Skip to main content
Log in

Comparison of precipitate behaviors in ultra-low carbon, titanium-stabilized interstitial free steel sheets under different annealing processes

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

Ultra-low carbon, titanium-stabilized interstitial free (ULC Ti-IF) steel sheets are widely used in the automobile industry because of excellent deep drawability. The annealing process is critical to their final property, and there are two different annealing processes used in industrial production of interstitial free (IF) steel sheets, namely batch annealing and continuous annealing. In this study, precipitation behaviors of titanium IF steels in the two annealing processes were investigated. Among the most common precipitates in titanium IF steels, that is, TiN, TiS, Ti4(CS)2, and TiC, the size and dispersion of TiN, TiS, and Ti4(CS)2 remained almost unchanged after either annealing process. Conversely, the average size of a TiC particle increased substantially after both annealing processes, while TiC after continuous annealing was larger than that after batch annealing due to the higher heating temperature of continuous annealing. Two new particles, FeTiP and (Ti, Mn)S, were also observed in the batch annealing process but not in continuous annealing. The structure of FeTiP and (Ti, Mn)S were studied, and furthermore the evolution of FeTiP precipitation was found to be closely related to recrystallization in batch annealing. Finally, the interrelation among processing parameters, precipitation behaviors, and final property was studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S.V. Subramanian and J. Gao, Effect of Precipitate Size and Dispersion on Lankford Values of Titanium Stabilized Interstitial-Free Steels, Proceedings International Forum for Physical Metallurgy of IF Steels (Tokyo, Japan), Iron and Steel Institute of Japan, 10–11 May 1994, p 53–56

  2. G. Tither, C.I. Garcia, M. Hua, and A.J. DeArdo, Precipitation Behavior and Solute Effects in Interstitial-Free Steels, Proceedings International Forum for Physical Metallurgy of IF Steels (Tokyo, Japan), Iron and Steel Institute of Japan, 10–11 May 1994, p 293–322

  3. A. Belyansky, V. Kapnin, and Y. Larin, Dispersed Particles in IF-Steels and Their Transformation in the Production Process, Proceedings International Forum for Physical Metallurgy of IF Steels (Tokyo, Japan), Iron and Steel Institute of Japan, 10–11 May 1994, p 289–292

  4. S. Akamatsu, M. Hasebe, T. Senuma, Y. Matsumura, and O. Akisue, Thermodynamic Calculation of Solute Carbon and Nitrogen in Nb and Ti Added Extra-Low Carbon Steels, ISIJ Int., Vol 34 (No. 1), 1994, p 9–16

    CAS  Google Scholar 

  5. S. Satoh, M. Morita, and O. Hashimoto, Carbide Dissolution in Interstitial Free Steels during Continuous Annealing, Proceedings Developments in the Annealing of Sheet Steels, The Minerals, Metals & Materials Society, 1992, p 177–188

  6. R.K. Ray, J.J. Jonas, and R.E. Hook, Cold Rolling and Annealing Textures in Low Carbon and Extra Low Carbon Steels, Int. Mater. Rev., Vol 39 (No. 4), 1994

  7. A. Okamoto and N. Mizui, Texture Formation in Ultra-Low-Carbon Titanium Added Cold-Rolled Sheet Steels Containing Manganese and Phosphorus, Proceedings Metallurgy of Vacuum-Degassed Steel Products (Indianapolis, IN), The Minerals, Metals & Materials Society, 1990, p 161–180

  8. K. Ushioda, N. Yoshinaga, and O. Akisue, Influences of Manganese on Recrystallization Behavior and Annealing Texture Formation of Ultra-Low-Carbon and Low-Carbon Steels, ISIJ Int., Vol 34 (No. 1), 1995, p 85–91

    Google Scholar 

  9. Z. Wang, “Effect of Metallurgical Factors on the Properties of High Strength IF Steels,” Ph.D. thesis, University of Science and Technology Beijing, 1994 (in Chinese)

  10. S. Satoh, T. Obara, and K. Tsunoyama, Effect of Precipitate Dispersion on the Recrystallization Texture of Niobium-Added Extra-Low Carbon Cold-Rolled Steel Sheet, Trans. Iron Steel Inst. Jpn., Vol 26 (No. 8), 1986, p 737–744

    CAS  Google Scholar 

  11. J. Shi, “Study on the Optimization of Batch Annealing Process and Recrystallization Texture Evolution for IF Steels,” Ph.D. thesis, University of Science and Technology Beijing, Jan 1998 (in Chinese)

  12. P. Hellman and M. Hillert, Effect of Second-Phase Particles on Grain Growth, Scand. J. Metall., Vol 4 (No. 5), 1975, p 211–219

    CAS  Google Scholar 

  13. M. Hillert, Zener’s Pinning Effect—Role of Dispersed Particles on Grain Size Control, Proceedings THERMEC ’88 (Tokyo, Japan), Vol 1, The Iron and Steel Institute of Japan, 6–10 June 1988, p 30–38

    Google Scholar 

  14. N. Louat, The Resistance to Normal Grain Growth From a Dispersion of Spherical Particles, Acta Metall., Vol 30 (No. 7), 1982, p 1291–1294

    Article  Google Scholar 

  15. K. Matsudo, T. Shimomura, K. Osawa, M. Sakoh, and S. Ono, Effect of Phosphorus on the Deep Drawability of Cold Rolled Steel Sheets, Proceedings 6th International Conference on Texture of Materials (Tokyo, Japan), Vol 2, Iron and Steel Institute of Japan, 1982, p 759

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shi, J., Wang, X. Comparison of precipitate behaviors in ultra-low carbon, titanium-stabilized interstitial free steel sheets under different annealing processes. J. of Materi Eng and Perform 8, 641–648 (1999). https://doi.org/10.1361/105994999770346396

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1361/105994999770346396

Keywords

Navigation