Thermodynamic optimization of the AgCl-KCl and BaCl2-LiCl systems
Basic And Applied Research
Received:
Revised:
- 139 Downloads
- 3 Citations
Abstract
The values of the thermodynamic properties of the liquid phase of the AgCl-KCl and BaCl2-LiCl systems were optimized taking into account all the available experimental thermochemical and phase diagram information from the literature. Each liquid was described as a substitutional solution, and a Redlich-Kister formalism was used for the excess Gibbs energy.
Keywords
Phase Diagram Gibbs Energy LiCl AgCl BaCl
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Preview
Unable to display preview. Download preview PDF.
References
- 1908Zem:.S. Zemczuzny: “Die Schmelzen von Kaliumchlorid mit Silberchlorid und den Kaliumchromaten,” Z. Anorg. Chem., 1908, 57, pp. 267–77 (in German).CrossRefGoogle Scholar
- 1948Red:.O. Redlich and A.T. Kister: “The Algebraic Representation of Thermodynamic Properties and the Classification of Solids,” Ind. Eng. Chem., 1948, 40, pp. 345–48.CrossRefGoogle Scholar
- 1953Ber:.A.G. Bergman and E.I. Banashek: “Reciprocal System of Lithium and Barium Fluorides and Chlorides,” Izv. Sektora Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim. Akad. Nauk. SSSR, 1953, 23, pp. 201–21.Google Scholar
- 1955Gro:.S.P. Gromakov and L.M. Gromakova: “Several Rules for the Plotting of Phase Diagrams of Binary Systems,” Zurnal Fiziceskoj Himii, 1955, 29(4), pp. 745–49 (in Russian).Google Scholar
- 1956Ste:.K.H. Stern: “Electrode Potentials in Fused Systems. A Study of the AgCl-KCl System,” J. Phys. Chem., 1956, 60, pp. 679–81.CrossRefGoogle Scholar
- 1957Mur:.I.G. Murgulescu and S. Sternberg: “Thermodynamische Eigenschaften Binarer Salzgemische im Geschmolzenen Zustand,” Revue de Chimie Roumaine, 1957, 2(2), pp. 251–66 (in German).Google Scholar
- 1958Mur:.I.G. Murgulescu and S. Sternberg: “Thermodynamische Eigenschaften Binarer Salzgemische im Geschmolzenen Zustand,” Revue de Chimie Roumaine, 1958, 3, pp. 55–67 (in German).Google Scholar
- 1962Mur:.I.G. Murgulescu and S. Sternberg: “Uber die Thermodynamischen Uberschussgrossen Binarer Geschmolzener Salzgemische,” Zh. Phys. Chem. (Leipzig), 1962, 219, pp. 114–33.Google Scholar
- 1963Zak:.M.A. Zakharchenko and S.M. Aslanov: “The Ba, Li, Na // Cl Ternary System.” Russ. J. Inorg. Chem., 1963, 8(6), pp. 797–98.Google Scholar
- 1965Her:.L.S. Hersh and O.J. Kleppa: “Enthalpies of Mixing in Some Binary Halide Mixtures,” J. Chem. Physics, 1965, 42(4), pp. 1309–22.CrossRefADSGoogle Scholar
- 1967Bab:.R. Baboian and S.N. Flengas: “High Temperature Solution Calorimetry,” Can. J. Chem., 1967, 45, pp. 813–20.CrossRefGoogle Scholar
- 1968Gui:.J. Guion, M. Blander, D. Hengstenberg, and K. Hagemark: “Thermodynamic Treatment and Electromotive Force Measurements of the Ternary Molten Salt Systems Silver Chloride-Sodium Chloride-Cesium Chloride,” J. Phys. Chem., 1968, 72(6), pp. 2086–94.CrossRefGoogle Scholar
- 1970Pel:.A.D. Pelton and S.N. Flengas: “Thermodynamics of Molten Silver Chloride-Alkali Chloride Solutions by Electomotive Force Measurements,” J. Electrochem. Soc., 1970, 117(9), pp. 1130–40.CrossRefGoogle Scholar
- 1971Zak:.M.N. Zakhvalinskii, V.G. Romanovskaya, V.F. Tkachenko, and N.A. Finkel’shtein: “The 2Li, Ba // 2Cl, SO4 Ternary Reciprocal System,” Russ. J. Inorg. Chem., 1971, 16(12), 1753–55.Google Scholar
- 1974Dan:.P. Dantzer and O.J. Kleppa: “Enthalpies of Mixing in the Liquid Silver Halide-Alkali Halide Mixtures,” J. Chim. Phys., 1974, 71(2), pp. 216–22.Google Scholar
- 1974Emo:.H.H. Emons: “Untersuchungen an Binaren Ladungsunsymmetrischen Salzschmelzen aus Erdalkalimetall- und Alkalimetallchloriden,” Chem. Zvesti, 1974, 28(4), pp. 447–62.Google Scholar
- 1975Emo:.H.H. Emons, G. Brautigam, and R. Scheunpflug: “EMK-Messungen in Binaren Ladungsunsymmetrischen Salzschmelzen aus Bariumchlorid und Alkalimetallchloriden,” Z. Anorg. Allgem. Chem, 1975, 411, pp. 118–24.CrossRefGoogle Scholar
- 1975Sto:.A.V. Storonkin, I.V. Vasilkova, and A.A. Tarasov: “Phase Diagram of the Sodium Chloride-Potassium Chloride-Silver Chloride System,” Vestnik. Leningrad Skogo Universiteta, 1975, 10, pp. 87–92 (in Russian).Google Scholar
- 1977Luk:.H.L. Lukas, E.Th. Henig, and B. Zimmermann: “Optimization of Phase Diagrams by a Lead-Square Method Using Simultaneously Different Types of Data,” Calphad, 1977, 1(2), pp. 225–36.CrossRefGoogle Scholar
- 1978Mos:.Z. Moser, M. Kucharski, and K. Rzyman: “Activities and Surface Tension of Liquid AgCl-KCl Solutions,” J. Electrochem. Soc., 1978, 125, pp. 692–97.CrossRefGoogle Scholar
- 1979Kra:.I.F. Kravchuk: “Refinement of the Equilibrium Diagrams of the LiCl-MCl2 Systems (M=Mg, Ca, Sr, Ba, Mn) by Zone Melting,” Russian J. Inorg. Chem., 1979, 24(10), pp. 1535–38.Google Scholar
- 1980Vyt:.R. Vytlacil and A. Neckel: “Determination of the Thermodynamic Excess Functions G, H, S Excess of the Liquid Ternary System AgCl-LiCl-KCl by Means of EMF-Measurements,” Monatshefte für Chemie, 1980, 111, pp. 331–46.CrossRefGoogle Scholar
- 1981Jan:.G.J. Janz and R.P.T. Tomkins: “Physical Properties Data Compilations Relevant to Energy Storage,” NSRDS-NBS 61, Part 4, US Govt, Washington DC, 1981.Google Scholar
- 1985Tum:.P.J. Tumidajski and S.N. Flengas: “Thermodynamic Properties of the Dilute Solutions of Silver Chloride and Aluminum Trichloride in Alkali Chlorides by Electromotive Force Measurements,” Can. J. Chem., 1985, 63(5), pp. 1080–88.CrossRefGoogle Scholar
- 1990Sun:.B. Sundman: “Review of Alloy Modelling,” Ann. Fisica, Serie B, 1990, 86, pp. 69–82.Google Scholar
- 2002Che:.B. Cheynet: “ThermoSuite,” Calphad, 2002, 26(2), pp. 167–74.CrossRefGoogle Scholar
Copyright information
© ASM International 2003