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A thermodynamic analysis of the Mg-Si system

  • Xin-Yan Yan
  • Y. A. Chang
  • F. Zhang
Basic And Applied Research

Abstract

A thermodynamic description of the Mg-Si binary system was obtained. The term “thermodynamic description” means that a set of thermodynamic model parameters was obtained, on the basis of which the Mg-Si phase diagram as well as any of the single-phase thermodynamic properties can be calculated. The model parameters were obtained by optimization with experimental phase equilibrium and thermodynamic data available in the literature. The present description has fewer model parameters than the previous ones published in the literature, while the agreement of the model-calculated thermodynamic properties and phase boundaries with the experimental data is as good or better than those of early descriptions. The computer program used to optimize the model parameters was WinPhaD, developed by CompuTherm LLC.

Keywords

Enthalpy Phase Diagram Gibbs Energy Phase Equilibrium Thermodynamic Description 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1909Leb:.
    P. Lebeau and R. Bossuet: Rev. Métall., 1901, vol. 6, pp. 273–78.Google Scholar
  2. 1909Vog:.
    R. Vogel: Z. Anorg. Chem., 1909, vol. 61, pp. 46–63.CrossRefGoogle Scholar
  3. 1926Woh:.
    L. Wöler and O. Schliephake: Z. Anorg. Chem., 1926, vol. 151, pp. 1–20.CrossRefGoogle Scholar
  4. 1927Sch:.
    W. Schmidt: Z. Metallkd., 1927, vol. 19, pp. 452–55.Google Scholar
  5. 1935Elc:.
    E. Elchardus and P. Laffitte: C.R. Hebd. Séances Acad. Sci., 1935, vol. 200, pp. 1938–40.Google Scholar
  6. 1935Saw:.
    H. Sawamoto: Suiyokwai-Shi, 1935, vol. 8, pp. 713–27.Google Scholar
  7. 1937Got:.
    M. Goto, M. Nito, and H. Asada: Rep. Aeronaut. Res. Inst. Tokyo Univ., 1937, vol. 12, pp. 163–318.Google Scholar
  8. 1940Ray:.
    G.V. Raynor: J. Inst. Met., 1940, vol. 66, pp. 403–26.Google Scholar
  9. 1940Kle:.
    W. Klemm and H. Westlinning: Z. Anorg. Chem., 1940, vol. 245, pp. 365–80.Google Scholar
  10. 1949Kub:.
    O. Kubaschewski and H. Villa: Z. Electrochem., 1949, vol. 53, pp. 32–40.Google Scholar
  11. 1959Yue:.
    A.S. Yue: Trans. TMS-AIME, 1959, vol. 215, pp. 870–71.Google Scholar
  12. 1962Cau:.
    H.J. Caulfield: Ph.D. Thesis, Iowa State University, Ames, IA, 1962, quoted in [1967Eld].Google Scholar
  13. 1962Grj:.
    K. Grjotheim, O. Herstad, S. Petrucci, R. Skarbo, and J. Toguri: Rev. De Chimie, Acad. Rep. Populaire Roumanie, 1962, vol. 7, pp. 217–23.Google Scholar
  14. 1964Luk:.
    G.M. Lukashenko and V.N. Eremenko: Russ. J. Inorg. Chem., 1964, vol. 9 (10), pp. 1243–44.Google Scholar
  15. 1964Sry:.
    I.T. Sryvalin, O.A. Esin, and B.M. Lepinskikh: Russ. J. Phys. Chem., 1964, vol. 38 (5), pp. 637–41.Google Scholar
  16. 1965Man:.
    W. Mannchen and G. Jacobi: Z. Naturforsch., 1965, vol. 206, pp. 178–79.Google Scholar
  17. 1966Bea:.
    P. Beardmore, B.W. Howlett, B.D. Lichter, and M.B. Bever: Trans. TMS-AIME, 1966, vol. 236, pp. 102–08.Google Scholar
