Abstract
The nanosized materials exhibit a great potential for high-performance electronics applications, and the knowledge of their optoelectronic properties is essential since they are closely related to efficient electron–hole pair generation and photodetection properties. The present work consists of the high-yield synthesis of CuxSn1–xSe (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) ternary alloy nanocrystals by sonochemical exfoliation technique and comprehensive photocatalytic investigation of these alloy engineered nanocrystals. The stoichiometry, chemical composition, morphology, phase, structure, bandgaps, vibrational properties, binding energy and oxidation states of the synthesized nanocrystals are characterized by EDAX, TEM, SAED, XRD, UV-DRS, photoluminescence (PL) and Raman spectroscopy. The synthesized CuxSn1–xSe nanocrystal samples have been evaluated for their photocatalytic activity by studying the degradation of methylene blue (MB) and crystal violet (CV) dyes under UV light irradiation. The present study reveals about material photoabsorption characteristics that these materials could be used as a promising heterogeneous photocatalyst for degradation of pollutant dyes under UV irradiation. Also, it demonstrates and highlights the further alloy engineering modification of CuxSn1–xSe nanocrystals would promote the photocatalytic activity for various environmental applications or not. Experiments have also been performed for understanding the stability and reusability of the photocatalyst.
Graphic abstract
Similar content being viewed by others
References
S. Ameen, H.K. Seo, M. Shaheer Akhtar, H.S. Shin, Novel graphene/polyaniline nanocomposites and its photocatalytic activity toward the degradation of rose Bengal dye. Chem. Eng. J. 210, 220–228 (2012). https://doi.org/10.1016/j.cej.2012.08.035
H. Zhu, R. Jiang, L. Xiao, Y. Chang, Y. Guan, X. Li, G. Zeng, Photocatalytic decolorization and degradation of Congo Red on innovative crosslinked chitosan/nano-CdS composite catalyst under visible light irradiation. J. Hazard. Mater. 169, 933–940 (2009). https://doi.org/10.1016/j.jhazmat.2009.04.037
G. Liu, L. Wang, H.G. Yang, H.M. Cheng, G.Q. Lu, Titania-based photocatalysts—crystal growth, doping and heterostructuring. J. Mater. Chem. 20, 831–843 (2010). https://doi.org/10.1039/b909930a
Q. Fan, Y. Huang, C. Zhang, J. Liu, L. Piao, Y. Yu, S. Zuo, B. Li, Superior nanoporous graphitic carbon nitride photocatalyst coupled with CdS quantum dots for photodegradation of RhB. Catal. Today. 264, 250–256 (2016). https://doi.org/10.1016/j.cattod.2015.08.006
J. Jiang, K. Zhang, X. Chen, F. Zhao, T. Xie, D. Wang, Y. Lin, Porous Ce-doped ZnO hollow sphere with enhanced photodegradation activity for artificial waste water. J. Alloys Compd. 699, 907–913 (2017). https://doi.org/10.1016/j.jallcom.2017.01.036
W.W. Anku, S.O.B. Oppong, S.K. Shukla, E.S. Agorku, P.P. Govender, Cobalt doped ZrO2 decorated multiwalled carbon nanotube: a promising nanocatalyst for photodegradation of indigo carmine and eosin Y dyes. Prog. Nat. Sci. Mater. Int. 26, 354–361 (2016). https://doi.org/10.1016/j.pnsc.2016.06.007
