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The European Physical Journal Special Topics

, Volume 226, Issue 5, pp 905–912 | Cite as

Thermal expansion of L-ascorbic acid

  • B. Nicolaï
  • M. Barrio
  • J. -Ll. Tamarit
  • R. Céolin
  • I. B. Rietveld
Regular Article
Part of the following topical collections:
  1. Phase Equilibria and Their Applications

Abstract

The specific volume of vitamin C has been investigated by X-ray powder diffraction as a function of temperature from 110 K up to complete degradation around 440 K. Its thermal expansion is relatively small in comparison with other organic compounds with an expansivity α v of 1.2(3) × 10−4 K−1. The structure consists of strongly bound molecules in the ac plane through a dense network of hydrogen bonds. The thermal expansion is anisotropic. Along the b axis, the expansion has most leeway and is about 10 times larger than in the other directions.

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Copyright information

© EDP Sciences and Springer 2017

Authors and Affiliations

  • B. Nicolaï
    • 1
  • M. Barrio
    • 2
  • J. -Ll. Tamarit
    • 2
  • R. Céolin
    • 3
  • I. B. Rietveld
    • 1
  1. 1.Caracterisation des Matériaux Moléculaires à Activité Thérapeutique (CAMMAT), Faculté de Pharmacie, Université Paris DescartesParisFrance
  2. 2.Grup de Caracteritzacio de Materials (GCM), Departament de Fisica, Campus Diagonal-Besòs, Universitat Politecnica de Catalunya, EEBE, Eduard Maristany, 10-14BarcelonaSpain
  3. 3.LETIAM, EA7357, IUT Orsay, université Paris Sud, rue NoetzlinOrsay CedexFrance

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