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Charge-transfer absorption of olefins with nitrosonium. Structural relevance to the dimethylbutene complex with dinitrogen tetraoxide

Research on Chemical Intermediates volume 22, pages 209–224 (1996)Cite this article

Abstract

The transient electron donor-acceptor (EDA) complexes of various olefins (dimethylbutene, etc.) with the nitrosonium acceptor (NO+) show diagnostic charge-transfer absorption bands in dichloromethane solutions at low temperatures. Since the same charge-transfer absorption bands are observed when olefins are exposed to dinitrogen tetraoxide, they are ascribed to analogous EDA complexes [olefin, NO+] NO3 − that are derived from the ionic disproportionation of nitrogen dioxide.

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  1. Department of Chemistry, University of Houston, 77204-5641, Houston, Texas, USA

    Eric Bosch & Jay K. Kochi

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  1. Eric Bosch
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Bosch, E., Kochi, J.K. Charge-transfer absorption of olefins with nitrosonium. Structural relevance to the dimethylbutene complex with dinitrogen tetraoxide. Res. Chem. Intermed. 22, 209–224 (1996). https://doi.org/10.1163/156856796X00412

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  • DOI: https://doi.org/10.1163/156856796X00412

Keywords

  • Nitrogen Dioxide
  • Nitrosonium
  • Dimethylbutene
  • Nitrosyl Chloride
  • Antimony Pentachloride