Abstract
Transgression by the Western Interior Sea during the Late Cretaceous in southwestern Minnesota caused swampy conditions to be imposed upon a laterite consisting of gibbsite, goethite and kaolinite. Reducing conditions overprinted upon the laterite reduced ferric Fe in goethite for incorporation of ferrous Fe into Fe-berthierine. Attendant oxidation of organic matter provided CO2 for siderite’s formation. Thermodynamic calculations indicate that berthierine, gibbsite, goethite, kaolinite and siderite were in equilibrium with a solution whose pH was 5.2 and whose pCO2 was on the order of 0.3 atm. Formation of Fe-berthierine is favored by solutions having: 1) low silica concentration; 2) low [Mg2+]/[Fe2+] ratio; 3) high pCO2; 4) extremely low sulfate content before reduction takes place; and 5) moderate reducing conditions (Eh around −0.05 V).
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References
Brookins DG. 1988. Eh-pH diagrams for geochemistry. Berlin: Springer-Verlag. 17. p.
Faure G. 1991. Principles and applications of inorganic geochemistry. New York: Macmillan. 62. p.
Flebbe PA. 1984. Carbon dioxide and methane systematics in selected Okefenokee Swamp sites. In: Cohen et al., editors. The Okefenokee Swamp. Los Alamos, NM: Wetland Surveys, p 380–390.
Kauffman EG. 1977. Geological and biological overview, Western Interior Basin. In: Kauffman EG, editor. Cretaceous facies, fauna, and paleoenvironments across the Western Interior Basin, Mountain Geologist. Rocky Mtn Assoc Geol 14:75–99.
Krauskopf K. 1967. Introduction to geochemistry. New York: J Wiley. 44. p.
Lindsay WL. 1979. Chemical equilibria in soils. New York: J Wiley. 44. p.
Nordstrom DK, Valentine SD, Ball JW, Plummer LN, Jones BE 1984. Partial compilation and revision of basic data in the WATEQ programs. US Geol Surv Water Res Invest 84–4186. 4. p.
Postala D. 1977. The Occurrence and chemical composition of recent Fe-rich mixed carbonates in a river bog. J Sed Petrol 47:1089–1098.
Robie RA, Hemingway BS, Fisher JR. 1979. Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and at higher temperatures. US Geol Surv Bull 1452. 45. p.
Stumm W, Morgan JJ. 1981. Aquatic chemistry. New York: J Wiley. 78. p.
Tardy Y, Garrels RM. 1974. A method of estimating the Gibbs energies of formation of layer silicates. Geochim Cosmochim Acta 38:1101–1116.
Wagman DD, Evans WH, Parker VB, Schumm RH, Halow I, Bailey SM, Churney K, Buttali RL. 1982. The NBS tables of chemical thermodynamic properties. Selected values for inorganic and C1 and C2 organic substances in SI units. J Phys Chem Ref Data 11 (suppl 2). 39. p.
Woods TL, Garrels RM. 1987. Thermodynamic values at low temperature for natural inorganic materials: An uncritical summary. New York: Oxford Univ Pr. 24. p.
Weast RC, Astle WJ. 1981. editors. Handbook of Chemistry and Physics. Boca Raton, FL: CRC Pr.
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Fritz, S.J., Toth, T.A. An Fe-Berthierine from a Cretaceous Laterite: Part II. Estimation of Eh, pH and pCO2 Conditions of Formation. Clays Clay Miner. 45, 580–586 (1997). https://doi.org/10.1346/CCMN.1997.0450409
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DOI: https://doi.org/10.1346/CCMN.1997.0450409