M.M. Sajid, S.B. Khan, N.A. Shad, N. Amin, Z. Zhang, Visible light assisted photocatalytic degradation of Crystal Violet dye and electrochemical detection of ascorbic acid using a BiVO4/FeVO4 heterojunction composite. RSC Adv. 8, 23489–23498 (2018). https://doi.org/10.1039/c8ra03890b
M. Lučić Škorić, I. Terzić, N. Milosavljević, M. Radetić, Z. Šaponjić, M. Radoičić, M. Kalagasidis Krušić, Chitosan-based microparticles for immobilization of TiO2 nanoparticles and their application for photodegradation of textile dyes. Eur. Polym. J. 82, 57–70 (2016). https://doi.org/10.1016/j.eurpolymj.2016.06.026
T. Parangi, M.K. Mishra, Titania nanoparticles as modified photocatalysts: a review on design and development. Comments Inorg. Chem. 39, 90–126 (2019). https://doi.org/10.1080/02603594.2019.1592751
C.W. Lai, S. Sreekantan, Fabrication of WO3 nanostructures by anodization method for visible-light driven water splitting and photodegradation of methyl orange. Mater. Sci. Semicond. Process. 16, 303–310 (2013). https://doi.org/10.1016/j.mssp.2012.10.007
F. Dong, Y. Guo, J. Zhang, Y. Li, L. Yang, Q. Fang, H. Fang, K. Jiang, Size-controllable hydrothermal synthesis of ZnS nanospheres and the application in photocatalytic degradation of organic dyes. Mater. Lett. 97, 59–63 (2013). https://doi.org/10.1016/j.matlet.2013.01.029
G. Elango, S.M. Kumaran, S.S. Kumar, S. Muthuraja, S.M. Roopan, Green synthesis of SnO2 nanoparticles and its photocatalytic activity of phenolsulfonphthalein dye. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 145, 176–180 (2015). https://doi.org/10.1016/j.saa.2015.03.033
R. Atchudan, T.N.J.I. Edison, S. Perumal, M. Shanmugam, Y.R. Lee, Direct solvothermal synthesis of zinc oxide nanoparticle decorated graphene oxide nanocomposite for efficient photodegradation of azo-dyes. J. Photochem. Photobiol. A Chem. 337, 100–111 (2017). https://doi.org/10.1016/j.jphotochem.2017.01.021
C. Racles, M.F. Zaltariov, M. Iacob, M. Silion, M. Avadanei, A. Bargan, Siloxane-based metal–organic frameworks with remarkable catalytic activity in mild environmental photodegradation of azo dyes. Appl. Catal. B Environ. 205, 78–92 (2017). https://doi.org/10.1016/j.apcatb.2016.12.034
A. Kharatzadeh, F. Jamali-Sheini, R. Yousefi, Excellent photocatalytic performance of Zn(1–x)MgxO/rGO nanocomposites under natural sunlight irradiation and their photovoltaic and UV detector applications. Mater. Des. 107, 47–55 (2016). https://doi.org/10.1016/j.matdes.2016.06.007
S. Feizpoor, A. Habibi-Yangjeh, I. Ahadzadeh, K. Yubuta, Oxygen-rich TiO2 decorated with c-dots: highly efficient visible-light-responsive photocatalysts in degradations of different contaminants. Adv. Powder Technol. 30, 1183–1196 (2019). https://doi.org/10.1016/j.apt.2019.03.014
J. Shi, D. Ma, G.F. Han, Y. Zhang, Q. Ji, T. Gao, J. Sun, X. Song, C. Li, Y. Zhang, X.Y. Lang, Y. Zhang, Z. Liu, Controllable growth and transfer of monolayer MoS2 on Au foils and its potential application in hydrogen evolution reaction. ACS Nano 8, 10196–10204 (2014). https://doi.org/10.1021/nn503211t
