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EPR studies of “self-spin-probing” reactions between the carbanion of nitroalkanes and ω-hydroperfluorodiacyl peroxides

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Abstract

The mechanism of “self-spin-probing” reactions between carbanion of nitroalkanes (1) and ω-hydroperfluorodiacyl peroxides (2) initiated by electron transfer has been verified by EPR detection of new bis(ω-hydroperfluoro-dialkyl) nitroxides (11) and ω-hydroperfluoroalkyl nitroalkyl nitroxides (12) — spin adducts of radical intermediates H(CF2CF2)n · (n=1,2,3) and R1R2C·NO2 to the nitroso trap H(CFCF)nNO (9) generated in the reactions.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Shanghai Jiao-Tong University, 800 Dongchuan Road, Shanghai, 200240, China

    C. -X. Zhao, Y. -L. Qu & G. -F. Chen

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  1. C. -X. Zhao
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  2. Y. -L. Qu
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  3. G. -F. Chen
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Zhao, C.X., Qu, Y.L. & Chen, G.F. EPR studies of “self-spin-probing” reactions between the carbanion of nitroalkanes and ω-hydroperfluorodiacyl peroxides. Res Chem Intermed 26, 365–374 (2000). https://doi.org/10.1163/156856700X00318

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  • DOI: https://doi.org/10.1163/156856700X00318

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