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Clays and Clay Minerals

, Volume 66, Issue 1, pp 28–42 | Cite as

Hydrothermal Experiments Reveal the Influence of Organic Matter on Smectite Illitization

  • Jingong CaiEmail author
  • Jiazong Du
  • Zewen Chen
  • Tianzhu Lei
  • Xiaojun Zhu
Article

Abstract

Smectite illitization is an important diagenetic phenomenon of mudstones, but only rarely has the influence of organic matter (OM) on this process been examined. In the present study, hydrothermal experiments were conducted with smectite (M1, total organic carbon (TOC) <0.3%) and a smectite and N,N-dimethylhexadecylamine (16DMA) complex (M2, TOC >1%). X-ray diffraction (XRD), infrared, X-ray fluorescence (XRF), and organic carbon analyses were employed to characterize the mineralogy and OM of the samples and the effect of OM on smectite illitization. The XRD patterns showed changes in clay mineral parameters with increased temperature. These changes varied in both M1 and M2 and indicated a difference in the degree of smectite illitization. Moreover, the OM in M2 was mainly adsorbed in smectite interlayers, the OM was largely desorbed/decomposed at temperatures above 350°C, and the OM was the main reason for differences in the degree of smectite illitization between M1 and M2. Bulk mineral composition, elemental content, and infrared absorption band intensities were changed with increased temperature (especially above 350°C). This indicated the formation of new minerals (e.g., ankerite). Overall, OM entered the interlayer space of smectite in M2 and delayed the exchange of K+ by interlayer cations, and thus, suppressed the transformation of smectite to illite and resulted in differences in smectite illitization of M1 and M2. In particular, the formation of CO2 after the decomposition of OM at temperatures above 300°C led to the formation of ankerite in M2. This demonstrated the effect of organic-inorganic interactions on smectite illitization and mineral formation. The disparities in smectite illitization between M1 andM2, therefore, were linked to differences in the mineral formation mechanisms of a water-rock system (M1) and a water-rock-OM system (M2) in natural environments. The insights obtained in the present study should be of high importance in understanding organic-mineral interactions, hydrocarbon generation, and the carbon cycle.

Key Words

Hydrothermal Experiments Mineral Formation Mechanism OM Occurrence Smectite Smectite Illitization Smectite-organic Complex 

