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Research on Chemical Intermediates

, Volume 24, Issue 4, pp 359–372 | Cite as

A key to progress: Identification of the state of catalysts during the catalytic reaction

  • B. Delmon
  • S. Zeyss
  • E. Gaigneauz
  • P. Ruiz
Article

Abstract

We stress the importance of identifying the state in which catalysts are during the catalytic reaction. Catalysts as prepared do not correspond to the real working catalyst. Several examples will be recalled, and a new one (Mo-Te-O catalyst) will be mentioned. In a more detailed way, it will be shown that the working state of MoO3 is MoxO3x-2 with 8 ≤x≤18. The pitfalls encountered when focusing on catalysts as prepared (as opposed to catalysts “as they work”) is illustrated in the case of mixed SbxMoyOz oxides which decompose spontaneously during the reaction.

Keywords

Catalytic Reaction Tellurium Riser Selective Oxidation Isobutene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer 1998

Authors and Affiliations

  • B. Delmon
    • 1
  • S. Zeyss
    • 1
  • E. Gaigneauz
    • 2
  • P. Ruiz
    • 1
  1. 1.Unité de catalyse et chimie des matériaux divisésUniversité catholique de LouvainLouvain-la-Neuve(Belgium)
  2. 2.Fonds National de la Recherche Scientifique(Belgium)

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