Abstract
Fougerite (IMA 2003-057) was accepted by the Commission on New Minerals and Mineral Names of the International Mineralogical Association (IMA) in 2004 as a new mineral to represent the green rust (GR) family. The data on which it was approved, however, are inconsistent. X-ray diffraction patterns from the Fouge`res soils contain no peaks that could meaningfully be attributed to a GR phase. The sequential dissolution procedure used to identify GR in the soils was not rigorously tested for selectivity. If indeed it is selective, the results indicate the presence of 40–78% Fe in minerals other than GR. Other Fe-bearing phases were not included in the interpretation of the spectroscopy data that were presented. The data are consistent with the presence of Fe-bearing clays and other silicate minerals. In light of the ambiguous and conflicting data, we recommend that the case for fougerite as a mineral be re-evaluated by the IMA.
References
Abdelmoula, M., Trolard, F., Bourrié, G., and Génin, J.-M.R. (1997) Evidence for the Fe(II)-Fe(III) Green Rust Fougerite mineral occurence in the hydromorphic soil and its transformation with depth. Hyperfine Interactions 112, 235–238.
Acebal, S.G., Mijovilovich, A., Rueda, E.H., Aguirre, M.E., and Saragovi, C. (2000) Iron-oxide mineralogy of a Mollisol from Argentina: A study by selective-dissolution techniques, X-ray diffraction, and Mössbauerspectroscopy. Clays and Clay Minerals, 48, 322–330.
Acebal, S.G., Aguirre, M.E., Santamaría, R.M., Mijovilovich, A., Petrick, S., and Saragovi, C. (2003) Selective dissolution techniques, X-ray diffraction and Mössbauerspectroscopy studies of forms of Fe in particle-size fractions of an Entic Haplustoll. Hyperfine Interactions, V148-149, 3–12.
Borggaard, O.K. (1988) Phase identification by selective dissolution techniques. Pp. 351–396 in: Iron in Soils and Clay Minerals (J.W. Stucki, B.A. Goodman, and U. Schwertmann, editors). D. Reidel Publishing Company, Dordrecht, The Netherlands.
Bourrié, G., Trolard, F., Genin, J.-M.R., Jaffrezic, A., Maitre, V., and Abdelmoula, M. (1999) Iron control by equilibria between hydroxy-Green Rusts and solutions in hydromorphic soils. Geochimica et Cosmochimica Acta, 63, 3417–3427.
Brigatti, M.F., Lugli, C., Cibin, G., Marcelli, A., Giuli, G., Paris, E., Mottana, A., and Wu, Z. (2000) Reduction and sorption of chromium by Fe(II)-bearing phyllosilicates: chemical treatments and X-ray absorption spectroscopy (XAS) studies. Clays and Clay Minerals, 48, 272–281.
Burke, E.A.J. and Ferraris, G. (2004) New minerals approved in 2003 and nomenclature modifications approved in 2003 by the Commission on New Minerals and Mineral Names, International Mineralogical Association. American Mineralogist, 29, 1566–1573.
Cardile, C., Childs, C., and Whitton, J. (1987) The effect of citrate bicarbonate dithionite treatment on standard and soil smectites as evidenced by 57Fe Mössbauers pectroscopy. Australian Journal of Soil Research, 25, 145–154.
Christiansen, B.C., Balic-Zunic, T., Dideriksen, K., and Stipp, S.L.S. (2009a) Identification of Green Rust in groundwater. Environmental Science and Technology, 43, 3436–3441.
Christiansen, B.C., Balic-Zunic, T., Petit, P.O., Frandsen, C., Mørup, S., Geckeis, H., Katerinopoulou, A., and Stipp, S.L.S. (2009b) Composition and structure of an ironbearing, layered double hydroxide (LDH)-Green rust sodium sulphate. Geochimica et Cosmochimica Acta, 73, 3579–3592.
Cornell, R.M. and Schwertmann, U. (2003) The Iron Oxides. Structure, Properties, Reactions, Occurrences and Uses. Wiley-VCN Verlag GmbH & Co, Weinheim, Germany.
