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Cation exchange dynamics confined in a synthetic clay mineral

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Abstract

In this work we report X-Ray Diffraction (XRD) and Energy Dispersive X-Ray Spectroscopy (EDS) measurements to investigate the confined cation exchange process in saline aqueous suspensions of a synthetic clay mineral from Lithium-Fluorohectorite to Nickel-Fluorohectorite, as well as the reverse process from Nickel-Fluorohectorite to Lithium-Fluorohectorite and also from Lithium-Fluorohectorite to Sodium-Fluorohectorite. The dynamics of these cation exchanges was followed and it was observed that these processes can be faster than 1 minute. The results are compared to the observations on samples prepared by cation exchange procedures for which the exchange process was performed on the time-scale of months.

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Authors and Affiliations

  1. Instituto de Física, Universidade de Brasília, 70.919-970, Brasília - DF, Brazil

    G. Grassi, M. A. S. Altoé, C. L. S. da Fonseca & G. J. da Silva

  2. Department of Physics, Norwegian University of Science and Technology, 7491, Trondheim, Norway

    G. Grassi, L. Michels, Z. Rozynek, E. C. dos Santos & J. O. Fossum

  3. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland

    Z. Rozynek

  4. Universidade Federal do ABC, 09.210-580, Santo André – SP, Brazil

    R. Droppa Jr.

  5. Laboratório de Microhidrodinâmica e Escoamento em Meios Porosos, Department of Mechanical Engineering, Pontifícia Universidade Católica do Rio de Janeiro, 22.451-263, Rio de Janeiro – RJ, Brazil

    A. Gholamipour-Shirazi

  6. Centro de Componentes Semicondutores, Universidade Estadual de Campinas, 13.083-870, Campinas – SP, Brazil

    A. Gholamipour-Shirazi

Authors
  1. G. Grassi
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  2. L. Michels
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  3. Z. Rozynek
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  4. M. A. S. Altoé
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  5. E. C. dos Santos
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  6. C. L. S. da Fonseca
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  7. R. Droppa Jr.
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  8. A. Gholamipour-Shirazi
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  9. J. O. Fossum
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  10. G. J. da Silva
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Corresponding authors

Correspondence to G. Grassi or J. O. Fossum.

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Grassi, G., Michels, L., Rozynek, Z. et al. Cation exchange dynamics confined in a synthetic clay mineral. Eur. Phys. J. Spec. Top. 223, 1883–1893 (2014). https://doi.org/10.1140/epjst/e2014-02233-8

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  • DOI: https://doi.org/10.1140/epjst/e2014-02233-8

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