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References

  1. Ahn, J. and Peacor, D. (1986) Transmission and analytical electron microscopy of the smectite-to-illite transition. Clays and Clay Minerals, 34, 165–179.CrossRefGoogle Scholar
  2. Alstadt, K.N., Katti, D.R., and Katti, K.S. (2012) An in situ FTIR step-scan photoacoustic investigation of kerogen and minerals in oil shale. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 89, 105–113.CrossRefGoogle Scholar
  3. Altaner, S. and Ylagan, R. (1997) Comparison of structural models of mixed-layer illite/smectite and reaction mechanisms of smectite illitization. Clays and Clay Minerals, 45, 517–533.CrossRefGoogle Scholar
  4. Armstrong, D.E. and Chesters, G. (1964) Properties of protein-bentonite complexes as influenced by equilibration conditions. Soil Science, 98, 39–52.CrossRefGoogle Scholar
  5. Arnarson, T.S. and Keil, R.G. (2007) Changes in organic matter—mineral interactions for marine sediments with varying oxygen exposure times. Geochimica et Cosmochimica Acta, 71, 3545–3556.CrossRefGoogle Scholar
  6. Balsam, W.L. and Deaton, B.C. (1991) Sediment dispersal in the Atlantic Ocean: Evaluation by visible light spectra. Reviews in Aquatic Sciences, 4, 411–447.Google Scholar
  7. Baronnet, A. (1997) Silicate microstructures at the sub-atomic scale. Comptes Rendus de l’Académie des Sciences. Série 2. Sciences de la Terre et des Planètes (in French), 324, 157–172.Google Scholar
  8. Berthelin, J. (2010) Soil microorganism-mineral-organic matter interactions and the impact on metal mobility. Pp. 49–51 in: Molecular Environmental Soil Science at the Interfaces in the Earth’s Critical Zone (J. Xu and P.M. Huang, editors). Springer, Hangzhou, China.CrossRefGoogle Scholar
  9. Bethke, C.M. and Altaner, S. (1986) Layer-by-layer mechanism of smectite illitization and application to a new rate law. Clays and Clay Minerals, 34, 136–145.CrossRefGoogle Scholar
  10. Boles, J.R. and Franks, S.G. (1979) Clay diagenesis in Wilcox sandstones of southwest Texas: Implications of smectite diagenesis on sandstone cementation. Journal of Sedimentary Research, 49, 55–70.Google Scholar
  11. Burst, J.F. (1969) Diagenesis of Gulf Coast clayey sediments and its possible relation to petroleum migration. AAPG Bulletin, 53, 73–93.Google Scholar
  12. Cai, J. (2004) Organic-complexes in Muddy Sediment and Mudstone. Science Press, Beijing, China, 212 pp.Google Scholar
  13. Cai, J., Bao, Y., Yang, S., Wang, X., Fan, D., Xu, J., and Wang, A. (2007) Research on preservation and enrichment mechanisms of organic matter in muddy sediment and mudstone. Science China: Earth Science, 50, 765–775.CrossRefGoogle Scholar
  14. Cai, J., Lu, L., Bao, Y., Fan, F., and Xu, J. (2012) The significance and variation characteristics of interlayer water in smectite of hydrocarbon source rocks. Science China: Earth Science, 55, 397–404.CrossRefGoogle Scholar
  15. Cai, J., Song, M., Lu, L., Bao, Y., Ding, F., and Xu, J. (2013) Organo-clay complexes in source rocksùa natural material for hydrocarbon generation. Marine Geology and Quaternary Geology, 33, 123–131.CrossRefGoogle Scholar
  16. Cuadros, J. (2012) Clay crystal-chemical adaptability and transformation mechanisms. Clay Minerals, 47, 147–164.CrossRefGoogle Scholar
  17. Cuadros, J. and Altaner, S.P. (1998) Compositional and structural features of the octahedral sheet in mixed-layer illite/smectite from bentonites. European Journal of Mineralogy, 10, 111–124.CrossRefGoogle Scholar
  18. Cuadros, J. and Linares, J. (1996) Experimental kinetic study of the smectite-to-illite transformation. Geochimica et Cosmochimica Acta, 60, 439–453.CrossRefGoogle Scholar
