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Spurious character of singularities associated with phase transitions in cylindrical pores

  • K. BinderEmail author
  • P. Virnau
  • D. Wilms
  • A. Winkler
Regular Article

Abstract

Phase transitions of simple fluids and binary fluid mixtures confined into long cylindrical pores are re-examined, such as capillary condensation/evaporation and wetting transitions. While a large part of the literature ignores the fact that due to the quasi-one-dimensional character of these systems a singular behavior associated with a sharp phase transition cannot occur, we pay attention to the extent in which these phase transitions are smoothed out (in relation to the magnitude of the pore cross-sectional area). We argue that the finiteness of the pore length is an important parameter which controls the physical phenomena that are observed in simulations (and presumably also experiments explaining the distinction between the apparent “pore critical temperature” and the “hysteresis critical temperature”). We illustrate our arguments with recent findings from simulations of a lattice gas/Ising system and of the Asakura-Oosawa model of colloid-polymer mixtures.

Keywords

Domain Wall European Physical Journal Special Topic Ising Model Hard Wall Cylindrical Pore 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© EDP Sciences and Springer 2011

Authors and Affiliations

  1. 1.Institut für PhysikJohannes Gutenberg-Universität MainzMainzGermany

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