Abstract
Pliocene volcaniclastic lacustrine rocks of the Doğanbey formation in the Beyşehir region (central Anatolia) are composed of organic-matter-bearing claystone, clastic units and dolomite interbeds, suggesting an anaerobic, shallow swampy, lacustrine depositional environment. The depositional environment was subjected to periodic climatic change during which diagenesis occurred, and smectite, and locally palygorskite, were precipitated. Smectite flakes formed authigenically on feldspar and palygorskite fibers between dolomite rhombs and at the edges of smectite flakes. Increases in leaching of Na, K, Sr, Ba and Rb, increasing Al/Si ratios, and Fe with increasing degree of alteration reveal that hydration of volcaniclastic grains (feldspar, glass) by meteoric water — determined from O and H isotopic values — was the main cause of precipitation of beidellite and montmorillonite based on the tetrahedral charge/octahedral charge ratio, with average structural formulae of (Si7.72Al0.28)(Al3.20Fe0.53Mg0.25 Mn0.02Ti0.04), and (Si7.88Al0.13)(Al3.18Fe0.53Mg0.18Mn0.02Ti0.05)(Ca0.11Na0.11K0.09), respectively. Therefore, the Doğanbey-area smectite is presumed to have formed by chemical weathering and dissolution-precipitation from feldspar and glass during diagenesis; palygorskite formed by direct precipitation from Mg-rich solutions during dolomitization, and by transformation from smectite in an alkaline lacustrine environment.
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Abdioğlu, E. and Arslan, M. (2005) Mineralogy, geochemistry and genesis of bentonites of the Ordo area, NE Turkey. Clay Minerals, 40, 131–151.
Akbulut, A. and Kadir, S. (2003) The geology and origin of sepiolite, palygorskite and saponite in Neogene lacustrine sediments of the Serinhisar-Acıpayam basin, Denizli, SW Turkey. Clays and Clay Minerals, 51, 279–292.
Altaner, S.P. and Grim, R.E. (1990) Mineralogy, chemistry, and diagenesis of tuffs in the Sucker Creek Formation (Miocene), Eastern Oregon. Clays and Clay Minerals, 38, 561–572.
Baker, J.C. and Golding, S.D. (1992) Occurrence and palaeohydrological significance of authigenic kaolinite in the Aldebaran sandstone, Denison Trough, Queensland, Australia. Clays and Clay Minerals, 40, 273–279.
Barnard, P.C. and Cooper, B.S. (1981) Oils and source rocks of the North Sea area. Pp. 169–175 in: Petroleum Geology of the Continental Shelf of North West Europe (L.V. Illing and G.D. Hobson, editors). Heyden & Son, London.
Braiser, M.D. (1985) Microfossils. George Allen & Unwin, London, 193 pp.
Brindley, G.W. (1980) Quantitative X-ray analysis of clays. Pp. 411–438 in: Crystal Structures of Clay Minerals and their X-ray Identification (G.W. Brindley and G. Brown, editors). Monograph 5, Mineralogical Society, London.
Çelik, M., Temel, A., Orhan, H. and Tunoğlu, C. (1997) Economic importance of clay and aluminium sulphate occurrences in west-southwest of Konya, Turkey. Turkish Journal of Earth Sciences, 6, 85–94.
Christidis, G.E. (1998) Comparative study of the mobility of major and trace elements during alteration of an andesite and a rhyolite to bentonite in the islands of Milos and Kimolos, Aegean, Greece. Clays and Clay Minerals, 46, 379–399.
Christidis, G. and Dunham, A.C. (1997) Compositional variations in smectites. Part II: Alteration of acidic precursors, a case study from Milos Island, Greece. Clay Minerals, 32, 253–270.
Christidis, G. and Scott, P.W. (1997) The origin and control of colour of white bentonites from the Aegean islands of Milos and Kimolos, Greece. Mineralium Deposita, 32, 271–279.
Christidis, G., Scott, P.W. and Marcopoulast, T. (1995) Origin of the bentonite deposits of Eastern Milos and Kimalos, Greece: geological, mineralogical and geochemical evidence. Clays and Clay Minerals, 43, 63–77.
