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Clays and Clay Minerals

, Volume 37, Issue 5, pp 469–473 | Cite as

Mechanisms of Palygorskite and Sepiolite Alteration as Deduced from Solid-State 27A1 and 29Si Nuclear Magnetic Resonance Spectroscopy

  • Sridhar Komarneni
Article

Abstract

The mechanisms of palygorskite and sepiolite alteration to smectite under mild hydrothermal conditions were investigated by solid-state 27Al and 29Si magic-angle spinning-nuclear magnetic resonance (MAS-NMR) spectroscopy, X-ray powder diffraction (XRD) and transmission electron microscopy (TEM). Palygorskite altered to smectite in the presence of NaOH at 150°C. 27Al MAS-NMR spectroscopy showed that the Al coordination changed from chiefly octahedral in palygorskite to chiefly tetrahedral in the smectite product. 29Si MAS-NMR spectroscopy showed that the nearest neighbor environment of Si also changed when palygorskite altered to smectite. The XRD data showed that the synthetic smectite is trioctahedral in nature with tetrahedral charge. The TEM results revealed that the needle-like morphology of palygorskite was preserved in the product smectite. The MAS-NMR results in conjunction with the above XRD and TEM studies suggest that the mechanism of palygorskite alteration was a dissolution and recrystallization process rather than a solid-state reorganization to form 2:1 layer silicate units from the preexisting chain structure. Sepiolite altered to smectite in the presence of 2 N salt solutions at 300°C. The trioctahedral nature of the product smectite as detected by XRD and the foil-like morphology of product smectite as shown by TEM suggest that the mechanism of sepiolite transformation to smectite was also a dissolution and recrystallization process. The tetrahedral Al coordination detected by 27Al MAS-NMR in the smectite altered from sepiolite corroborated the XRD and TEM results.

Key Words

Al coordination Hydrothermal transformation Nuclear magnetic resonance Palygorskite Sepiolite Smectite X-ray powder diffraction 

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Copyright information

© The Clay Minerals Society 1989

Authors and Affiliations

  • Sridhar Komarneni
    • 1
  1. 1.Materials Research Laboratory and Department of AgronomyThe Pennsylvania State UniversityUniversity ParkUSA

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