Abstract
A carbonate rock silicification reaction has been defined and shown to be dependent on the presence of clay in the host rock. Introduction of silica in soluble form(s) serves to polymerize the clay fraction, forming a continuous three-dimensional network. This siliceous network (polymer) can be separated from the rock by leaching away the carbonate minerals. Laboratory silicification of argillaceous carbonate rocks under controlled conditions has served to define critical variables.
Early studies were limited to argillaceous carbonate rocks from the Devonian Cedar Valley formation in eastern Iowa. Similar results have been obtained with carbonate rocks from the Devonian Chaffee formation in south-central Colorado. Some of the rocks in the latter formation have been silicified in nature, and yield siliceous polymers on acid leaching identical to those formed by silicification in the laboratory.
The reaction defined is suggested to be common in natural diagenesis of argillaceous rocks, clay-rich sedimentary material, and soils.
In the case of argillaceous carbonates this reaction affects physical properties of the rock which control processes involved in petroleum migration, ore-metal transfer, rock leaching and all diagenetic reactions that involve solution transfer.
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References
Bigga, D. L. (1957) Petrography and origin of Illinois nodular cherts: Ill. State Geol. Surv., Circ. 245, pp. 1–25.
Bisque, R. E. (1959) Silicification of argillaceous carbonate rocks: Ph. D. thesis, Iowa State Univ. Library, Ames, Iowa.
Bisque, R. E. (1961) Analysis of carbonate rocks for calcium, magnesium, iron and aluminum with EDTA: J. Sed. Petrol., v. 31, pp. 113–123.
Bisque, R. E. and Lemish, John (1958) Chemical characteristics of some carbonate aggregates as related to the durability of concrete: Natl. Acad. Sci.—Natl. Res. Council, Pub. 622; Highway Res. Brd., Bull. 196, pp. 29–45.
Bisque, R. E. and Lemish, John (1959a) Insoluble residue—magnesium content relationship of carbonate rocks from the Devonian Cedar Valley formation: J. Sed. Petrol, v. 29, pp. 73–76.
Bisque, R. E. and Lemish, John (1959b) Silicification of carbonate aggregates in concrete: Natl. Acad. Sci.—Natl. Res. Counc., pub. 725, Highway Res. Brd., Bull. 239, pp. 41–55.
Bisque, R. E. and Lemish, J. (1961) The effect of illitic clay on the chemical stability of carbonate aggregates: Natl. Acad. Sci.—Natl. Res. Counc., pub. 813, Highway Res. Brd., Bull. 275, pp. 32–38.
Carlson, A. B. and Banks, C. V. (1952) Spectrophotometric determination of silicon in the presence of zirconium, beryllium, aluminum and calcium: Anal. Chem., v. 24, pp. 472–482.
Grim, R. E. (1953) Clay Mineralogy: McGraw-Hill Book Co., Inc., New York, 384 pp.
Hiltrop, C. L. and Lemish, John (1959) Treatment of carbonate rocks with a vaporous mixture of (CH3)2SiCl2 and CH3SiCl3: Iowa Acad. Sci. Proc., v. 66, pp. 214–221.
Hiltrop, C. L. and Lemish, John (1960) A method for determining the relative abundance and composition of calcite and dolomite in carbonate rocks: Iowa Acad. Sci. Proc., v. 67, pp. 237–245.
Hiltrop, C. L. and Lemish, John (1960) Relationship of pore-size distribution and other rock properties to serviceability of some carbonate aggregates: Natl. Acad. Sci.—Natl. Res. Council, pub. 725, Highway Res. Brd., Bull. 239, pp. 1–23.
Lemish, John, Rush, F. E. and Hiltrop, C. L. (1958) Relationship of physical properties of some Iowa carbonate aggregates to durability of concrete: Natl. Acad. Sci.—Natl. Bes. Council, pub. 622, Highway Res. Brd., Bull. 196, pp. 1–16.
Mason, Brian (1958) Principles of Geochemistry: John Wiley & Sons, Inc., New York, 310 pp.
Murray, R. C. (1960) Origin of porosity in carbonate rocks: J. Sed. Petrol., v. 30, pp. 59–84.
Ostrom, M. E. (1961) Separation of clay minerals from carbonate rocks by using acid: J. Sed. Petrol., v. 31, pp. 123–125.
Tennant, C. B. and Berger, R. W. (1957) X-ray determination of dolomite-calcite ratio of a carbonate rock: Amer. Min., v. 42, pp. 23–29.
Weyl, P. K. (1960) Porosity through dolomitization: conservation-of-mass requirements: J. Sed. Petrol, v. 30, pp. 85–90.
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Bisque, R.E. Clay Polymerization in Carbonate Rocks: A Silicification Reaction Defined. Clays Clay Miner. 9, 365–373 (1960). https://doi.org/10.1346/CCMN.1960.0090123
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DOI: https://doi.org/10.1346/CCMN.1960.0090123