Abstract
The crystallization behavior of melt-spun A85Y10Fe5−xNx (x=0, 2.5, 5) amorphous alloys has been investigated by a combination of differential scanning calorimetry (DSC) and x-ray diffractometry (XRD). XRD traces of these alloys consisted of a single broad peak corresponding to fully amorphous structure. Continuous DSC results showed that, the first crystallization peak temperature of Al85Y10Fe5 amorphous alloy was about 60 K higher than that of Al85Y10Ni5. The activation energies for the first crystallization peak increased from 210 kJ/mol for Al85Y10Ni5 to 280 for Al85Y10Fe5. These results indicate that 5 at.% substitutions Ni by Fe increases the stability of the amorphous phase.
This is a preview of subscription content, access via your institution.
References
R. Sabet-Sharghi, Z. Altounian, and W.B. Muir: “Formation, Structure and Crystallization of Al-Rich Metallic Glasses,” J. Appl. Phys., 1994, 75(9), pp. 4438–41.
A.K. Gangopadhyay and K.F. Kelton: “Effect of Rare-Earth Atomic Radius on the Devitrification of Al88RE8Ni4 Amorphous Alloys,” Phil. Mag. A, 2000, 80(5), pp. 1193–206.
W. Lui and U. Köster: “Decomposition of the Icosahedral Phase in Al-Cu-Fe Alloys,” Mater. Sci. Eng. A, 1991, 133, pp. 388–92.
S.J. Hong, P.J. Warren, and B.S. Chun: “Nanocrystallization Behaviour of Al-Y-Ni With Cu Additions,” Mater. Sci. Eng. A, 2001, 304–306, pp. 362–66.
A. Inoue, K. Ohtera, A.P. Tsai, and T. Masumoto: “Aluminum-Based Amorphous Alloys With Tensile Strength Above 980 MPa (100 kg/mm2),” Jap. J. Appl. Phys., 1988, 27, pp. L479–82.
Y.H. Kim, A. Inoue, and T. Masumoto: “Increase in Mechanical Strength of Al-Y-Ni Amorphous Alloys by Dispersion of Nanoscale fcc-Al Particles,” Mater. Trans. JIM., 1991, 32, pp. 331–38.
Y.H. Kim, A. Inoue, and T. Masumoto: “Ultrahigh Tensile Strengths of Al88Y2Ni9M1 (M = Mn or Fe) Amorphous Alloys Containing Finely Dispersed fcc-Al Particles,” Mater. Trans. JIM., 1990, 31, pp. 747–49.
Y.H. Kim, A. Inoue, and T. Masumoto: “Ultrahigh Mechanical Strengths of Al88Y2Ni10−xMx M = Mn, Fe, Co Amorphous Alloys Containing Nanoscale fcc-Al Particles,” Mater. Trans. JIM., 1991, 32, pp. 599–608.
M. Gögebakan: “Amorphous and Nanocrystalline Al-Based Alloys,” Ph.D. Thesis, University of Oxford, Oxford, UK, 1998.
A. Inoue, N. Matsumoto, and T. Masumoto: “Al-Y-Ni-Co Amorphous Alloys With High Mechanical Strengths, Wide Supercooled Liquid Region and Large Glass-Forming Capacity,” Mater. Trans. JIM., 1990, 31, pp. 493–500.
H.E. Kissinger: “Reaction Kinetics in Differential Thermal Analysis,” Anal. Chem., 1957, 29, pp. 1702–06.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gögebakan, M. Crystallization studies of Al85Y10Fe5−xNix (x = 0, 2.5, 5) alloys. J. of Materi Eng and Perform 12, 521–523 (2003). https://doi.org/10.1361/105994903100277166
Received:
Issue Date:
DOI: https://doi.org/10.1361/105994903100277166
Keywords
- activation energy
- AlYFeNi alloy
- crystallization