Abstract
Bimetallic ruthenium-tin catalysts were prepared using the sol-gel method and the method of carrier impregnation. Two different procedures were used for their reduction — reduction in hydrogen atmosphere under an increased temperature, and reduction using an aqueous solution of sodium borohydride. Hydrogenation of 3-phenylpropenal (cinnamaldehyde) in tetrahydrofuran at 433 K and the total pressure 7 MPa was used as the model reaction for comparing the catalytic properties of the prepared catalysts. It was demonstrated that a tin addition notably affected catalytic properties of ruthenium in the sense of a selectivity increment related to the production of an unsaturated alcohol.
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Kuzma, M., Červený, L. Cinnamaldehyde hydrogenation using ruthenium-tin catalyst type. Res Chem Intermed 26, 347–356 (2000). https://doi.org/10.1163/156856700X00291
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DOI: https://doi.org/10.1163/156856700X00291