Clayton, R.N. and Mayeda, T. (1963) The use of bromine pentafluoide in the extraction of oxygen from oxides and silicates for isotopic analysis. Geochimica et Cosmochimica Acta, 27, 47–52.
Colson, J., Cojan, I. and Thiry, M. (1998) A hydrological model for palygorskite formation in the Danian continental facies of the Provence Basin (France). Clay Minerals, 33, 333–347.
Compton, J.S. (1991) Origin and diagenesis of clay minerals in the Monterey Formation, Santa Maria Basin Area, California. Clays and Clay Minerals, 39, 449–466.
Craig, H. (1961) Isotopic variations in meteoric waters. Science, 133, 1702–1703.
Ece, Ö.İ. and Çoban, F. (1994) Geology, occurrence and genesis of Eskişehir sepiolites, Turkey. Clays and Clay Minerals, 42, 81–92.
Galán, E. and Ferrero, A. (1982) Palygorskite-sepiolite clays of Lebrija, southern Spain. Clays and Clay Minerals, 30, 191–199.
Grim, R.E. and Güven, N. (1978) Bentonites, Geology, Mineralogy, Properties and Uses. Elsevier, Amsterdam, pp. 13–137.
Güven, N. (1988) Smectites. Pp. 497–559 in: Hydrous Phyllosilicates (S.W. Bailey, editor). Reviews in Mineralogy 19, Mineralogical Society of America, Washington, D.C.
Hynes, A. (1980) Carbonatization and mobility of Ti, Y, and Zr in Ascot Formation metabasalts, SE Quebec. Contributions to Mineralogy and Petrology, 75, 79–87.
Iijima, A. and Tada, R. (1981) Silica diagenesis of Neogene diatomaceous and volcaniclastic sediments in northern Japan. Sedimentolgy, 28, 185–200.
Inglès, M. and Anadón, P. (1991) Relationship of clay minerals to depositional environment in the non-marine Eocene Pontils Group, SE Ebro basin (Spain). Journal of Sedimentary Petrology, 61, 926–939.
James, N.P. (1972) Holocene and Pleistocene calcareous crust (caliche) profiles: creteria for subaerial exposure. Journal of Sedimentary Petrology, 42, 817–836.
Jamoussi, F., Ben Aboud, A. and López-Galindo, A. (2003) Palygorskite genesis through silicate transformation in Tunisian continental Eocene deposits. Clays Minerals, 38, 187–199.
Jones, J.B. and Segnit, E.R. (1971) The nature of opal I. Nomenclature and constituent phases. Journal of Geological Society of Australia, 18, 57–68.
Kadir, S. and Karakaş, Z. (2002) Mineralogy, chemistry and origin of halloysite, kaolinite and smectite from Miocene ignimbrites, Konya, Turkey. Neues Jahrbuch für Mineralogie, Abhandlungen, 177, 113–132.
Karakaş, Z. and Kadir, S. (1998) Mineralogical and genetic relationships between carbonate and sepiolite-palygorskite formations in the Neogene lacustrine Konya Basin, Turkey. Carbonates and Evaporites, 13, 198–206.
Keller, J., Jung, D., Burgath, K. and Wolff, F. (1977) Geologie und petrographie des Neogenen Kalkalkali-Vulkanismus von Konya (Erenler Dağ-Alaca Dağ-massiv, Zentral-Anatolien). Geologisches Jahrbuch Hessen, 25, 37–117.
Knox, G.J. (1977) Caliche profile formation. Saldanha Bay (South Africa). Sedimentology, 24, 657–674.
Kunze, G.W. and Dixon, J.B. (1986) Pretreatment for mineralogical analysis. Pp. 91–99 in: Methods of Soil Analysis, Part I, Physical and Mineralogical Methods 2nd edition (A. Klute, editor). Soil Science Society of America, Madison, Wisconsin.
