Abstract
Gap and InP nanocrystals were synthesized from Na3P and GaCI3 at low temperature (80–100°C) and atmospheric pressure. The samples were characterized by XRD and TEM measurements. The surface reactivity of Gap nanocrystals was studied by heating in N2. The weight of the nanocrystals increased at the temperature between 370°C and 480°C. It can be concluded that N, molecule was absorbed and reactivated on the surface of Gap nanocrystals. Keywords: gallium phosphide, indium phosphide, nanocrystal, surface reactivity.
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Brus, L. E., Electron-electron and electron-hole interactions in small semiconductor crystallites: The size dependence of the lower excited electronic state, J. Chem. Phys., 1984, 80: 403–4409,
Henglein, A., Small-particle research: Physicochemical properties of extremely small colloidal metal and semiconductor particles, Chem. Rev., 1989, 89: 1861–1873.
Rama Krishna, M. V., Friesner, R. A., Quantum confinement effects in semiconductor clusters, J. Chem. Phys., 1991, 95: 8309–8322.
Kortan, A. R., Hull, R., Opila, R. L. et a1., Nucleation and growth of CdSe on ZnS quantum crystallite seeds, and vice versa, in inverse micelle media, J. Am. Chem. Soc., 1990,112: 1327–1332.
Colin, V.L., Schlamp, M. C., Alivisatos, A. P., Light-emitting diodes made from cadmium selenide nanocrystals and a semiconducting polymer, Nature, 1994,370: 354–357.
Huang Jinman, Yang Yi, Xue Shanhua et al., Photoluminescence and electroluminescence of ZnS: Cu nanocrystals in polymeric networks, Appl.Phys. Lett., 1997,70: 2335–2337.
Greenham, N. C., Peng Xiaogang, Alivisatos, A. P., Charge separation and transport in conjugated- polymer/ semiconductornanocrystal composites studied by photoluminescence quenching and photoconductivity, Phys. Rev. B., 1996, 54: 17628–17638.
Narayan, K. S., Manoj, A. G., Nanda, J. et al., Dual function hybrid polymer-nanoparticle device, Appl. Phys. Lett., 1999, 74: 871–874.
Mac Dougall, J. E., Eckert, H., Stucky, G. D. et a1., Synthesis and characterization of 111-V semiconductor clusters: Gap in Zeolite Y, J. Am. Chem. Soc., 1989, 111: 8006–8007.
Olshavsky, M. A., Goldstein, A. N., Alivisatos, A. P., Organometallic synthesis of GaAs crystallites exhibiting quantum confinement, J. Am. Chem. Soc., 1990, 112: 9438–9439.
Xie Yi, Qian Yitai, Wang Wenzhong et a1., A benzene-thermal synthetic route to nanocrystalline GaN, Science, 1996, 272: 1926–1927.
Wells, R. L., Self, M. F., Mcphail, A. T. et a1., Synthesis, characterization and thermal decomposition of [Cl2GaP(SiMe2)2]2 a potential precursor to gallium phosphide, Organometallics, 1993, 12: 2832–2834.
Aubuchon, S. R., Mcphail, A. T., Wells, R. L. et al., Preparation, characterization and facile thermolysis of [X2GaP(SiMe2)2]2 (X = Br, I) and (C13Ga2P)n: New precursors to nanocrystalline gallium phosphide, Chem. Mater., 1994, 6: 82–86.
Gao Shanmin, Cui Deliang, Huang Baibiao et al., Study on the factors affecting the particles size of Gap nanocrystalline materials, J. Crystal Growth., 1998,192: 89–92.
Cui, D. L., Pan, J. Q., Zhang, Z. C. et al., The stability and surface reactivity of Gallium phosphide nanocrystals, Ehgress in Crystal Growth and Characterization of Materials, 2000, 40: 145–151.
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Pan, J., Huang, B., Cui, D. et al. Synthesis and surface reactivity of phosphide nanocrystals. Sci. China Ser. A-Math. 45, 661–665 (2002). https://doi.org/10.1360/02ys9072
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DOI: https://doi.org/10.1360/02ys9072