  19. Dickens, A.F., Baldock, J.A., Smernik, R.J., Wakeham, S.G., Arnarson, T.S., Gélinas, Y., and Hedges, J.I. (2006) Solid-state 13C NMR analysis of size and density fractions of marine sediments: Insight into organic carbon sources and preservation mechanisms. Geochimica et Cosmochimica Acta, 70, 666–686.CrossRefGoogle Scholar
  20. Ding, C. and Shang, C. (2010) Mechanisms controlling adsorption of natural organic matter on surfactant-modified iron oxide-coated sand. Water Research, 44, 3651–3658.CrossRefGoogle Scholar
  21. Drits, V.A., Lindgreen, H., and Salyn, A.L. (1997) Determination of the content and distribution of fixed ammonium in illite-smectite by X-ray diffraction: Application to North Sea illite-smectite. American Mineralogist, 82, 79–87.CrossRefGoogle Scholar
  22. Eberl, D. (1978) Reaction series for dioctahedral smectites. Clays and Clay Minerals, 26, 327–340.CrossRefGoogle Scholar
  23. Eberl, D. and Srodon, J. (1988) Ostwald ripening and interparticle-diffraction effects for illite crystals. American Mineralogist, 73, 1335–1345.Google Scholar
  24. Egli, M., Mirabella, A., and Fitze, P. (2001) Clay mineral transformations in soils affected by fluorine and depletion of organic matter within a time span of 24 years. Geoderma, 103, 307–334.CrossRefGoogle Scholar
  25. GBT 14506.28-2010, 2010. Methods for chemical analysis of silicate rocks-Part 28: Determination of 16 major and minor elements content. Standards Press of China, Beijing.Google Scholar
  26. Ge, Y., Liu, L., and Ji, J. (2009) Rapid quantification of calcite in North Atlantic sediments by drifts and its climate significance-example of drilling site U1308. Geological Journal of China Universities, 15, 184–191.Google Scholar
  27. Greenwood, P., Brocks, J., Grice, K., Schwark, L., Jaraula, C., Dick, J., and Evans, K. (2013) Organic geochemistry and mineralogy. I. Characterisation of organic matter associated with metal deposits. Ore Geology Reviews, 50, 1–27.CrossRefGoogle Scholar
  28. Grim, R.E. (1953) Clay Mineralogy. McGraw-Hill, New York, 596 pp.CrossRefGoogle Scholar
  29. Hanke, A., Sauerwein, M., Kaiser, K., and Kalbitz, K. (2014) Does anoxic processing of dissolved organic matter affect organic—mineral interactions in paddy soils? Geoderma, 228, 62–66.CrossRefGoogle Scholar
  30. He, H., Frost, R.L., Bostrom, T., Yuan, P., Duong, L., Yang, D., Xi, Y., and Kloprogge, J.T. (2006) Changes in the morphology of organoclays with HDTMA+ surfactant loading. Applied Clay Science, 31, 262–271.CrossRefGoogle Scholar
  31. He, H., Guo, J., Xie X., and Pen, J.(1999) Experimental studies on the selective adsorption of Cu2+, Pb2+, Zn2+, Cd2+, Cr2+ ions on montmorillonite, illite and kaolinite and the influence of medium conditions. Acta Mineralogical Sinica, 19, 231–235.Google Scholar
  32. He, K., Zhang, S., Wang, X., Mi, J., Mao, R., and Hu, G. (2013) Effect of gas generation from in situ cracking of residual bitumen in source on hydrocarbon generation from organic matter. Acta Petrolei Sinica, 34, 57–64.Google Scholar
  33. Howard, J.J. and Roy, D. (1985) Development of layer charge and kinetics of experimental smectite alteration. Clays and Clay Minerals, 33, 81–88.CrossRefGoogle Scholar
  34. Hower, J., Eslinger, E.V., Hower, M.E., and Perry, E.A. (1976) Mechanism of burial metamorphism of argillaceous sediment: 1. Mineralogical and chemical evidence. Geological Society of America Bulletin, 87, 725–737.CrossRefGoogle Scholar
  35. Huang, W.L., Longo, J.M., and Pevear, D.R. (1993) An experimentally derived kinetic model for smectite-to-illite conversion and its use as a geothermometer. Clays and Clay Minerals, 41, 162–162.CrossRefGoogle Scholar
