Abstract
We report investigations on the processing by Spark Plasma Sintering (SPS) of RE2Fe14B (RE = Nd, Pr…) powders obtained by hydrogen decrepitation of decommissioned magnets and the magnetic properties of the consolidated magnets. First experiments have been carried out with a commercial powder to make clear the mechanisms occurring during the powder densification. The magnetic properties of the sintered bulks were measured to determine the SPS cycle resulting in the best saturation and remanent magnetization (Ms and Mr, respectively), coercive field (Hc) and stored magnetic energy (BHmax product). The optimized cycle was subsequently applied to a recycled powder. The properties of the magnets obtained after processing the recycled powder are compared to those made with the commercial one.
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References
J.W. Lyman, G.R. Palmer, Recycling of rare earths and iron from NdFeB magnet scrap. High Temp Mater Process 11, 175–187 (1993)
D. Guyonnet, G. Lefebvre, N. Menad (2015) Challenges and innovation in recycling, ENSCP Chimie Paristech
S. Ahonen et al. (2015) Strengthening the European rare-earths supply-chain. Challenges and policy options. Report by the Europe Report Rare Earths competency network (ERECON)
J. Seaman (2019) Rare earths and China—a review of changing criticality in the new economy. Notes de l’IFRI (Institut Français des Relations Internationales), Janvier
M. Zakotnik, E. Devlin, I.R. Harris, A.J. Williams, Hydrogen decrepitation and recycling of NdFeB-type sintered magnets. J. Iron. Steel Res. Int. 13(Suppl. 1), 289–295 (2006)
M. Zakotnik, I.R. Harris, A.J. Williams, “Multiple recycling of NdFeB-type sintered magnets. J. Alloys Comp. 469, 314–321 (2009)
M. Xia, A.B. Abrahamsen, C.R.H. Bahl, B. Veluri, A.I. Søegaard, P. Bøjsøe, Hydrogen decrepitation press-less process recycling of NdFeB sintered magnets. J. Magn. Magn. Mater. 441, 55–61 (2017)
M. Tokita, Development of large size ceramic/metal bulk FGM fabricated by spark plasma sintering. Mater Sci Forum. 308–311, 83–88 (1999)
R. Orru, R. Licheri, A.M. Locci, A. Cincotti, G. Cao, Consolidation/synthesis of materials by electric current activated/assisted sintering. Mater. Sci. Eng. R 63, 127–287 (2009)
Y.L. Huang, Y. Wang, Y.H. Hou, Y.L. Wang, Y. Wu, S.C. Ma, Z.W. Liu, D.C. Zeng, Y. Tian, W.X. Xia, Z.C. Zhong, Magnetic microstructure and magnetic properties of spark plasma sintered NdFeB magnets. J. Magnet. Magn. Mater. 399, 175–178 (2016)
Z. Hu, L. Chu, J. Li, Y. Liu, Enhanced magnetic properties in Nd-Fe-B magnets prepared by spark plasma sintering via die-upsetting process. J Rare Earths 29, 660–663 (2011)
https://www.aichisteel.co.jp/ENGLISH/products/electromagnetic/bonded_magnet/technoogy.html
A. Sun, S. Wu, W. Xu et al., Nd2Fe17 nanograins effect on the coercivity of HDDR NdFeB magnets with low boron content. Int J Miner Metall Mater 19, 236–239 (2012)
A. Oharoni, Demagnetizing factors for rectangular ferromagnetic prisms. J. Appl. Phys. 83, 3432–3434 (1998)
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Bernstein, P., Xing, Y., Dubus, JM. et al. Investigating the properties of recycled NdFeB magnets. Eur. Phys. J. Spec. Top. 231, 4179–4183 (2022). https://doi.org/10.1140/epjs/s11734-022-00662-y
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DOI: https://doi.org/10.1140/epjs/s11734-022-00662-y