Abstract
Catalytic oxidation rate of 2-ethyl-5,6,7,8-tetrahydro-9,10-anthrahydroquinone (ETHAHQ) using oxygen in a stirred reactor was studied. It was found that NaOH and some amines exhibit catalytic properties suitable for this oxidation. In the presence of NaOH with its amountof-substance concentration of 2 mmol/l(l)-phase, five times increased reaction rate is achieved. Additionally, mineral acids (sulphuric and phosphoric) and antioxidants (diphenylamine, N-isopropyl4-diphenylamine) were used for a thorough study of partial mechanism steps and their rates during oxidation. Experimental results were used for determination of the rate limiting step of the ETHAHQ oxidation. It was the hydrogen elimination from hydroxyl of hydroquinone.
Similar content being viewed by others
REFERENCES
E. Santacesaria, R. Ferro, S. Ricci and S. Carra, Ind. Eng. Chem. Res. 26 (1), 155 (1987).
P. I. Filimonov, O. M. Smirnova, J. I. Derbencev and A. I. Gorbunov, Dokl. Akad. Nauk SSSR 233 (3), 453 (1977).
F. G. Boyaci, S. Takac and T. H. Özdamar, Appl. Catal.: General 172, 59 (1998).
T. Berglin and N.-H. Shöön, Ind. Chem. Process Des. Dev. 22, 150 (1983).
L. Cervený, V. Heral, A. Marhoul and V. Ruzicka, Chem. Listy 68, 1285 (1974).
J. Pospíšil, in: Antioxidanty, p. 56. SNTL, Praha (1968).
A. Sadana and J. R. Katzer, J. Catal. 35, 140 (1974).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kurc, L., Vopravil, V. & CČervený, L. Catalytic oxidation of 2-ethyl-5,6,7,8-tetrahydro-9,10-anthrahydroquinone. Research on Chemical Intermediates 27, 249–258 (2001). https://doi.org/10.1163/156856701300356464
Issue Date:
DOI: https://doi.org/10.1163/156856701300356464