Dainyak, L., Drits, V., and Lindgreen, H. (2004) Computer simulation of octahedral cation distribution and interpretation of the Mössbauer Fe2+ components in dioctahedral trans-vacant micas. European Journal of Mineralogy, 16, 451–468.
Diamant, A., Pasternak, M., and Banin, A. (1982) Characterization of adsorbed iron in montmorillonite by Mössbauerspectroscopy. Clays and Clay Minerals, 30, 63–66.
Drissi, H., Refait, P., Abdelmoula, M., and Génin, J.-M.R. (1995) The preparation and thermodynamic properties of Fe(II)-Fe(III) hydroxide-carbonate (Green Rust 1); Pourbaix diagram of iron in carbonate-containing aqueous media. Corrosion Science, 37, 2025–2041.
Ekosse, G., (2000) The Makoro kaolin deposit, southeastern Botswana: its genesis and possible industrial applications. Applied Clay Science 16, 301–320.
Feder, F., Trolard, F., Klingelhofer, G., and Bourrié, G. (2005) In situ Mössbauer spectroscopy: Evidence for green rust (fougerite) in a gleysol and its mineralogical transformations with time and depth. Geochimica et Cosmochimica Acta, 69, 4463–4483.
Ferrow, E.A. (2002) Experimental weathering of biotite, muscovite and vermiculite: a Mössbauerspectroscopy study. European Journal of Mineralogy, 14, 85–95.
Frost, R.L. (1995) Fourier transform Raman spectroscopy of kaolinite, dickite and halloysite. Clays and Clay Minerals, 43, 191–195.
Frost, R.L. (1997) The structure of the kaolinite minerals — a FT-Raman study. Clay Minerals, 32, 65–77.
Génin, J.-M.R., Olowe, A.A., Refait, P., and Simon, L. (1996) On the stoichiometry and Pourbaix diagram of Fe(II)-Fe(III) hydroxyl-sulphate or sulphate containing Green Rust. 2: an electrochemical and Mössbauerspectroscopy study. Corrosion Science, 38, 1751–1762.
Génin, J.-M.R., Bourrié, G., Trolard, F., Abdelmoula, M., Jaffrezic, A., Refait, P., Maitre, V., and Herbillon, A. (1998) Thermodynamic equilibria in aqueous suspensions of synthetic and natural Fe(II)-Fe(III) Green Rusts: Occurrences of the mineral in hydromorphic soils. Environmental Science and Technology, 32, 1058–1068.
Hansen, H.C.B. (2001) Environmental chemistry of iron(II)- iron(III) LDHs (Green Rusts). Pp. 469–493 in: Layered Double Hydroxides: Present and Future (V. Rives, editor). Nova Science Publishers, Inc., New York.
Heller-Kallai, L. and Rozenson, I. (1981) The use of Mössbauer spectroscopy of iron in clay mineralogy. Physics and Chemistry of Minerals, 7, 223–238.
Jefferson, D.A., Tricker, M.J., and Winterbottom, A.P. (1975) Electron-microscopic and Mössbauers pectroscopic studies of iron-stained kaolinite minerals. Clays and Clay Minerals, 23, 355–360
Jonin, M. (1973) Les différents types granitiques de la Mancellia et l’unité du batholite manceau (Massif armoricain). Comptes Rendus hebdomadaires de séances de l’Académie des Sciences. Series D, Sciences Naturelle, 277, 281–284.
Kanket, W., Suddhiprakarn, A., Kheoruenromne, I., and Gilkes, R.J. (2005) Chemical and crystallographic properties of kaolin from Ultisols in Thailand. Clays and Clay Minerals, 53, 478–489.
Manceau, A., Bonnin, D., Kaiser, P., and Fretigny, C. (1988) Polarized exafs of biotite and chlorite. Physics and Chemistry of Minerals, 16, 180–185.
Manceau, A., Drits, V.A., Lanson, B., Chateigner, D., Wu, J., Huo, D., Gates, W.P., and Stucki, J.W. (2000) Oxidationreduction mechanism of iron in dioctahedral smectites: II. Crystal chemistry of reduced Garfield nontronite. American Mineralogist, 85, 153–172.