Lawrence, J.R. and Taylor, H.R. (1971) Deuterium and oxygen-18 correlation: Clay minerals and hydroxides in Quaternary soils compaired to meteoric water. Geochimica et Cosmochimica Acta, 35, 993–1003.
Lawrence, J.R. and Taylor, H.R. (1972) Hydrogen and oxygen isotope systematics in weathering profiles. Geochimica et Cosmochimica Acta, 36, 1377–1393.
MacLean, W.H. and Kranidiotis, P. (1987) Immobile elements as monitors of mass transfer in hydrothermal alteration: Phelps Dodge massive sulfide deposits, Matagami, Quebec Economic Geology, 2, 951–962.
Moore, D.M. and Reynolds, R.C. (1989) X-ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, Oxford, 332 pp.
Mount, J.F. and Cohen, A.S. (1984) Petrology and geochemistry of rhizoliths from plio-Pleistocene fluvial and marginal lacustrine deposits, East Lake Turkana, Kenya. Journal of Sedimentary Petrology, 54, 263–275.
Murphy, J.B. and Hynes, A.J. (1986) Contrasting secondary mobility of Ti, P, Zr, Nb, and Y in two metabasaltic suites in the Appalachians. Canadian Journal of Earth Sciences, 23, 1138–1144.
Müller, G., Irion, G. and Förstner, U. (1972) Formation and diagenesis of inorganic Ca-Mg carbonates in the lacustrine environment. Naturwissenschaften, 59, 158–164.
Özgüner, A.M., Büyüktemiz, M., Kılıç, M.F. and Demirci, A.R. (1987) Konya yöresi seramik hammaddeleri etüdü, 2 cilt. MTA Report No. 8371. Unpublished).
Rodas, M., Luque, F.J., Mas, R. and Garzon, M.G. (1994) Calcretes, palycretes and silcretes in the paleogene detrital sediments of the Dueo and Tajo Basins, central Spain. Clay Minerals, 29, 273–285.
Savin, S.M. and Epstein, S. (1970) The oxygen and hydrogen isotope geochemistry of clay minerals. Geochimica et Cosmochimica Acta, 34, 25–42.
Şenel, M. (2002) 1/500.000 scale geological map of Turkey — Konya, General Directorate of Mineral Research and Exploration of Turkey.
Sheppard, S.M.F. (1986) Characterization and isotopic variations in natural waters. Pp. 141–162 in: Stable Isotopes in High Temperature Geological Processes (J.W. Valley, H.P. Taylor and J.R. O’Neil, editors). Reviews in Mineralogy 16, Mineralogical Society of America, Washington, D.C.
Sheppard, S.M.F. and Gilg, H.A. (1996) Stable isotope geochemisty of clay minerals. Clay Minerals, 31, 1–24.
Singer, A. (1979) Palygorskite in sediments: detrital, diagenetic, or neoformed — a critical review. Geologische Rundschau, 68, 996–1008.
Singer, A. (1989) Palygorskite and sepiolite group minerals. Pp. 829–872 in: Minerals in Soil Environments (J. B. Dixon and S. B. Weed, editors). Soil Science Society of America, Madison, Wisconsin, USA.
Stamatakis, M.G., Hein, J.R. and Magganas, A.C. (1989) Geochemistry and diagenesis of Miocene lacustrine siliceous sedimentary and pyroclastic rocks, Mytilinii basin, Greece. Sedimentary Geology, 64, 65–78.
Suludere, Y., Aydoğan, N., Özgüner, A.M. and Atilla, A. (1986) Toçak yaylası (Konya — Beyşehir — Damlapınar) kaolen sahası. Dülger Kışlağı (Konya — Seydişehir — Çavuş) ve Helaloğlu yaylası (Konya — Beyşehir — Doğanbey) bentonit sahaları maden jeolojisi raporu. MTA Report No 8071 (unpublished)
Taylor, H.P. (1974) The application of oxygen and hydrogen isotope studies to problems of hydrothermal alteration and ore deposition. Economic Geology, 69, 843–883.