J. Yu, C.Y. Xu, F.X. Ma, S.P. Hu, Y.W. Zhang, L. Zhen, Monodisperse SnS2 nanosheets for high-performance photocatalytic hydrogen generation. ACS Appl. Mater. Interfaces. 6, 22370–22377 (2014). https://doi.org/10.1021/am506396z
Z. Wu, Y. Xue, Y. Zhang, J. Li, T. Chen, SnS2 nanosheet-based microstructures with high adsorption capabilities and visible light photocatalytic activities. RSC Adv. 5, 24640–24648 (2015). https://doi.org/10.1039/c5ra00395d
C. Lin, X. Zhu, J. Feng, C. Wu, S. Hu, J. Peng, Y. Guo, L. Peng, J. Zhao, J. Huang, J. Yang, Y. Xie, Hydrogen-incorporated TiS2 ultrathin nanosheets with ultrahigh conductivity for stamp-transferrable electrodes. J. Am. Chem. Soc. 135, 5144–5151 (2013). https://doi.org/10.1021/ja400041f
Y. Sang, Z. Zhao, M. Zhao, P. Hao, Y. Leng, H. Liu, From UV to near-infrared, WS2 nanosheet: a novel photocatalyst for full solar light spectrum photodegradation. Adv. Mater. 27, 363–369 (2015). https://doi.org/10.1002/adma.201403264
Y. Wu, M. Xu, X. Chen, S. Yang, H. Wu, J. Pan, X. Xiong, CTAB-assisted synthesis of novel ultrathin MoSe2 nanosheets perpendicular to graphene for the adsorption and photodegradation of organic dyes under visible light. Nanoscale 8, 440–450 (2016). https://doi.org/10.1039/c5nr05748e
H. Li, J. Wu, Z. Yin, H. Zhang, Preparation and applications of mechanically exfoliated single-layer and multilayer MoS2 and WSe2 nanosheets. Acc. Chem. Res. 47, 1067–1075 (2014). https://doi.org/10.1021/ar4002312
L. Das, A. Guleria, S. Adhikari, Aqueous phase one-pot green synthesis of SnSe nanosheets in a protein matrix: negligible cytotoxicity and room temperature emission in the visible region. RSC Adv. 5, 61390–61397 (2015). https://doi.org/10.1039/c5ra09448h
M.L. Liu, B. Bin Chen, R.S. Li, C.M. Li, H.Y. Zou, C.Z. Huang, Dendritic CuSe with hierarchical side-branches: synthesis, efficient adsorption, and enhanced photocatalytic activities under daylight. ACS Sustain. Chem. Eng. 5, 4154–4160 (2017). https://doi.org/10.1021/acssuschemeng.7b00126
M.B. Zaman, T. Chandel, R. Poolla, Controlled hydrothermal growth and photocatalytic performance of Cu2SnSe3 nanocrystals with different morphologies for dye degradation. Mater. Res. Express. 6, 25004 (2018). https://doi.org/10.1088/2053-1591/aae96c
Q.H. Wang, K. Kalantar-Zadeh, A. Kis, J.N. Coleman, M.S. Strano, Electronics and optoelectronics of two-dimensional transition metal dichalcogenides. Nat. Nanotechnol. 7, 699–712 (2012). https://doi.org/10.1038/nnano.2012.193
W. Wang, T. Ding, G. Chen, L. Zhang, Y. Yu, Q. Yang, Synthesis of Cu2SnSe3–Au heteronanostructures with optoelectronic and photocatalytic properties. Nanoscale 7, 15106–15110 (2015). https://doi.org/10.1039/c5nr04468e
P. Kush, S. Deka, Anisotropic kesterite Cu2ZnSnSe4 colloidal nanoparticles: photoelectrical and photocatalytic properties. Mater. Chem. Phys. 162, 608–616 (2015). https://doi.org/10.1016/j.matchemphys.2015.06.034
E.K. Chere, Q. Zhang, K. Dahal, F. Cao, J. Mao, Z. Ren, Studies on thermoelectric figure of merit of Na-doped p-type polycrystalline SnSe. J. Mater. Chem. A. 4, 1848–1854 (2016). https://doi.org/10.1039/c5ta08847j
C.L. Chen, H. Wang, Y.Y. Chen, T. Day, G.J. Snyder, Thermoelectric properties of p-type polycrystalline SnSe doped with Ag. J. Mater. Chem. A. 2, 11171–11176 (2014). https://doi.org/10.1039/c4ta01643b
