Skip to main content
Log in

The Relationship between the I.R. Spectra of Serpentines and Their Structures

  • Published:
Clays and Clay Minerals

Abstract

Possible assignments are suggested for some of the absorption bands in the 1150–400 cm−1 region of the i.r. spectra of serpentines. Polarized light was used to identify the out-of-plane vibrations in antigorites and platy lizardites and the vibrations parallel to the fibre axis in chrysotiles and fibrous lizardites. An attempt is made to correlate some known structural characteristics and the chemical composition of the serpentines with some features of the i.r. spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Aumento, F. (1967) A serpentine mineral showing diverse strain-relief mechanisms: Am. Miner. 52, 1399–1413.

    Google Scholar 

  • Brindley, G. W., Comer, J. J., Uyeda, R. and Zussman, J. (1958) Electron-optical observations with crystals of antigorite: Acta Cryst. 11, 99–102.

    Article  Google Scholar 

  • Brindley, G. W. and Zussman, J. (1959) Infra-red absorption data for serpentine minerals: Am. Miner. 44, 185–188.

    Google Scholar 

  • Farmer, V. C. (1958) The infra-red spectra of talc, saponite and hectorite: Min. Mag. 31, 829–845.

    Google Scholar 

  • Farmer, V. C. and Russell, J. D. (1964) The infra-red spectra of layer silicates: Spectrochim. Acta 20, 1149–1173.

    Article  Google Scholar 

  • Faust, T. G. and Fahey, J. J. (1962) The serpentine-group minerals: U.S.G.S. Prof. Paper 384-A, 1–92.

    Google Scholar 

  • Kunze, G. (1961) Antigorit: Strukturtheoretische Grundlagen und ihre praktische Bedeutung fuer die weitere Serpentin-Forschung: Fortschr. Miner. 39, 206–324.

    Google Scholar 

  • Luce, R. W. (1971) Identification of serpentine varieties by infra-red absorption: U.S.G.S. Prof. Paper 750B, 199–201.

    Google Scholar 

  • Page, N. J. (1968) Chemical differences among the serpentine ‘polymorphs’: Am. Miner. 53, 201–215.

    Google Scholar 

  • Pampuch, R. and Ptak, W. (1968) Pol. Akad. Nauk, Oddzal Krakowie, Pr. Miner. 15, 7.

    Google Scholar 

  • Pampuch, R. and Ptak, W. (1970) Pol. Akad. Nauk, Oddizal Krakowie, Pr. Kom. Ceram., Ceram. 14, 7–36.

    Google Scholar 

  • Russell, J. D., Farmer, V. C. and Velde, B. (1970) Replacement of OH by OD in layer silicates, and identification of the vibrations of these groups in infra-red spectra: Min. Mag. 37, 869–879.

    Article  Google Scholar 

  • Stubican, V. and Roy, R. (1961) Isomorphous substitution and infra-red spectra of layer lattice silicates: Am. Miner. 46, 32–51.

    Google Scholar 

  • Veniale, F. and van der Marel, H. V. (1963) An interstrati-fied saponite-swelling chlorite mineral as a weathering product of lizardite rock from St. Margherita Staffora (Pavia Province), Italy: Beitraege zur Mineral, und Petrogr. 9, 198–245.

    Google Scholar 

  • Whittaker, E. S. W. (1956) The structure of chrysotile—II: Clinochrysotile: Acta Cryst. 9, 855–862.

    Article  Google Scholar 

  • Whittaker, E. J. W. and Zussman, J. (1956) The characterization of serpentine minerals by X-ray diffraction. Min. Mag. 31, 107–126.

    Google Scholar 

  • Whittaker, E. J. W. and Wicks, F. J. (1970) Chemical differences among the serpentine ‘polymorphs’: A discussion: Am. Miner. 55, 1025–1047.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yariv, S., Heller-Kallai, L. The Relationship between the I.R. Spectra of Serpentines and Their Structures. Clays Clay Miner. 23, 145–152 (1975). https://doi.org/10.1346/CCMN.1975.0230210

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1346/CCMN.1975.0230210

Navigation