Magdalena Śliwka-Kaszyńska.

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Jaszczołt, K., Śliwka-Kaszyńska, M. Preparation and Evaluation of 1,3-alternate 25,27-Bis-[p-nitrobenzyloxy]-26,28-bis-[3-propyloxy]-calix[4]arene-bonded Silica Gel Stationary Phase for LC. Chroma 66, 837–845 (2007). https://doi.org/10.1365/s10337-007-0419-z

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