  36. Inoue, A., Kohyama, N., Kitagawa, R., and Watanabe, T. (1987) Chemical and morphological evidence for the conversion of smectite to illite. Clays and Clay Minerals, 35, 111–120.CrossRefGoogle Scholar
  37. Inoue, A., Watanabe, T., Kohyama, N., and Brusewitz, A.M. (1990) Characterization of illitization of smectite in bentonite beds at Kinnekulle, Sweden. Clays and Clay Minerals, 38, 241–249.CrossRefGoogle Scholar
  38. Kennedy, M.J., Pevear, D.R., and Hill, R.J. (2002) Mineral surface control of organic carbon in black shale. Science, 295, 657–660.CrossRefGoogle Scholar
  39. Kothawala, D., Roehm, C., Blodau, C., and Moore, T. (2012) Selective adsorption of dissolved organic matter to mineral soils. Geoderma, 189, 334–342.CrossRefGoogle Scholar
  40. Lanson, B., Sakharov, B.A., Claret, F., and Drits, V.A. (2009) Diagenetic smectite-to-illite transition in clay-rich sediments: A reappraisal of X-ray diffraction results using the multi-specimen method. American Journal of Science, 309, 476–516.CrossRefGoogle Scholar
  41. Lasaga, A.C. and Luttge, A. (2001) Variation of crystal dissolution rate based on a dissolution stepwave model. Science, 291, 2400–2404.CrossRefGoogle Scholar
  42. Leithold, E.L., Perkey, D.W., Blair, N.E., and Creamer, T.N. (2005) Sedimentation and carbon burial on the northern California continental shelf: The signatures of land-use change. Continental Shelf Research, 25, 349–371.CrossRefGoogle Scholar
  43. Li, J. and David, J.B. (2005) Palynofacies: Principles and methods. Acta Palaeontologica Sinica, 44, 138–156.Google Scholar
  44. Li, Y., Cai, J., Song, G., and Ji, J. (2015) Drift spectroscopic study of diagenetic organic-clay interactions in argillaceous source rocks. Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 148, 138–145.CrossRefGoogle Scholar
  45. Li, Y., Cai, J., Song, M., Ji, J., and Bao, Y. (2016) Influence of organic matter on smectite illitization: A comparison between red and dark mudstone from the Dongying Depression, China. American Mineralogist, 101, 134–145.CrossRefGoogle Scholar
  46. Liu, W., Ni, Y., and Xiao, H. (2005) Preparation and characterization of hydrophobic cationic montmorillonite. Transactions of China Pulp and Paper, 20, 169–173.Google Scholar
  47. Lu, L., Cai, J., Liu, W., Teng, E., and Hu, W. (2011) Water bridges mechanism of organo smectite interaction in argillaceous hydrocarbon source rocks: Evidences from in situ drift spectroscopic study. Oil & Gas Geology, 32, 47–55.Google Scholar
  48. Lu, X., Hu, W., Fu, Q., Miao, D., Zhou, G., and Hong, Z. (1999) Study of combination pattern of soluble organic matters and clay minerals in the immature source rocks in Dongying Depression, China. Scientia Geologica Sinica, 34, 72–80.Google Scholar
  49. Mayer, L.M. (1994) Surface area control of organic carbon accumulation in continental shelf sediments. Geochimica et Cosmochimica Acta, 58, 1271–1284.CrossRefGoogle Scholar
  50. Metwally, Y.M. and Chesnokov, E.M. (2012) Clay mineral transformation as a major source for authigenic quartz in thermo-mature gas shale. Applied Clay Science, 55, 138–150.CrossRefGoogle Scholar
  51. Moore, D.M. and Reynolds, R.C. (1997). X-ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, New York, 332 pp.Google Scholar
  52. Mosser-Ruck, R., Cathelineau, M., Baronnet, A., and Trouiller, A. (1999) Hydrothermal reactivity of K-smectite at 300°C and 100 bar: Dissolution-crystallization process and non-expandable dehydrated smectite formation. Clay Minerals, 34, 275–290.CrossRefGoogle Scholar
