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Research on Chemical Intermediates

, Volume 26, Issue 7–8, pp 679–689 | Cite as

Photoinduced Electron Transfer Oxygenations of 4-Arylmethylene-1,3(2H,4H)-isoquinolinediones via their anion radical intermediates

  • Xiao -Long Wang
  • Jing -Zhi Tian
  • Ke -Qing Ling
  • Jian -Hua Xu
Article

Abstract

Photoinduced Electron Transfer Oxygenations of 4-Arylmethylene-1,3(2H,4H)-isoquinolinediones afforded oxiranes (5a-5c, 6a-6c, 7) and 1, 3, 4-isoquinolinetriones (8 and 9) as major products in high yields in the presence of triethylamine (TEA). These oxygenation reactions are initiated by single electron transfer between photoexcited 4-Arylmethylene-1,3(2H,4H)-isoquinolinediones and TEA, and proceeded via the anion radicals of the substrates.

Keywords

Petroleum Ether Singlet Oxygen Colorless Crystal Oxirane Single Electron Transfer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer 2000

Authors and Affiliations

  • Xiao -Long Wang
    • 1
  • Jing -Zhi Tian
    • 1
  • Ke -Qing Ling
    • 1
  • Jian -Hua Xu
    • 1
  1. 1.Department of ChemistryNanjing UniversityNanjingP. R. China

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