Abstract
The concept of activation energy for ion movement is discussed. It is shown that the activation energy for exchangeable ion movement is directly correlated with the specific volume of the adsorbed water, with the resistance to freezing of this water and with the activation energy for deuterium oxide diffusion in this water. Electrical interaction between ion and clay appears to have little effect on the activation energy. Consequently, it is concluded that the most important factor governing exchangeable ion movement in the pores of a clay-water system is the structure of the adsorbed water.
Similar content being viewed by others
References
Anderson, D. M. and Low, P. F. (1958) The density of water adsorbed by lithium-, sodium-and potassium-bentonite: Soil Sci. Soc. Amer. Proc, v. 22, 99–103.
Dutt, G. R. (1960) Diffusion in clay-water systems: Ph. D. thesis, Purdue University.
Glasstone, S., Laidler, K. J. and Eyring, H. (1941) The Theory of Mate Processes: McGraw-Hill Co. Inc., New York, 611 pp.
Hemwall, J. B. and Low, P. P. (1956) The hydrostatic repulsive force in clay swelling: Soil Sci., v. 82, 135–145.
Kolaian, J. H. (1960) Thermodynamic and freezing properties of water adsorbed by Wyoming bentonite: Ph. D. thesis, Purdue University.
Low, P. F. (1958) The apparent mobilities of exchangeable alkali metal cations in bentonite-water systems: Soil Sci. Soc. Amer. Proc, v. 22, 395–398.
Low, P. F. and Anderson, D. M. (1958) The partial specific volume of water in bentonite suspensions: Soil Sci. Soc. Amer. Proc., v. 22, 22–24.
Martin, R. T. (1960) Adsorbed water on clay: a review: Preprint of paper presented at 9th Natl. Clay Conf., Purdue University.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Low, P.F. Influence of Adsorbed Water on Exchangeable Ion Movement. Clays Clay Miner. 9, 219–228 (1960). https://doi.org/10.1346/CCMN.1960.0090112
Published:
Issue Date:
DOI: https://doi.org/10.1346/CCMN.1960.0090112