  53. Mosser-Ruck, R., Pironon, J., Cathelineau, M., and Trouiller, A. (2001) Experimental illitization of smectite in K-rich solution. European Journal of Mineralogy, 13, 829–840.CrossRefGoogle Scholar
  54. Nadeau, P., Wilson, M., McHardy, W., and Tait, J. (1985) The conversion of smectite to illite during diagenesis: Evidence from some illitic clays from bentonites and sandstones. Mineralogical Magazine, 49, 393–400.CrossRefGoogle Scholar
  55. Naderizadeh, Z., Khademi, H., and Arocena, J. (2010) Organic matter induced mineralogical changes in clay-sized phlogopite and muscovite in alfalfa rhizosphere. Geoderma, 159, 296–303.CrossRefGoogle Scholar
  56. Nemecz, E. (1981) Clay Minerals. Akademiai Kiado, Budapest, Hungary, 547 pp.Google Scholar
  57. Nguyen, T., Janik, L.J., and Raupach, M. (1991) Diffuse reflectance infrared fourier transform (drift) spectroscopy in soil studies. Soil Research, 29, 49–67.CrossRefGoogle Scholar
  58. Olives, J., Amouric, M., and Perbost, R. (2000) Mixed layering of illite-smectite: Results from high-resolution transmission electron microscopy and lattice-energy calculations. Clays and Clay Minerals, 48, 282–289.CrossRefGoogle Scholar
  59. Pacton, M., Gorin, G.E., and Vasconcelos, C. (2011) Amorphous organic matter — experimental data on formation and the role of microbes. Review of Palaeobotany and Palynology, 166, 253–267.CrossRefGoogle Scholar
  60. Parbhakar, A., Cuadros, J., Sephton, M.A., Dubbin, W., Coles, B.J., and Weiss, D. (2007) Adsorption of l-lysine on montmorillonite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 307, 142–149.CrossRefGoogle Scholar
  61. Pearson, M. and Small, J. (1988) Illite-smectite diagenesis and palaeotemperatures in northern North Sea Quaternary to Mesozoic shale sequences. Clay Minerals, 23, 109–132.CrossRefGoogle Scholar
  62. Peltonen, C., Marcussen, Ø., Bjørlykke, K., and Jahren, J. (2009) Clay mineral diagenesis and quartz cementation in mudstones: The effects of smectite to illite reaction on rock properties. Marine and Petroleum Geology, 26, 887–898.CrossRefGoogle Scholar
  63. Pentrák, M., Bizovská, V. and Madejová, J. (2012) Near-IR study of water adsorption on acid-treated montmorillonite. Vibrational Spectroscopy, 63: 360–366.CrossRefGoogle Scholar
  64. Pérez, M.A., Moreira-Turcq, P., Gallard, H., Allard, T., and Benedetti, M.F. (2011) Dissolved organic matter dynamic in the Amazon basin: Sorption by mineral surfaces. Chemical Geology, 286, 158–168.Google Scholar
  65. Perry, E.A. and Hower, J. (1970) Burial diagenesis in Gulf Coast pelitic sediments. Clays and Clay Minerals, 18, 165–177.CrossRefGoogle Scholar
  66. Pollard, C.O. (1971) Appendix: Semidisplacive mechanism for diagenetic alteration of montmorillonite layers to illite layers. Geological Society of America Special Papers, 134, 79–94.CrossRefGoogle Scholar
  67. Pusino, A., Liu, W., and Gessa, C. (1993) Dimepiperate adsorption and hydrolysis on Al3+, Fe3+, Ca2+, and Na+ montmorillonite. Clays and Clay Minerals, 41, 335–340.CrossRefGoogle Scholar
  68. Putnis, A. (2002) Mineral replacement reactions: From macroscopic observations to microscopic mechanisms. Mineralogical Magazine, 66, 689–708.CrossRefGoogle Scholar
  69. Ramseyer, K. and Boles, J. (1986) Mixed-layer illite/smectite minerals in Tertiary sandstones and shales, San Joaquin Basin, California. Clays and Clay Minerals, 34, 115–124.CrossRefGoogle Scholar
  70. Reynolds, R.C. (1985). NEWMOD, A Computer Program for the Calculation of One-dimensional Diffraction Patterns of Mixed-layered Clays. Self-published, Hanover, New Hampshire.Google Scholar
  71. Roberson, H.E. and Lahann, R.W. (1981) Smectite to illite conversion rates: Effects of solution chemistry. Clays and Clay Minerals, 29, 129–135.CrossRefGoogle Scholar