J. Gao, H. Zhu, T. Mao, L. Zhang, J. Di, G. Xu, The effect of Sm doping on the transport and thermoelectric properties of SnSe. Mater. Res. Bull. 93, 366–372 (2017). https://doi.org/10.1016/j.materresbull.2017.04.053
J.H. Kim, S. Oh, Y.M. Kim, H.S. So, H. Lee, J.S. Rhyee, S.D. Park, S.J. Kim, Indium substitution effect on thermoelectric and optical properties of Sn1−xInxSe compounds. J. Alloys Compd. 682, 785–790 (2016). https://doi.org/10.1016/j.jallcom.2016.04.308
X. Shi, A. Wu, T. Feng, K. Zheng, W. Liu, Q. Sun, M. Hong, S.T. Pantelides, Z.G. Chen, J. Zou, High thermoelectric performance in p-type polycrystalline Cd-doped SnSe achieved by a combination of cation vacancies and localized lattice engineering. Adv. Energy Mater. 9, 1–15 (2019). https://doi.org/10.1002/aenm.201803242
Y.X. Chen, Z.H. Ge, M. Yin, D. Feng, X.Q. Huang, W. Zhao, J. He, Understanding of the extremely low thermal conductivity in high-performance polycrystalline SnSe through potassium doping. Adv. Funct. Mater. 26, 6836–6845 (2016). https://doi.org/10.1002/adfm.201602652
X.L. Shi, K. Zheng, W. Di Liu, Y. Wang, Y.Z. Yang, Z.G. Chen, J. Zou, Realizing high thermoelectric performance in n-type highly distorted Sb-doped SnSe microplates via tuning high electron concentration and inducing intensive crystal defects. Adv. Energy Mater. (2018). https://doi.org/10.1002/aenm.201800775
R. Chen, S. Li, J. Liu, Y. Li, F. Ma, J. Liang, X. Chen, Z. Miao, J. Han, T. Wang, Q. Li, Hierarchical Cu doped SnSe nanoclusters as high-performance anode for sodium-ion batteries. Electrochim. Acta. 282, 973–980 (2018). https://doi.org/10.1016/j.electacta.2018.07.035
J. Li, J. Xu, H. Wang, G.Q. Liu, X. Tan, H. Shao, H. Hu, J. Jiang, Enhanced thermoelectric performance in p-type polycrystalline SnSe by Cu doping. J. Mater. Sci. Mater. Electron. 29, 18727–18732 (2018). https://doi.org/10.1007/s10854-018-9996-x
X. Shi, K. Zheng, M. Hong, W. Liu, R. Moshwan, Y. Wang, X. Qu, Z.G. Chen, J. Zou, Boosting the thermoelectric performance of p-type heavily Cu-doped polycrystalline SnSe: via inducing intensive crystal imperfections and defect phonon scattering. Chem. Sci. 9, 7376–7389 (2018). https://doi.org/10.1039/c8sc02397b
Y. Gong, C. Chang, W. Wei, J. Liu, W. Xiong, S. Chai, D. Li, J. Zhang, G. Tang, Extremely low thermal conductivity and enhanced thermoelectric performance of polycrystalline SnSe by Cu doping. Scr. Mater. 147, 74–78 (2018). https://doi.org/10.1016/j.scriptamat.2017.12.035
J. Gao, G. Xu, Thermoelectric performance of polycrystalline Sn1−xCuxSe (x = 0–0.03) prepared by high pressure method. Intermetallics 89, 40–45 (2017). https://doi.org/10.1016/j.intermet.2017.05.018
X. Wang, X. Liu, D. Yin, Y. Ke, M.T. Swihart, Size-, shape-, and composition-controlled synthesis and localized surface plasmon resonance of copper tin selenide nanocrystals. Chem. Mater. 27, 3378–3388 (2015). https://doi.org/10.1021/acs.chemmater.5b00618
N.K. Singh, S. Bathula, B. Gahtori, K. Tyagi, D. Haranath, A. Dhar, The effect of doping on thermoelectric performance of p-type SnSe: promising thermoelectric material. J. Alloys Compd. 668, 152–158 (2016). https://doi.org/10.1016/j.jallcom.2016.01.190
