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The antioxidant reactivity of sorbitylfurfural towards potential harmful radicals, studied by radiation chemistry techniques

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Abstract

Ionising radiations, employed in a broad range of dose-rate, together with a complex non-linear computation of reaction mechanisms, allow the determination of boundary values of rate constants concerning sorbitylfurfural (SF) reactivity towards a wide series of oxidant and/or virtually harmful radicals. SF reacts with some radicals (H, SO4 -·, CO3 -·, Br2 -·, CH3 ·), produced with both pulse and stationary radiolysis in neutral aqueous solution, having electrophilic and/or oxidative behaviour. The rate constants range from diffusional (k = (7–9 ) × 109 M-1 s-1) to relatively low values (k = 2 × 105 M-1 s-1). The possibility to observe these reactions, by means of radiolytical techniques, is heavily influenced by dose-rate. A relation between the radical E NHE 0 and their reactivity with SF is hinted.

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Authors
  1. M. Russo
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  2. L. Sgariglia
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  3. M. D'Angelantonio
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  4. S.S. Emmi
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Russo, M., Sgariglia, L., D'Angelantonio, M. et al. The antioxidant reactivity of sorbitylfurfural towards potential harmful radicals, studied by radiation chemistry techniques. Research on Chemical Intermediates 30, 253–267 (2004). https://doi.org/10.1163/1568567041257544

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