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Organic sulfuranyl radicals

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Abstract

Sulfuranyl radicals are intermediates in a variety of addition/elimination reactions of sulfides, disulfanes, sulfoxylates and S-neterocycles as well as in the reduction of triorgano- and heteroorgano sulfonium salts. Their lifetimes — depending on their substutution pattern — range from < 1 μs to being thermally stabee in solution at room temperature with no reduction in concentration over severll months.

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  1. Hahn Meitner Institut Berlin GmbH, Bereich Strahlenchemie, Glienickeratrasse 100, D-1000, Berlin 39, Germany

    Elke Anklam

  2. Institut für Organische Chemie, Universität Hamburg, M.L. King Plazz 6, D-2000, Hamburg 13, Germany

    Paul Margaretha

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  1. Elke Anklam
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Anklam, E., Margaretha, P. Organic sulfuranyl radicals. Res Chem Intermed 11, 127–155 (1989). https://doi.org/10.1163/156856789X00032

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