Abstract
Spherical halloysite aggregates have been identified for the first time in mineral matter isolated from bituminous coals. The spherules, found in Permian coals of the Sydney basin, New South Wales, range from 0.4 to 0.6 µm in diameter and have a delicate ring-like structure that helps to confirm the halloysite identification. They appear from their location to be related to influxes of pyroclastic debris, either directly or from nearby soils, into the original peat accumulation. Analytical electron microscopy indicates higher proportions of Si and Fe than coexisting particles of hexagonal platy kaolinite, and electron diffraction reveals a typical disordered halloysite structure. The aggregates are larger than those normally reported in soils, and comparison to growth rates in soils suggests development over a significantly longer time than that expected for accumulation of the host coal seams. The buckled structure in the ring-like pattern and the related crude polyhedral outlines probably reflect shrinkage with dehydration during the coalification process, but it may also be due to the different sample preparation techniques.
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References
Aomine, S. and Wada, K. (1962) Differential weathering of volcanic ash and pumice, resulting in formation of hydrated halloysite: Amer. Mineral. 47, 1024–1048.
Brindley, G. W. and De Kimpe, C. (1961) Identification of clay minerals by single crystal electron diffraction: Amer. Mineral. 46, 1005–1016.
Glasmann, J. R. (1982) Alteration of andésite in wet, unstable soils of Oregon’s Western Cascades: Clays & Clay Minerals 30, 253–263.
Gluskoter, H. J. (1965) Electronic low-temperature ashing of bituminous coal: Fuel (Lond.) 44, 285–291.
Holmes, G. G. (1983) Bentonite and fullers earth in New South Wales: Geol. Surv. New South Wales, Mineral Resources 45, 138 pp.
Hood, A., Gutjahr, C. C. M., and Heacock, R. L. (1975) Organic metamorphism and the generation of petroleum: Bull. Amer. Assoc. Petrol. Geol. 59, 986–996.
Hunt, J. W. and Hobday, D. K. (1984) Pétrographie composition and sulphur content of coals associated with alluvial fans in the Permian of the Sydney and Gunnedah Basins, eastern Australia: in Sedimentology of Coal and Coal-bearing Sequences, R. A. Rahmani and R. M. Flores, eds., Spec. Publ Int. Ass. Sedimentol. 7, 43–60.
Kirkman, J. H. (1981) Morphology and structure of halloysite in New Zealand tephras: Clays & Clay Minerals 29, 1–9.
Kohyama, N., Fukushima, K., and Fukami, A. (1978) Observation of the hydrated form of tubular halloysite by an electron microscope equipped with an environmental cell: Clays & Clay Minerals 26, 25–40.
Kohyama, N., Fukushima, K., and Fukami, A. (1982) In-terlayer hydrates and complexes of clay minerals observed by electron microscopy using an environmental cell: in Proc. Int. Clay Conf., Bologna, Pavia, 1981, H. van Olphen and F. Veniale, eds., Elsevier, Amsterdam, 373–384.
Loughnan, F. C. and Craig, D. C. (1961) A complex inter-stratified clay mineral in the pottery shale from Marran-garoo, N.S.W.: Aust. J. Sci. 23, p. 379.
Nagasawa, K. and Miyazaki, S. (1976) Mineralogical properties of halloysite as related to its genesis: in Proc. Int. Clay Conf. 1975, S. W. Bailey, ed., Applied Publications Ltd., Wilmette, Illinois, 257–265.
Roberts, F. I. and Loughnan, F. C. (1989) Mineralogy and economic significance of the bentonite occurrences in the upper Hunter Valley: in Proc. Mineralogy-Petrology Symposium, Sydney, 1989, Australasian Inst. Min. Metall., Melbourne, 123–127.
Stach, E., Mackowsky, M. Th., Teichmüller, M., Taylor, G. H., Chandra, D., and Teichmüller, R. (1982) Stach’s Text-book of Coal Petrology: 3rd ed., Gebrüder Bornträger, Stuttgart, 535 pp.
Sudo, T., Shimoda, S., Yotsumoto, H., and Aita, S. (1981) Electron Micrographs of Clay Minerals: Elsevier, Amsterdam, 203 pp.
Sudo, T. and Yotsumoto, H. (1977) The formation of hal-loysite tubes from spherulitic halloysite: Clays & Clay Minerals 25, 155–159.
Tazaki, K. (1982) Analytical electron microscopic studies of halloysite formation processes—Morphology and composition of halloysite: in Proc. Int. Clay Conf, Bologna, Pavia, 1981, H. van Olphen and F. Veniale, eds., Elsevier, Amsterdam, 573–584.
Tomura, S., Shibasaki, Y., Mizuta, H., and Kitamura, M. (1983) Spherical kaolinite: synthesis and mineralogical properties: Clays & Clay Minerals 31, 413–421.
Wada, K. (1987) Minerals formed and mineral formation from volcanic ash by weathering: Chem. Geol. 60, 17–28.
Ward, C. R. (1978) Mineral matter in Australian bituminous coals: Proc. Australasian Inst. Min. Metall. 267, 7–25.
Ward, C. R. (1989) Minerals in bituminous coals of the Sydney basin (Australia) and the Illinois basin (U.S.A.): in Coal: Classification, Coalification, Mineralogy, Trace Element Geochemistry, and Oil and Gas Potential, P. C. Lyons and B. Alpern, eds., Int. J. Coal Geol. 13, 455–479.
Ward, C. R., Warbrooke, P. R., and Roberts, F. I. (1989) Geochemical and mineralogical changes in a coal seam due to contact metamorphism, Sydney basin, New South Wales, Australia: Int. J. Coal Geol. 11, 105–125.
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Ward, C.R., Roberts, F.I. Occurrence of Spherical Halloysite in Bituminous Coals of the Sydney Basin, Australia. Clays Clay Miner. 38, 501–506 (1990). https://doi.org/10.1346/CCMN.1990.0380506
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DOI: https://doi.org/10.1346/CCMN.1990.0380506