Abstract
Vibrational energy transfer was a key property of chemical reactions that remains deeply understood. In this work, the detail information of vibrational energy transfer in aniline, N,N-dimethylaniline (DMA) and N,N-diethylaniline (DEA) were studied by femtosecond time-resolved coherent anti-Stokes Raman scattering (CARS) spectroscopy, respectively. Low frequency modes of aniline, DMA and DEA were collectively excited, the beats arising from vibrational couplings among these modes were described. With analysis of vibrational coupling, energy transfer flow from one mode to another was visualized. An investigation into the molecular structure and vibrational couplings can be found that vibrational energy transfer is related to vibrational mode symmetry. In addition, substituent groups play an important role in vibrational coupling and energy transfer of aniline, DMA and DEA. A decrease of the number of substituent vibrational modes involved in coupling and energy transfer efficiency with the increase of the amount of relative molecular mass ratio was found out.
Graphical abstract
Similar content being viewed by others
Data availability statement
This manuscript has no associated data or the data will not be deposited. [Authors’ comment: All our data are available from the corresponding author on reasonable request.]
References
N.C. Cole-Filipiak, R. Knepper, M. Wood, K. Ramasesha, J. Phys. Chem. Lett. 11, 6664 (2020)
H.K. Shin, J. Phys. Chem. A 124, 3031 (2020)
R. Borrelli, M.F. Gelin, New J. Phys. 22, 123002 (2020)
H. Wu, Y. Song, G. Yu, X. Chen, Y. Yang, J. Raman Spectrosc. 47, 1213 (2016)
G. Yu, Y. Zeng, W. Guo, H. Wu, G. Zhu, Z. Zheng, X. Zheng, Y. Song, Y. Yang, J. Phys. Chem. A 121, 2565 (2017)
A.A. Mohamed, A.W. El-Harby, J. Mol. Struct. (Thoechem) 849, 52 (2008)
S. Ohashi, D. Iguchi, T.R. Heyl, P. Froimowicz, H. Ishida, Polym. Chem. 9, 4194 (2018)
H. Yang, Y. Peng, L. Huang, H. Zhang, Y. Wang, S. Xie, J. Lumin. 135, 26 (2013)
A.N. Manin, K.V. Drozd, G.L. Perlovich, J. Mol. Liq. 347, 118320 (2022)
S. Zhao, S. Zhu, H. Zhu, G. Xie, R. Liu, H. Zhu, Opt. Mater. 126, 112183 (2022)
I. Borges, R.M.P.O. Guimares, G. Monteiro-de-Castro, N.M.P. Rosa, R. Nieman, H. Lischka, A.J.A. Aquino, J. Comput. Chem. (2023). https://doi.org/10.1016/j.dyepig.2018.09.028
N. Grover, N. Chaudhri, M. Sankar, Dyes Pigm. 161, 104 (2019)
X. Liu, Y. Song, W. Zhang, G. Zhu, Z. Lv, W. Liu, Y. Yang, RSC Adv. 8, 29775 (2018)
X. Liu, Q. Zou, W. Liu, New J. Chem. 45, 530–521 (2021)
Z. Wang, A. Pakoulev, Y. Pang, D.D. Dlott, J. Phys. Chem. A 108, 9054 (2004)
B.C. Pein, Y. Sun, D.D. Dlott, J. Phys. Chem. B 117, 10898 (2013)
Y. Sun, B.C. Pein, D.D. Dlott, J. Phys. Chem. B 117, 15444 (2013)
C.C. Yu et al., Nat. Commun. 11, 5977 (2020)
Y. Yamada, N. Mikami, T. Ebata, J. Chem. Phys. 121, 11530 (2004)
Y. Yamada, Y. Katsumoto, T. Ebata, Phys. Chem. Chem. Phys. P 9, 1170 (2007)
X. Liu, W. Zhang, W. Liu, Y. Song, W. Zhang, J. Mol. Struct. 1199, 126966 (2020)
X. Liu, H. Li, W. Liu, W. Zhang, Z. Shi, Microw. Opt. Technol. Lett. 1, 6 (2021)
X. Liu, Q. Zou, H. Li, W. Liu, B. Hu, O.A. Al-Hartomy, A. Al-Ghamdi, S. Wageh, Z. Shi, ChemistrySelect 6, 10998 (2021)
R. Ahdenov, A.A. Mohammadi, S. Makarem, S. Taheri, H. Mollabagher, Heterocycl. Commun. 28, 67 (2022)
H.P.R. Kannapu, V. Vaddeboina, Y.K. Park, Catal. Today 397, 28–36 (2022)
D. Pan, B. Jana, J. Ganguly, J. Appl. Polymer Sci. 139, 52236 (2022)
L. Wang, Y. Wu, C. Yu, J. Solid State Chem. 310, 123038 (2022)
X. Liu, W. Zhang, Y. Song, G. Yu, Z. Zheng, Y. Zeng, Z. Lv, H. Song, Y. Yang, J. Phys. Chem. A 121, 4948 (2017)
T. Ebata, C. Minejima, N. Mikami, J. Phys. Chem. A 106, 11070 (2002)
D.A. Chernoff, S.A. Rice, J. Chem. Phys. 70, 2511 (1979)
X. Liu, W. Liu, Z. Yuan, W. Zhang, Vib. Spectrosc. 116, 103296 (2021)
P.M. Wojciechowski, W. Zierkiewicz, D. Michalska, P. Hobza, J. Chem. Phys. 118, 10900 (2003)
G.N.R. Tripathi, R.H. Schuler, J. Chem. Phys. 86, 3795 (1987)
T. Shimanouchi, J. Phys. Chem. Ref. Data 2, 225 (1973)
B. Çatıkkaş, Period. Eng. Nat. Sci. 5, 2 (2017)
A.M. Brouwer, R. Wilbrandt, J. Phys. Chem. 100, 9678 (1996)
G. Rajaa, K. Saravananb, and S. Sivakumarc. D, Bharathiar University, Chapter VIII (2019–2013)
R.A. Weersink, S.C. Wallace, J. Phys. Chem. 97, 6127 (1993)
L.O. Poizat, Spectrochim. Acta, Part A 45A, 2 (1989)
K. Bern, A. Keith, Nelson, J. Phys. Chem. 94, 859 (1992)
L. Dhar, J.A. Rogers, K.A. Nelson, Chem. Rev. 94, 157 (1994)
Acknowledgements
Key Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant NO. 20KJA430005).
Author information
Authors and Affiliations
Contributions
Both authors have contributed equally to the paper. All authors declare no conflict of interest.
Corresponding author
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Liu, X., Zou, Q., Li, H. et al. Studying substituent number effects on vibrational energy transfer by time−resolved CARS spectroscopy. Eur. Phys. J. D 78, 41 (2024). https://doi.org/10.1140/epjd/s10053-024-00830-w
Received:
Accepted:
Published:
DOI: https://doi.org/10.1140/epjd/s10053-024-00830-w