Spectral studies of nano Ni ferrite doped with Cr ions

  • O. M. Hemeda
  • M. I. Abdel-Ati
  • B. I. Salem
  • A. M. A. HenaishEmail author
  • F. S. El-Sbakhy
Regular Article


Nano-crystalline NiCrxFe2-xO4 (where x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) system have been synthesized by the flash auto-combustion method annealed at 400°C for 2h. The X-ray diffraction (XRD) technique was employed to confirm the single phase formation of nickel ferrite. The transmission electron microscopy (TEM) was used to characterize the nanostructure of ferrite. All samples were crystallized in a spinel cubic structure. The (IR) spectra was recorded in the range from 200-4000cm^-1. The absorption bands at 601cm^-1 (\(\nu_{1}\) and 410 cm-1 (\(\nu_{2}\)) were assigned to tetrahedral (A site) and octahedral (B site) groups complex. The morphological observation which was determined by scanning electron microscopy (SEM) shows agglomerated grains with different shapes and sizes. The values of lattice constant, X-ray density, bulk density, and porosity were calculated. The decrease in the lattice constant was endorsed to the difference in ionic radius of both Fe3+ (0.67 Å) and Cr3+ (0.64 Å). The particle size was found in the range of 18-25nm by X-ray and TEM analysis. The porosity has an inverse character with the bulk density.


  1. 1.
    J.D. Adam, S.V. Krishnaswamy, S.H. Talisa, K.C. Yoo, J. Magn. & Magn. Mater. 83, 419 (1990)ADSCrossRefGoogle Scholar
  2. 2.
    M.K. Shobana, H. Choe, J. Mater. Sci.: Mater. Electron. 27, 13052 (2016)Google Scholar
  3. 3.
    K. Maaz, S. Karim, A. Mumtaz, S.K. Hasanin, J. Liu, J.L. Duan, J. Magn. & Magn. Mater. 321, 1838 (2009)ADSCrossRefGoogle Scholar
  4. 4.
    M. Miroslaw, B.K. Haberko, J. Eur. Ceram. Mater. 27, 723 (2007)CrossRefGoogle Scholar
  5. 5.
    M. Mouallem-Bahout, S. Bertrand, O. Pena, J. Solid State Chem. Mater. 178, 1080 (2005)ADSCrossRefGoogle Scholar
  6. 6.
    S.A. Popescu, P. Vlazan, P.V. Notingher, S. Novaconi, I. Grozescu, A. Bucur, P. Sfirloaga, Optoelectron. Adv. Mater. 13, 260 (2011)Google Scholar
  7. 7.
    D.R. Mane, D.D. Birajdar, S.E. Telugu, R.A. Kadam, Phys. Status Solidi A 207, 2355 (2010)ADSCrossRefGoogle Scholar
  8. 8.
    M.A. Ahmed, S.I. El-dek, S.F. Mansour, N. Okasha, Solid State Sci. 13, 1180 (2011)ADSCrossRefGoogle Scholar
  9. 9.
    S.F. Mansour, O.M. Hemeda, S.I. El-dek, B.I. Salem, J. Magn. & Magn. Mater. 420, 7 (2016)ADSCrossRefGoogle Scholar
  10. 10.
    B.D. Cullity, Elements of X-ray Diffraction (Addison-Wesley, Reading, MA, 1959) p. 514Google Scholar
  11. 11.
    A. Kumar, K. Yadav, Mater. Sci. Eng. B 176, 227 (2011)CrossRefGoogle Scholar
  12. 12.
    N. Jahan, F.Z. Chowdhury, A.K.M. Zakaria, Mater. Sci.-Poland 34, 185 (2016)CrossRefGoogle Scholar
  13. 13.
    A.K. Ghatage, S.C. Choudhari, S.A. Patil, J. Mater. Sci. Lett. 15, 1548 (1996)CrossRefGoogle Scholar
  14. 14.
    M.A. Gabaln, S. Kosa, T.S. El Muttairiatil, Ceram. Int. 40, 675 (2014)CrossRefGoogle Scholar
  15. 15.
    H.E. Hassan, T. Sharshar, M.M. Hessien, O.M. Hemeda, Nucl. Instrum. Methods Phys. Res. B 304, 72 (2013)ADSCrossRefGoogle Scholar
  16. 16.
    K.J. Standely, Oxide Magnetic Materials (Clarendon Press, Oxford, 2010)Google Scholar
  17. 17.
    O.M. Hemeda, J. Magn. & Magn. Mater. 251, 50 (2002)ADSCrossRefGoogle Scholar
  18. 18.
    A. Rais, A.M. Gismelseed, I.A. AL-Omari, Phys. Status Solidi (b) 242, 1497 (2005)ADSCrossRefGoogle Scholar
  19. 19.
    A. Rafferty, K. Gun, R. Raghavendra, Mater. Res. Bull. 44, 747 (2009)CrossRefGoogle Scholar
  20. 20.
    J.S. Ghodake, R.C. Kambale, T.J. Shinde, P.K. Maskar, S.S. Suryavanshi, J. Magn. & Magn. Mater. 401, 938 (2016)ADSCrossRefGoogle Scholar
  21. 21.
    O.M. Hemeda, M.Z. Said, M.M. Barakat, J. Magn. & Magn. Mater. 224, 132 (2001)ADSCrossRefGoogle Scholar
  22. 22.
    W.Z. Lv, B. Liu, Z.K. Luo, X.Z. Ren, P.X. Zhang, J. Alloys Compd. 465, 261 (2008)CrossRefGoogle Scholar
  23. 23.
    P.A. Shaikh, R.C. Kambale, A.V. Rao, Y.D. Kolekar, J. Alloys Compd. 492, 590 (2010)CrossRefGoogle Scholar
  24. 24.
    M.J. Iqbal, Z. Ahmed, T. Meydan, Y. Melikhov, J. Appl. Phys. 111, 590 (2012)Google Scholar
  25. 25.
    M. Lakshmi, K. Vijaya Kumar, K. Thyagarajan, J. Nanostruct. Chem. 5, 365 (2015)CrossRefGoogle Scholar
  26. 26.
    R.M. Sebastain, S. Xavier, E.M. Mohammed, Int. J. Eng. Sci. Innor. Technol. (IJESIT) 2, 512 (2013)Google Scholar
  27. 27.
    J.S. Ghodake, R.C. Kambale, T.J. Shinde, P.K. Maskar, S.S. Suryavanshi, J. Magn. & Magn. Mater. 401, 938 (2016)ADSCrossRefGoogle Scholar

Copyright information

© Società Italiana di Fisica and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Physics Department, Faculty of ScienceTanta UniversityTantaEgypt
  2. 2.Physics Department, Faculty of EngineeringSinai UniversityEl-ArishEgypt

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