Taylor, H.P. (1979) Oxygen and hydrogen relationships in hydrothermal mineral deposits. Pp. 236–277 in: Geochemistry of Hydrothermal Ore Deposits, 2nd edition (H.L. Barnes, editor). Wiley, New York.
Teale, C.T. and Spears, D.A. (1986) The mineralogy and origin of some Silurian bentonites, Welsh Borderland, UK. Sedimentology, 33, 757–765.
Temel, A., Çelik, M. and Tunoğlu, C. (1995) Konya Batı-Güneybatısmda yeralan Neojen yaşlı volkanosedimater basenindeki kil oluşmları. VII National Clay Symposium, Ankara, pp. 32–45.
Temel, A., Gündoğdu, N.M. and Gourgaud, A. (1998) Petrological and geochemical characteristics of Cenozoic high-K calc-alkaline volcanism in Konya, central Anatolia, Turkey. Journal of Volcanology and Geothermal Research, 85, 447–471.
Torres-Ruiz, J., López-Galindo, A., González-López and Delgado, A. (1994) Geochemistry of Spanish sepiolite-palygorskite deposits: Genetic considerations based on trace elements and isotopes. Chemical Geology, 112, 221–245.
Tucker, M.E. and Bathurst, R.G.C. (1990) Carbonate Diagenesis. Blackwell Scientific Publications, 1, Oxford, UK, 312 pp.
Umut, M., Karabıyıkoğlu, M., Saraç, G., Bulut, V., Demirci, A.R., Erkan, M., Kurt, Z., Metin, S. and Özgönül, E. (1987) Tuzlukçu — Ilgın — Doğanhisar — Doğanbey Konya ili ve dolayının jeolojisi. MTA Report No. 8246, 38 p. (Unpublished)
Velde, B. (1995) Origin and Mineralogy of Clays. Clays and the Environment. Springer, France, 334 pp.
Weaver, C.E. (1989) Clays, Muds, and Shales. Developments in Sedimentology, 44, Elsevier, Amsterdam, 819 pp.
Weaver, C.E. and Beck, K. (1977) Miocene of the S.E. United States: A Model for chemical sedimentation in a peri-marine environment. Special Issue. Sedimentary Geology, 17, 1–234.
Winchester, J.A. and Floyd, P.A. (1977) Geochemical discrimination of different magma series and their differentiation products using immobile elements. Chemical Geology, 20, 245–252.
Wright, V.P. (1984) The significance of needle-like calcite in a Lower Carboniferous paleosol. Geological Journal, 19, 23–32.
Wright, V.P. and Tucker, M.E. (1991) Calcretes. The International Association of Sedimentologists, Oxford, London, 352 pp.
Yalçın, H. and Gümüşer, G. (2000) Mineralogical and geochemical characteristics of Late Cretaceous bentonite deposits of the Kelkit Valley Region, Northern Turkey. Clay Minerals, 35, 807–825.
Yui, T.F. and Chang, S.S. (1999) Formation conditions of vesicle/fissure-filling smectites in Penghu basalts: a stable-isotope assessment. Clay Minerals, 34, 381–393.
Zedef, V., Öncel, M.S., Arslan, M., Döyen, A. and Söğüt, A.R. (1994) Alpin tipi kromit yataklarına jeokimyasal açıdan farklı bir örnek: Yeşildağ (Beyşehir-Konya) kromit yatağı. S.Ü.Mühendislik-Mimarlık Fakültesi Dergisi, 9, 28–35.
Zielinski, R.A. (1982) The mobility of uranium and other elements during alteration of rhyolite ash to montmorillonite: A case study in the Troublesome formation, Colorado, USA. Chemical Geology, 35, 185–204.
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Kadir, S. Mineralogy, geochemistry and genesis of smectite in pliocene volcaniclastic rocks of the doğanbey formation, beyşehir basin, Konya, Turkey. Clays Clay Miner. 55, 402–422 (2007). https://doi.org/10.1346/CCMN.2007.0550408
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DOI: https://doi.org/10.1346/CCMN.2007.0550408