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Ruthenium-tin sol-gel catalysts: effect of the preparation and tin precursor influence

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Abstract

The influence of the synthesis route and the chemical nature of tin precursors on the catalytic properties of supported sol-gel Ru-Sn/SiO2 catalysts were studied. It was demonstrated that introduction of tin afforded better selectivities than a monometallic sol-gel catalyst in the liquid-phase hydrogenation of cinnamaldehyde; however, the chemical nature of the tin precursor did not influence the catalyst performance. Sol-gel catalyst properties depended significantly upon the preparation method used and on the activation temperature. The selectivity to unsaturated alcohol increased with conversion, which is indicative of the in-situ creation of active sites selective in the carbonyl bond hydrogenation.

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Authors
  1. J. Hájek
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  2. P. Kačer
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  3. D. Yu. Murzin
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  4. L. Červený
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Hájek, J., Kačer, P., Murzin, D.Y. et al. Ruthenium-tin sol-gel catalysts: effect of the preparation and tin precursor influence. Research on Chemical Intermediates 28, 561–573 (2002). https://doi.org/10.1163/15685670260373326

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