J. Fan, W. Carrillo-Cabrera, I. Antonyshyn, Y. Prots, I. Veremchuk, W. Schnelle, C. Drathen, L. Chen, Y. Grin, Crystal structure and physical properties of ternary phases around the composition Cu5Sn2Se7 with tetrahedral coordination of atoms. Chem. Mater. 26, 5244–5251 (2014). https://doi.org/10.1021/cm501899q
A.M. Alotaibi, B.A.D. Williamson, S. Sathasivam, A. Kafizas, M. Alqahtani, C. Sotelo-Vazquez, J. Buckeridge, J. Wu, S.P. Nair, D.O. Scanlon, I.P. Parkin, Enhanced photocatalytic and antibacterial ability of Cu-doped anatase TiO2 thin films: theory and experiment. ACS Appl. Mater. Interfaces 12, 15348–15361 (2020). https://doi.org/10.1021/acsami.9b22056
S. Mathew, P. Ganguly, S. Rhatigan, V. Kumaravel, C. Byrne, S.J. Hinder, J. Bartlett, M. Nolan, S.C. Pillai, Cu-doped TiO2: visible light assisted photocatalytic antimicrobial activity. Appl. Sci. 8, 2067 (2018). https://doi.org/10.3390/app8112067
K. Patel, G.K. Solanki, K.D. Patel, V.M. Pathak, P. Chauhan, A. Patel, Synthesis and photodetection properties of sonochemically exfoliated Cu0.2Sn0.8Se nanoparticles. J. Nano-Electron. Phys. 12, 02005 (2020). https://doi.org/10.21272/JNEP.12(2).02005
K. Patel, G.K. Solanki, K.D. Patel, V.M. Pathak, X-ray diffraction analysis of hexagonal klockmannite CuSe nanoparticles for photodetectors under UV light. J. Phys. Chem. C. 125, 3526 (2021). https://doi.org/10.1021/acs.jpcc.0c09353
K. Patel, G. Solanki, K. Patel, V. Pathak, P. Chauhan, Investigation of optical, electrical and optoelectronic properties of SnSe crystals. Eur. Phys. J B 92, 1–11 (2019). https://doi.org/10.1140/EPJB/E2019-100306-8
K. Patel, P. Chauhan, A. Patel, G.K. Solanki, K. Patel, V.M. Pathak, Orthorhombic SnSe nanocrystals for visible-light photodetectors. ACS Appl. Nano Mater. 3, 11143–11151 (2020). https://doi.org/10.1021/acsanm.0c02301
K. Venkataraman (ed.), The Chemistry of Synthetic Dyes (Elsevier, Amsterdam, 1971)
D.R. Paul, R. Sharma, S.P. Nehra, A. Sharma, Effect of calcination temperature, pH and catalyst loading on photodegradation efficiency of urea derived graphitic carbon nitride towards methylene blue dye solution. RSC Adv. 9, 15381–15391 (2019). https://doi.org/10.1039/c9ra02201e
K. Patel, G. Solanki, K. Patel, V. Pathak, P. Chauhan, Investigation of optical, electrical and optoelectronic properties of SnSe crystals. Eur. Phys. J. B. 92, 200 (2019). https://doi.org/10.1140/epjb/e2019-100306-8
X. Xu, Q. Song, H. Wang, P. Li, K. Zhang, Y. Wang, K. Yuan, Z. Yang, Y. Ye, L. Dai, In-Plane anisotropies of polarized Raman response and electrical conductivity in layered tin selenide. ACS Appl. Mater. Interfaces. 9, 12601–12607 (2017). https://doi.org/10.1021/acsami.7b00782
F. Liu, P. Parajuli, R. Rao, P.C. Wei, A. Karunarathne, S. Bhattacharya, R. Podila, J. He, B. Maruyama, G. Priyadarshan, J.R. Gladden, Y.Y. Chen, A.M. Rao, Phonon anharmonicity in single-crystalline SnSe. Phys. Rev. B. 98, 224309 (2018). https://doi.org/10.1103/PhysRevB.98.224309
M.A. Franzman, C.W. Schlenker, M.E. Thompson, R.L. Brutchey, Solution-phase synthesis of SnSe nanocrystals for use in solar cells. J. Am. Chem. Soc. 132, 4060–4061 (2010). https://doi.org/10.1021/ja100249m
