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Cage effect in the CIDEP observation of the photolysis of the pyruvic-lactic acid system

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Abstract

Strong intermolecular interactions in pyruvic acid/lactic acid solutions result in the observation of several unusual effects in the CIDEP spectra detected after photolysis. These effects are discussed in terms of a free diffusion model and a cage model of the radical pair mechanism of CIDEP.

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Authors and Affiliations

  1. Department of Chemistry, Queen’s University, K7L 3N6, Kingston, Canada

    A. I. Shushin, M. C. Depew & J. K. S. Wan

Authors
  1. A. I. Shushin
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  2. M. C. Depew
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  3. J. K. S. Wan
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Shushin, A.I., Depew, M.C. & Wan, J.K.S. Cage effect in the CIDEP observation of the photolysis of the pyruvic-lactic acid system. Res Chem Intermed 16, 165–178 (1991). https://doi.org/10.1163/156856791X00237

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  • DOI: https://doi.org/10.1163/156856791X00237

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