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Change in resonance parameters of a linear molecule as it bends: Evidence in electron-impact vibrational transitions of hot COS and CO2 molecules*

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Abstract

Inelastic and superelastic electron-impact vibrational excitation functions of hot carbonyl sulphide COS (and hot CO2) are measured for electron energies from 0.5 to 3.0 eV (1.5 to 6.0 eV) and at a scattering angle of 90°. Based on the vibrational populations and the principle of detailed balance, these excitation functions are decomposed into contributions from state-to-state vibrational transitions involving up to the second bending overtone (030) in the electronically ground state. Both the 2 Π resonance for COS around 1.2 eV and the 2 Π u resonance for CO2 around 3.8 eV are shifted to lower energies as the initial vibrational state is excited in the bending mode. The width of the resonance hump for COS changes only little as the molecule bends, whereas that of the overall boomerang resonance for CO2 becomes narrower. The angular distribution of the electrons resonantly scattered by hot COS and hot CO2 is also measured. The different shapes depending on the vibrational transitions and gas temperatures are discussed in terms of the symmetry of the vibrational wave functions.

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Authors and Affiliations

  1. Department of Physics, Sophia University, Chiyoda-ku, 102-8554, Tokyo, Japan

    Masamitsu Hoshino, Yohei Ishijima, Hidetoshi Kato & Hiroshi Tanaka

  2. Fine Chemicals Sales Dept.-III, Sales Div., Kanto Denka Kogyo Co., Ltd., Chiyoda-ku, 101-0063, Tokyo, Japan

    Daisuke Mogi

  3. Development & Marketing Management Dept., New Products Development Div., Kanto Denka Kogyo Co., Ltd., Chiyoda-ku, 101-0063, Tokyo, Japan

    Yoshinao Takahashi

  4. Shibukawa Decelopment Research Lab., New Products Development Div., Kanto Denka Kogyo Co., Ltd., Shibukawa-shi, 377-0008, Gunma, Japan

    Katsuya Fukae

  5. Laboratório de Colisões Atómicas e Moleculares, CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516, Caparica, Portugal

    Paulo Limão-Vieira

  6. Atomic Physics Research Unit, RIKEN, Hirosawa 2-1, Wako, 351-0198, Saitama, Japan

    Isao Shimamura

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  1. Masamitsu Hoshino
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Correspondence to Masamitsu Hoshino.

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Hoshino, M., Ishijima, Y., Kato, H. et al. Change in resonance parameters of a linear molecule as it bends: Evidence in electron-impact vibrational transitions of hot COS and CO2 molecules*. Eur. Phys. J. D 70, 100 (2016). https://doi.org/10.1140/epjd/e2016-70085-9

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  • DOI: https://doi.org/10.1140/epjd/e2016-70085-9

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