  72. Schulten, H.R., Leinweber, P., and Theng, B. (1996) Characterization of organic matter in an interlayer clay-organic complex from soil by pyrolysis methylation-mass spectrometry. Geoderma, 69, 105–118.CrossRefGoogle Scholar
  73. Środoń, J., Elsass, F., McHardy, W., and Morgan, D. (1992) Chemistry of illite-smectite inferred from TEM measurements of fundamental particles. Clay Minerals, 27, 137–158.CrossRefGoogle Scholar
  74. Theng, B.K.G. (1974) The Chemistry of Clay-organic Reactions. Wiley, New York, USA, 343 pp.Google Scholar
  75. Theng, B.K.G. (1979) Formation and Properties of Clay-polymer Complexes. Elsevier, Amsterdam, Netherlands, 362 pp.Google Scholar
  76. Theng, B.K.G., Churchman, G., and Newman, R. (1986) The occurrence of interlayer clay-organic complexes in two New Zealand soils. Soil Science, 142, 262–266.CrossRefGoogle Scholar
  77. Thyberg, B., Jahren, J., Winje, T., Bjørlykke, K., Faleide, J.I., and Marcussen, Ø. (2010) Quartz cementation in Late Cretaceous mudstones, northern North Sea: Changes in rock properties due to dissolution of smectite and precipitation of micro-quartz crystals. Marine and Petroleum Geology, 27, 1752–1764.CrossRefGoogle Scholar
  78. Tissot, B. and Welte, D. (1984) Petroleum Formation and Occurrence: A New Approach to Oil and Gas Exploration. Springer, Berlin, Germany, 699 pp.CrossRefGoogle Scholar
  79. Tyson, R.V. (1993) Palynofacies analysis. Pp. 153–191 in: Applied Micropalaeontology (D.G. Jenkins, editor). Springer, Netherlands.CrossRefGoogle Scholar
  80. Velde, B. and Vasseur, G. (1992) Estimation of the diagenetic smectite to illite transformation in time-temperature space. American Mineralogist, 77, 967–976.Google Scholar
  81. Wang S. (1998) Stability of interlayer water of montmorillonite under burial conditions. Bulletin of Mineralogy, Petrology and Geochemistry, 17, 211–216.Google Scholar
  82. Whitney, G. (1990) Role of water in the smectite-to-illite reaction. Clays and Clay Minerals, 38, 343–350.CrossRefGoogle Scholar
  83. Whitney, G. and Velde, B. (1993) Changes in particle morphology during illitization: An experimental study. Clays and Clay Minerals, 41, 209–218.CrossRefGoogle Scholar
  84. Xu, S. and Harsh, J.B. (1992) Alkali cation selectivity and surface charge of 2:1 clay minerals. Clays and Clay Minerals, 40, 567–567.CrossRefGoogle Scholar
  85. Yang, Y., Lei, T., Xing, L., Cai, J., Wu, Y., and Si, G. (2015) Oil generation abilities of chemically bound organic matter in different types of organic clay complexes. Petroleum Geology & Experiment, 37, 487–493.CrossRefGoogle Scholar
  86. Yariv, S. and Cross, H. (2002) Organo-clay Complexes and Interactions. Dekker, New York, USA, 688 pp.Google Scholar
  87. Yariv, S. and Lapides, I. (2005) The use of thermo-XRD-analysis in the study of organo-smectite complexes. Journal of Thermal Analysis and Calorimetry, 80, 11–26.CrossRefGoogle Scholar
  88. Zheng, M., Li, J., Wu, X., Wang, M., Chen, X., and Wang, G. (2014) High-temperature pyrolysis gas-sourcing potential of organic matter in marine shale source rock system. China Petroleum Exploration, 19, 1–11.Google Scholar

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© Clay Minerals Society 2018

Authors and Affiliations

  • Jingong Cai
    • 1
    Email author
  • Jiazong Du
    • 1
  • Zewen Chen
    • 1
  • Tianzhu Lei
    • 2
  • Xiaojun Zhu
    • 1
  1. 1.State Key Laboratory of Marine GeologyTongji UniversityShanghaiChina
  2. 2.Lanzhou Institute of GeologyChinese Academy of SciencesLanzhouChina

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