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Photoelectrorheological properties of polyimides with sulfo-acid and sodium salt sulfo-acid groups: a comparative study

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Abstract

The paper describes a new device that allows us to study the effect of ultraviolet irradiation on the electrorheological characteristics of new photosensitive materials based on colloidal polyimide systems containing SO3H (PI-I) and SO3Na (PI-II) groups. The samples were analyzed using rotational viscometry methods, and a significant effect of irradiation of the systems on the flow velocity and hence the viscosity of the medium and the electrorheological response was shown. At the same time, the dimensional and microrheological properties of colloidal polyimide systems in polar and nonpolar media under simultaneous ultraviolet irradiation and exposure to an electric field were monitored using IR spectroscopy and dynamic light scattering methods. The mobility and zeta potential of polyimide molecules were determined using a sensitive method of phase analysis of light scattering. It is shown that in almost all cases, irradiation of colloidal systems of polyimides led to the uncontrolled formation of larger particles, which decreased during the thermal reaction almost to the initial size, which indicates the stability of the studied systems to external influences (irradiation and electric current).

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Data Availability Statement

This manuscript has associated data in a data repository. [Authors’ comment: All data included in this manuscript are available upon request by contacting with the corresponding author.]

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Acknowledgements

Spectral studies by infrared spectroscopy were performed using the scientific equipment of the Center for molecule composition studies of INEOS RAS.

Funding

The work was financially supported by the Russian Science Foundation (Project 22-19-00678).

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Author notes

  1. Alexander N. Danilin, Mariam G. Ezernitskaya and Nikolay A. Semenov have contributed equally to this work.

Authors and Affiliations

  1. Institute of Applied Mechanics of Russian Academy of Science, Leningradsky Prt. 7, Moscow, Russia, 125040

    Elena S. Kelbysheva, Alexander N. Danilin & Nikolay A. Semenov

  2. A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilova Str. 28, Moscow, Russia, 119334

    Mariam G. Ezernitskaya

Authors
  1. Elena S. Kelbysheva
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  2. Alexander N. Danilin
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Correspondence to Elena S. Kelbysheva.

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Kelbysheva, E.S., Danilin, A.N., Ezernitskaya, M.G. et al. Photoelectrorheological properties of polyimides with sulfo-acid and sodium salt sulfo-acid groups: a comparative study. Eur. Phys. J. Plus 138, 747 (2023). https://doi.org/10.1140/epjp/s13360-023-04383-6

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