Abstract
The microstructure and aqueous corrosion characteristics of a Ni-Cr-Mo-Si-B high-velocity oxy-fuel (HVOF) coating have been assessed. It has been shown that postprocessing by vacuum fusion has a significant effect on the coating microstructure by increasing the type and concentration of hard phase particles. The principal hard phases in the as-sprayed condition and vacuum-sealed condition are chromium carbides, whereas molybdenum-containing boride phases are also present after vacuum fusion. Vacuumfusion post-treatment eliminates splat boundaries, which can act as sites, where preferential corrosion can occur and, hence, the dominant corrosion mechanisms change. In as-sprayed and vacuum-sealed coatings, localized attack at splat particle boundaries and crevice corrosion dominate, whereas in vacuum-fused coating, the principal mechanism of corrosion is “micropitting” as a result of the hard phase loss.
Similar content being viewed by others
References
H.D. Steffens, M. Gramlich, and K. Nassenstein: Mater. Sci. Forum, 1994, vols. 163–165, pp. 559–72.
K. Haugen, O. Kvernvold, A. Ronold, and R. Sandberg: Wear, 1995, vol. 186, pp. 179–88.
F. Ladru, E. Lugscheider, H. Jungklaus, and C. Herbst: Proc. 1st United Thermal Spray Conf., Indianapolis, IN, Sept. 15–18, 1997, ASM International, Materials Park, OH, 1997, pp. 175–81.
K. Tani and A. Nakahira: Proc. 15th Int. Thermal Spray Conf., Nice, France, May 25–29, 1998, vol. 2, pp. 1097–2002.
G. Barbezat, S. Keller, and G. Wuest: Proc. 1st United Thermal Spray Conf., Indianapolis, IN, Sept. 15–18, 1997, ASM International, Materials Park, OH, 1997, pp. 11–15.
J.P. Huchin: Proc. 15th Int. Thermal Spray Conf., Nice, France, May 25–29, 1998, vol. 2, pp. 925–31.
A. Neville, T. Hodgkiess, and J.T. Dallas: Wear, 1995, vol. 186–187, pp. 497–507.
A. Neville and T. Hodgkiess: Br. Corr. J., 1997, vol. 32 (3), pp. 197–205.
A. Ashary and R.C. Tucker: Surface Coatings Technol., 1991, vol. 49, pp. 78–82.
A. Neville and T. Hodgkiess: Surface Eng., 1996, vol. 12 (4), pp. 303–12.
A. Neville and T. Hodgkiess: Proc. 1st United Thermal Spray Conf., Indianapolis, Sept. 15–18, 1997, ASM International, Materials Park, OH, 1997, pp. 161–66.
A. Neville and T. Hodgkiess: Corr. Sci., 1996, vol. 38 (6), pp. 927–56.
E. Lugscheider, P. Jokiel, V. Messeschmidt, and G. Beckschulte: Inst. Mater., London, 1993, pp. 46–51.
B. Wielage, U. Hofmann, S. Steinhauser, and G. Zimmermann: Surface Eng., 1998, vol. 14 (2), pp. 136–38.
M.C. Garcia-Alonso, M.L. Escudero, V. Lopez, and A. Macias: Iron Steel Inst. Jpn. Int., 1997, vol. 37 (2), pp. 161–68.
K. Sridhar, A.S. Khanna, and M.B. Deshmukh: Proc. 15th Int. Thermal Spray Conf., Nice, France, May 25–29, 1998, vol. 1, pp. 43–48.
S. Shrestha: Ph.D. Thesis, University of Glasgow, Glasgow, United Kingdom, 2000.
S. Tobe: Proc. 15th Int. Thermal Spray Conf., Nice, France, May 25–29, 1998, vol. 1, pp. 3–11.
M.F. Smith, R.C. Dykhuizen, and R.A. Neiser: Proc. 1st United Thermal Spray Conf., Indianapolis, IN, Sept. 15–18, 1997, ASM International, Materials Park, OH, 1997, pp. 885–93.
I. Kretschmer, P. Heimgartner, R. Polak, and P.A. Kammer: Proc. 1st United Thermal Spray Conf., Indianapolis, IN, Sept. 15–18, 1997, ASM International, Materials Park, OH, 1997, pp. 199–202.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shrestha, S., Hodgkiess, T. & Neville, A. The effect of post-treatment of a high-velocity oxy-fuel Ni-Cr-Mo-Si-B coating Part I: Microstructure/corrosion behavior relationships. J Therm Spray Tech 10, 470–479 (2001). https://doi.org/10.1361/105996301770349240
Received:
Issue Date:
DOI: https://doi.org/10.1361/105996301770349240