Abstract
Coarse-grained vermiculite from a serpentinite-pegmatite thermal zone displays a rational series of narrow 14.4 Å basal reflections and an unusual broad 28 Å peak. X-ray diffraction simulations and fitting techniques show that the 28 Å peak is related to 28 Å domains consisting of elongated 2:1 layers of different lengths. The domains are located at the crystal edges of the vermiculite.
Similar content being viewed by others
References
Collins, D.R., Fitch, A.N. and Catlow, R.A. (1992) Dehydration of vermiculites and montmorillonites: a time-resolved powder neutron diffraction study. Journal of Materials Chemistry, 2, 865–873.
de la Calle, C. and Suquet, H. (1988) Vermiculite. Pp. 455–496 in: Hydrous Phyllosilicates (exclusive of micas) (S.W. Bailey, editor). Reviews in Mineralogy, 19, Mineralogical Society of America, Washington, D.C.
Drits, V.A. and Sakharov, B.A. (1976) X-ray Structural Analysis of Mixed-layer Minerals. Transactions of Academy of Sciences U.S.S.R., 295, Moscow, 252 pp. (in Russian).
Drits, V.A. and Tchoubar, C. (1990) X-Ray Diffraction by Lamellar Structures. Theory and Application to Microdivided Silicates and Carbons. Springer-Verlag, Berlin-Heidelberg-New York-London-Paris-Tokyo-Hong Kong-Barcelona, 371 pp.
Drits, V.A., Eberl, D.D. and Srodon, J. (1998) XRD measurement of mean thickness, thickness distribution and strain for illite and illite/smectite crystallites by the Bertaut-Warren-Awerbach technique. Clays and Clay Minerals, 46, 38–50.
Dubinska, E., Jelitto, J. and Kozlowski, A. (1995) Origin and evolution of granite-serpentinite reaction zones at Wiry, Lower Silesia. Acta Geologica Polonica, 45, 41–82.
Janeczek, J. and Sachanbitiski, M. (1995) New data on hybridal pegmatite in serpentinite from magnesite mine in Wiry (Lower Silesia). Przeglad Geologiczny, 53, 777–782 (in Polish).
Jelitto, J., Dubinska, E., Wiewióra A. and Bylina, P. (1993) Layer silicates from serpentinite-pegmatite contact (Wiry, Lower Silesia, Poland). Clays and Clay Minerals, 41, 693–701.
MacEwan, D.M.C., and Wilson, M.J. (1980) Interlayer and intercalation complexes of clay minerals. Pp. 197–248 in: Crystal Structures of Clay Minerals and their X-ray Identification (G.W Brindley and G. Brown, editors). Monograph, 5. Mineralogical Society, London.
Moore, D.M. and Reynolds, R.C. (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, Oxford-New York, 378 pp.
Pons, C.H., Pozzuoli, A., Rausell-Colon, J.A. and de la Calle, C. (1989) Mechanisme de passage de l’état hydraté à une couche à l’état “zero couche” d’une vermiculite-Li de San-ta-Olalla. Clay Minerals, 24, 479–493.
Reichenbach, H., Graf V., Wachsmuth, H. and Marcks C. (1988) Observations at the mica-vermiculite interface with HRTEM. Colloid & Polymer Science, 266, 652–656.
Reichenbach, H., Graf V. and Beyer, J. (1994) Dehydration and rehydration of vermiculites: I. Phlogopitic Mg-vermic-ulite. Clay Minerals, 29, 327–340.
Reichenbach, H., Graf V. and Beyer, J. (1995) Dehydration and rehydration of vermiculites: II. Phlogopitic Ca-vermiculite. Clay Minerals, 30, 273–286.
Reichenbach, H., Graf V., and Schütte, R. (1995) PH2o-T stability diagrams of hydrated vermiculites, Clays: Controlling the Environment. Pp. 235–239 in: Proceedings of the 10th International Clay Conference Adelaide, Australia 1993, (G.J. Churchman, R.W. Fitzpatrick and R. A. Eggleton, editors). CSIRO Publishing Melbourne, Australia.
Reynolds, R.C. (1986) The Lorentz-polarization factor and preferred orientation in oriented clay aggregates. Clays and Clay Minerals, 34, 359–367.
Ruiz-Conde, A., Ruiz-Amil, A., Pérez-Rodriguez, J.L. and Sânchez-Soto, P.J. (1996) Dehydration-rehydration in magnesium vermiculite: Conversion from two-one and one-two water layer hydration states through the formation of inter-stratified phases. Journal of Materials Chemistry, 6, 1557–1566.
Sachanbinski, M. (1993) Talc and vermiculite occurrence in ultramafic rocks of the Slçza ophiolite (Lower Silesia). Acta Universitatis Wraclaviensis, 1412, 63–117 (in Polish).
Walker, G.W. (1975) Vermiculites. Pp. 155–189 in: Soil Components, Vol. 2: Inorganic Components (J.E. Gieseking, editor). Springer, New York-Berlin-Heidelberg.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sakharov, B.A., Dubińska, E., Bylina, P. et al. Unusual X-Ray Characteristics of Vermiculite from Wiry, Lower Silesia, Poland. Clays Clay Miner. 49, 197–203 (2001). https://doi.org/10.1346/CCMN.2001.0490302
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1346/CCMN.2001.0490302