A. Sharma, L.S. Chongad, M. Banerjee, Microstructure and optical properties of Cu doped CdS nanostructured thin Films. J. Phys. Conf. Ser. 755, 12034 (2016). https://doi.org/10.1088/1742-6596/755/1/012034
M.B. Zaman, T. Chandel, R. Poolla, Controlled hydrothermal growth and photocatalytic performance of Cu2SnSe3 nanocrystals with different morphologies for dye degradation. Mater. Res. Express (2019). https://doi.org/10.1088/2053-1591/aae96c
P.S. Rao, E. Hayon, Redox potentials of free radicals. IV. Superoxide and hydroperoxy radicals ·O2− and··HO2. J. Phys. Chem. 79, 397–402 (1975). https://doi.org/10.1021/j100571a021
Y. Gu, Y. Su, D. Chen, H. Geng, Z. Li, L. Zhang, Y. Zhang, Hydrothermal synthesis of hexagonal CuSe nanoflakes with excellent sunlight-driven photocatalytic activity. CrystEngComm 16, 9185–9190 (2014). https://doi.org/10.1039/c4ce01470g
H. Lei, H. Zhang, Y. Zou, X. Dong, Y. Jia, F. Wang, Synergetic photocatalysis/piezocatalysis of bismuth oxybromide for degradation of organic pollutants. J. Alloys Compd. 809, 151840 (2019). https://doi.org/10.1016/j.jallcom.2019.151840
S. Nair, J. Joy, C. Limberkar, K.D. Patel, G.K. Solanki, V.M. Pathak, Photocatalytic degradation of organic dyes by Ni (25%) doped WSe2 nanosheets. Mater. Sci. Semicond. Process. 125, 105625 (2021). https://doi.org/10.1016/j.mssp.2020.105625
L. Tong, Z. Wang, C. Xia, Y. Yang, S. Yuan, D. Sun, X. Xin, Self-assembly of peptide-polyoxometalate hybrid sub-micrometer spheres for photocatalytic degradation of Methylene Blue. J. Phys. Chem. B. 121, 10566–10573 (2017). https://doi.org/10.1021/acs.jpcb.7b07100
C. Xia, Z. Wang, D. Sun, B. Jiang, X. Xin, Hierarchical nanostructures self-assembled by polyoxometalate and alkylamine for photocatalytic degradation of dye. Langmuir 33, 13242–13251 (2017). https://doi.org/10.1021/acs.langmuir.7b03495
S. Yu, J. Liu, Y. Zhou, R.D. Webster, X. Yan, Effect of synthesis method on the nanostructure and solar-driven photocatalytic properties of TiO2–CuS composites. ACS Sustain. Chem. Eng. 5, 1347–1357 (2017). https://doi.org/10.1021/acssuschemeng.6b01769
P. Sun, S. Zhang, J. Pang, Y. Tan, D. Sun, C. Xia, X. Cheng, X. Xin, Self-assembly of ionic-liquid-type imidazolium gemini surfactant with polyoxometalates into supramolecular architectures for photocatalytic degradation of dye. J. Mol. Liq. 272, 180–187 (2018). https://doi.org/10.1016/j.molliq.2018.08.016
Acknowledgements
The authors would like to thank the University Grants Commission, India, for providing Fellowship (NFO-2017-18-OBC-GUJ-54983) to the corresponding author Mr. Kunjal Patel.
Author information
Authors and Affiliations
Corresponding authors
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Patel, K., Parangi, T., Solanki, G.K. et al. Photocatalytic degradation of methylene blue and crystal violet dyes under UV light irradiation by sonochemically synthesized CuSnSe nanocrystals. Eur. Phys. J. Plus 136, 743 (2021). https://doi.org/10.1140/epjp/s13360-021-01725-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1140/epjp/s13360-021-01725-0