Mitchell, B.D., Smith, B.F.L., and De Endredy, A.S. (1971) Effect of buffered sodium dithionite solution and ultrasonic agitation on soil clays. Israel Journal of Chemistry, 9, 45–52.
Moore, D.M. and Reynolds, R.C. (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, New York. xviii + 378 pp.
Murad, E. (1998) Clays and clay minerals: What can Mössbauerspect roscopy do to help understand them? Hyperfine Interactions, 117, 39–70.
Murad, E. and Wagner, U. (1994) The Mössbauerspectr um of illite. Clay Minerals, 29, 1–10.
O’Day, P.A., Rivera Jr., N., Root, R., and Carroll, S.A. (2004) X-ray absorption spectroscopic study of Fe reference compounds forth e analysis of natural sediments. American Mineralogist, 89, 572–585.
Refait, P., Abdelmoula, M., Trolard, F., Génin, J.-M.R., Ehrhardt, J.J., and Bourrié, G. (2001) Mössbauerand XAS study of a green rust mineral; the partial substitution of Fe2+ by Mg2+. American Mineralogist, 86, 731–739.
Refait, P., Abdelmoula, M., and Génin, J.-M.R. (1998) Mechanisms of formation and structure of green rust one in aqueous corrosion of iron in the presence of chloride ions. Corrosion Science 40, 1547–1560.
Refait, P., Drissi, S.H., Pytkiewicz, J., and Génin, J.-M.R. (1997) The anionic species competition in iron aqueous corrosion: Role of various green rust compounds. Corrosion Science, 39, 1699–1710.
Sontevska, V., Jovanovski, G., and Makreski, P. (2007) Minerals from Macedonia. Part XIX. Vibrational spectroscopy as identificational tool forsome sheet silicate minerals. Journal of Molecular Structure, 834-836, 318–327.
Trolard, F. (2006) Fougerite: From field experiment to the homologation of the mineral. Comptes Rendus Geosciences, 338, 1158–1166.
Trolard, F. and Bourrié, G. (2008) Geochemistry of green rusts and fougerite: a reevaluation of Fe-cycle in soils. Pp. 227–288 in: Advances in Agronomy (D.L. Sparks, editor). Vol. 99. ElsevierAcad emic Press, Inc, San Diego, California, USA.
Trolard, F., Abdelmoula, M., Bourrié, G., Humbert, B., and Genin, J.-M.R. (1996) Evidence of the occurrence of a “Green Rust” component in hydromorphic soils. Proposition of the existence of a new mineral: “Fougerite”. Comptes Rendus De L Academie Des Sciences Serie Ii Fascicule A -Sciences De La Terre Et Des Planetes, 323, 1015–1022.
Trolard, F., Génin, J.-M.R., Abdelmoula, M., Bourrié, G., Humbert, B., and Herbillon, A. (1997) Identification of a green rust mineral in a reductomorphic soil by Mössbauer and Raman spectroscopies. Geochimica et Cosmochimica Acta, 61, 1107–1111.
Trolard, F., Bourrié, G., Abdelmoula, M., Refait, P., and Feder, F. (2007) Fougerite, a new mineral of the pyroaurite—iowaite group: description and crystal structure. Clays and Clay Minerals, 55, 323–334.
Vantelon, D., Montarges-Pelletier, E., Michot, L.J., Briois, V., Pelletier, M., and Thomas, F. (2003) Iron distribution in the octahedral sheet of dioctahedral smectites. An FeK-edge X-ray absorption spectroscopy study. Physics and Chemistry of Minerals, 30, 44–53.
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Christiansen, B.C., Dideriksen, K., Skovbjerg, L.L. et al. Letter to the Editor on Fougerite. Clays Clay Miner. 59, 3–9 (2011). https://doi.org/10.1346/CCMN.2011.0590102
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DOI: https://doi.org/10.1346/CCMN.2011.0590102