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Contribution to the benchmark for ternary mixtures: Measurement of diffusion and Soret coefficients of ternary system tetrahydronaphtalene-isobutylbenzene-n-dodecane with mass fractions 80-10-10 at 25 °C

Abstract

This paper provides the molecular diffusion and Soret coefficients of the ternary system 1,2,3,4-tetrahydronaphtalene, isobutylbenzene, n -dodecane system at mass fractions 0.8-0.1-0.1 and temperature 25 °C for implementation into the benchmark presented in this topical issue. The Soret coefficients are determined by digital interferometry using the data of DSC-DCMIX microgravity experiment. The method used takes into account the influence of the thermal field on the Soret separations and the selection of the image processing techniques results in reproducible Soret coefficients.The diffusion coefficients are obtained by the Open Ended Capillary technique The fitting of the data collected through a set of two complementary experimental runs allows retrieving the four Fickian diffusion coefficients.

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References

  1. M.M. Bou-Ali, A. Ahadi, D. Alonso de Mezquía, Q. Galand, M. Gebhardt, O. Khlybov, W. Köhler, M. Larrañaga, J.C. Legros, T. Lyubimova, A. Mialdun, I. Ryzhkov, M.Z. Saghir, V. Shevtsova, S. Van Varenbergh, ``Benchmark values for the Soret, thermodiffusion and molecular diffusion coefficients of the ternary mixture tetralin+isobutylbenzene+$n$-dodecane with 0.8-0.1-0.1 mass fraction'', this topical issue.

  2. V. Shevtsova, T. Lyubimova, Z. Saghir, D. Melnikov, Y. Gaponenko, V. Sechenyh, J.C. Legros, A. Mialdun, J. Phys.: Conf. Ser. 327, 012031 (2011) DOI:10.1088/1742-6596/327/1/012031.

    ADS  Google Scholar 

  3. S.R. de Groot, P. Mazur, Non-equilibrium thermodynamics (Dover, New-York, 1984).

  4. A. Ahadi, S. Van Vaerenbergh, M.Z. Saghir, J. Chem. Phys. 138, 204201 (2013) DOI:10.1063/1.4802984.

    Article  ADS  Google Scholar 

  5. J.S. Anderson, K. Saddington, J. Chem. Soc. 2, S381 (1975) DOI:10.1039/JR949000S381.

    Google Scholar 

  6. J.N. Agar, V.M.M. Lobo, J. Chem. Soc. Faraday Trans. 1 71, 1659 (1975) DOI:10.1039/F19757101659.

    Article  Google Scholar 

  7. N.D. Kosov, I.V. Poyarkov, Meas. Techniques 37, 581 (1994) DOI:10.1007/BF00980450.

    Article  Google Scholar 

  8. J.F. Dutrieux, J.K. Platten, G. Chavepeyer, M.M. Bou-Ali, J. Phys. Chem. B 106, 6104 (2002) DOI:10.1021/jp013945r.

    Article  Google Scholar 

  9. A. Leahy-Dios, M.M. Bou Ali, J.K. Platten, A. Firoozabadi, J. Chem. Phys. 122, 234502 (2005) DOI:10.1063/1.1924503.

    Article  ADS  Google Scholar 

  10. Q. Galand, M. Luhmer, S. Van Vaerenbergh, High Temp. High Pres. 38, 329 (2010).

    Google Scholar 

  11. M. Larranaga, M. Bou-Ali, D. Soler, M. Martinez-Aguirre, A. Mialdun, M. Shevtsova, C. R. Mec. 341, 356 (2013) DOI:10.1016/j.crme.2013.01.008.

    Article  ADS  Google Scholar 

  12. J.E. Greivenkamp, J.H. Bruning, ``Phase-shifting interferometry,'' in Optical Shop Testing, edited by D. Malacara (Wiley, New York, 1992).

  13. M. Takeda, H. Ina, J. Kobayashi, J. Opt. Soc. Am. 72, 156 (1982).

    Article  ADS  Google Scholar 

  14. T. Kreis, J. Opt. Soc. Am. 3, 347 (1986) DOI:10.1364/JOSAA.3.000847.

    Article  Google Scholar 

  15. P. Hari Haran, B.F. Oreb, T. Eiju, Appl. Opt. 26, 2504 (1987).

    Article  ADS  Google Scholar 

  16. Zhaoyang Wang, Bongtae Han, Opt. Lett. 29, 1671 (2004) DOI:10.1364/OL.29.001671.

    Article  ADS  Google Scholar 

  17. A. Mialdun, V. Shevtsova, J. Chem. Phys. 134, 044524 (2011) DOI:10.1063/1.3546036.

    Article  ADS  Google Scholar 

  18. A. Mialdun, V. Shevtsova, C. R. Méc. 339, 462 (2011) DOI:10.1016/j.crme.2013.02.001.

    Article  Google Scholar 

  19. D.J. Bone, Appl. Opt. 30, 3627 (1991) DOI:10.1364/AO.30.003627.

    Article  ADS  Google Scholar 

  20. M. Costantini, IEEE Trans GARS 36, 813 (1998) DOI:10.1109/36.673674.

    ADS  Google Scholar 

  21. G. Wittko, W. Köhler, Philos. Mag. 83, 2017 (2003).

    Article  Google Scholar 

  22. S. Van Vaerenbergh, J.C. Legros, Phys. Rev. A 41, 6727 (1990) DOI:10.1103/PhysRevA.41.6727.

    Article  ADS  Google Scholar 

  23. V.V. Sechenyh, J.C. Legros, V. Shevtsova, J. Chem. Thermodyn. 62, 64 (2013) DOI:10.1016/j.jct.2013.01.026.

    Article  Google Scholar 

  24. A. Königer, H. Wunderlich, W. Köhler, J. Chem. Phys. 132, 174506 (2010) DOI:10.1063/1.3421547.

    Article  ADS  Google Scholar 

  25. M. Larranaga, D. Andrew, M. Bou-Ali, J. Chem. Phys. 140, 984503 (2014) DOI:10.1063/1.4864189.

    Article  Google Scholar 

  26. Q. Galand, S. Van Vaerenbergh, F. Montel, Energy Fuels 22, 770 (2008) DOI:10.1021/ef7004332.

    Article  Google Scholar 

  27. M.J.D. Powel, Math. Prog. 4, 193 (1973) DOI:10.1007/BF01584660.

    Article  Google Scholar 

  28. R. Taylor, R. Krishna, Multicomponent Mass Transfer (Wiley, New York, 1976).

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Correspondence to Quentin Galand.

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Contribution to the Topical Issue “Thermal non-equilibrium phenomena in multi-component fluids” edited by Fabrizio Croccolo and Henri Bataller.

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Galand, Q., Van Vaerenbergh, S. Contribution to the benchmark for ternary mixtures: Measurement of diffusion and Soret coefficients of ternary system tetrahydronaphtalene-isobutylbenzene-n-dodecane with mass fractions 80-10-10 at 25 °C. Eur. Phys. J. E 38, 26 (2015). https://doi.org/10.1140/epje/i2015-15026-3

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  • DOI: https://doi.org/10.1140/epje/i2015-15026-3

Keywords

  • Topical Issue: Thermal non-equilibrium phenomena in multi-component fluids