  18. 1966Cau:.
    H.J. Caulfield and D.E. Hudson: Solid State Communications, Pergamon Press Ltd., New York, 1966, vol. 4, pp. 299–301.Google Scholar
  19. 1967Eld:.
    J.M. Eldridge, E. Miller, and K.L. Komarek: Trans. TMS-AIME, 1967, vol. 239, pp. 775–81.Google Scholar
  20. 1968Gef:.
    R. Geffken and E. Miller: Trans. TMS-AIME, 1968, vol. 242, 2323–28.Google Scholar
  21. 1971Stu:.
    D.R. Stull and H. Prophet: JANAF Thermodynamical Tables, 2nd ed., Washington, U.S. National Bureau of Standards, NSDRS-NBS37. 1971.Google Scholar
  22. 1973Cha:.
    T.-G. Chart: High Temp. High Pressure, 1973, vol. 5, pp. 241–52.Google Scholar
  23. 1973Bar:.
    I. Barin and O. Knacke: Thermochemical Properties of Inorganic Substances, Springer-Verlag, New York, NY, 1973.Google Scholar
  24. 1977Bar:.
    I. Barin, O. Knacke, and O. Kubaschewski: Thermochemical Properties of Inorganic Substances, Supplement, Springer-Verlag, New York, NY, 1977.Google Scholar
  25. 1977Sch:.
    E. Schurmann and A. Fischer: Giessereiforschung, 1977, vol. 29, pp. 111–13.Google Scholar
  26. 1979Kub:.
    O. Kubaschewski and C.B. Alcock: Metallurgical Thermochemistry, 5th ed., Pergamon Press, New York, NY, 1979.Google Scholar
  27. 1981Dor:.
    P. Dorner, H. Krieg, H.L. Lukas, R. Muller, and G. Petzow: CALPHAD, 1981, vol. 1, pp. 41–55.CrossRefGoogle Scholar
  28. 1981Rao:.
    Y.K. Rao and G.R. Belton: Chemical Metallurgy—A Tribute to Carl Wagner, N.A. Gokcen, ed., TMS-AIME, Warrendale, PA, 1981, pp. 75–96.Google Scholar
  29. 1986Lud:.
    D. Lüdecke: Z. Metallkd., 1986, vol. 77, pp. 278–83.Google Scholar
  30. 1988Nay:.
    A.A. Nayeb-Hashemi and J.B. Clark: Phase Diagrams of Binary Magnesium Alloys, ASM International, Meterials Park, OH, 1988, pp. 280–88.Google Scholar
  31. 1991Din:.
    A.T. Dinsdale: CALPHAD, 1991, vol. 15, pp. 317–425.CrossRefGoogle Scholar
  32. 1992Cha:.
    N. Chakraborti and H.-L. Lukas: CALPHAD, 1992, vol. 16, pp. 79–86.CrossRefGoogle Scholar
  33. 1994Luk:.
    H.L. Lukas: in Thermochemical Database for Light Metal Alloys, I. Ansara, ed., European Commission, rue de la Loi 200 (SDME 1/44), B-1049 Brussels, 1994, p. 12.Google Scholar
  34. 1997Cha:.
    Y.A. Chang and S.-L. Chen: in Advanced Physical Chemistry for Process Metallurgy, Nobuo Sano, Wei-Kao Lu, and Paul V. Riboud, eds., Academic Press, New York, NY, 1997, pp. 5–43.Google Scholar
  35. 1997Feu:.
    H. Feufel, T. Gödecke, H.L. Lukas, and F. Sommer: Alloys Compounds, 1997, vol. 247, pp. 31–42.CrossRefGoogle Scholar
  36. 1999Win:.
    WinPhaD(Binary)—A Computer Software for Phase Diagram Calculation, Version 1, CompuTherm, LLC, Madison, WI, 1999.Google Scholar

Copyright information

© ASM International 2000

Authors and Affiliations

  • Xin-Yan Yan
    • 1
  • Y. A. Chang
    • 1
  • F. Zhang
    • 2
  1. 1.Department of Materials Science and EngineeringUniversity of Wisconsin-MadisonMadison
  2. 2.CompuTherm LLCMadison

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